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Novel properties of liquid crystal gels with helical alignment

Research Project

Project/Area Number 21350123
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyoto University

Principal Investigator

URAYAMA Kenji  京都大学, 工学研究科, 准教授 (20263147)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2011: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2010: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2009: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords液晶 / エラストマー / ゲル / キラリティ / 液晶エラストマー / 光学活性 / ゴム / らせん / アクチュエータ / キラル / 液晶ゲル
Research Abstract

Twist nematic elastomers having a 90 degree twist alignment with definite handedness are prepared by chiral imprint method. The twist nematic elastomers exhibit a macroscopic helical form, and the reversal of the handedness is driven by temperature change. In addition, the shape transition between helicoids and spiral ribbons is induced by changing the width/thickness ratio. Cholesteric elastomers are prepared using reactive chiral LC monomers. The cholestric elastomers reflect the left-circularly polarized light with a characteristic wavelength, and the corresponding wavelength is variable by imposed strain.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (44 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (18 results) (of which Peer Reviewed: 15 results) Presentation (20 results) (of which Invited: 5 results) Book (4 results) Remarks (2 results)

  • [Journal Article] Switching Shapes of Nematic Elastomers with Various Director Configurations2013

    • Author(s)
      K. Urayama
    • Journal Title

      React. Funct. Polym

      Volume: 73 Issue: 7 Pages: 885-885

    • DOI

      10.1016/j.reactfunctpolym.2012.10.008

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Memory and Development of Textures of Polydomain Nematic Elastomers2012

    • Author(s)
      H. Higaki, K. Urayama, T. Takigawa
    • Journal Title

      Macromol. Chem. Phys

      Volume: 213 Issue: 18 Pages: 1907-1907

    • DOI

      10.1002/macp.201200239

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electro-Opto-Mechanical Effects of Swollen Nematic Elastomers2012

    • Author(s)
      K.Urayama
    • Journal Title

      Adv. Polym. Sci.

      Volume: 250 Pages: 119-119

    • DOI

      10.1007/12_2010_107

    • ISBN
      9783642315817, 9783642315824
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] ハイブリッド配向液晶エラストマーの熱屈曲挙動2012

    • Author(s)
      澤芳樹、浦山健治、瀧川敏算、DeSimone,A.,Teresi, L.
    • Journal Title

      日本液晶学会誌

      Volume: 16 Pages: 56-56

    • NAID

      10030617817

    • URL

      http://jglobal.jst.go.jp/public/20090422/201202248765118556

    • Related Report
      2011 Final Research Report
  • [Journal Article] ハイブリッド配向液晶エラストマーの熱屈曲挙動2012

    • Author(s)
      澤 芳樹、浦山健治、瀧川敏算、DeSimone, A., Teresi, L.
    • Journal Title

      日本液晶学会誌

      Volume: 16 Pages: 56-63

    • NAID

      10030617817

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Large Electromechanical Effect of Isotropic Genesis PolydomainNematic Elastomers2011

    • Author(s)
      T.Okamoto,T.,K.Urayama,T.Takigawa
    • Journal Title

      Soft Matter

      Volume: 7 Issue: 22 Pages: 10585-10585

    • DOI

      10.1039/c1sm06372c

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shape Selection of Twist Nematic Elastomer Ribbons2011

    • Author(s)
      Y. Sawa,Y.Fangfu,K.Urayama,T.Takigawa,V.Gimenez-Pinto,R.Selinger,J.Selinger
    • Journal Title

      Proc. Natl. Acad. Sci.

      Volume: 108 Issue: 16 Pages: 6364-6364

    • DOI

      10.1073/pnas.1017658108

    • NAID

      130004590601

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature responsive bending of nematic elastomers with hybrid molecular alignment2011

    • Author(s)
      Y. Sawa, K. Urayama, T. Takigawa
    • Journal Title

      Mol.Cryst.Liq.Cryst

      Volume: 106 Issue: 1 Pages: 549-549

    • DOI

      10.1080/15421406.2011.581157

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shape Selection of Twist Nematic Elastomer Ribbons2011

    • Author(s)
      Y.Sawa, K.Urayama, T.Takigawa
    • Journal Title

      Proceedings of Natural Academy Science of America

      Volume: 108 Pages: 6364-6368

    • NAID

      130004590601

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermally Driven Giant Bending of Liquid Crystal Elastomer Films with Hybrid Alignment2010

    • Author(s)
      Y.Sawa,K.Urayama,T.Takigawa,T.,A.DeSimone,L.Teresi
    • Journal Title

      Macromolecules

      Volume: 43 Issue: 9 Pages: 4362-4362

    • DOI

      10.1021/ma1003979

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 液晶エラストマー・液晶ゲルの多様な刺激応答特性2010

    • Author(s)
      浦山健治
    • Journal Title

      物性研究

      Volume: 93 Pages: 579-579

    • URL

      http://hdl.handle.net/2433/169245

    • Related Report
      2011 Final Research Report
  • [Journal Article] Thermally Driven Giant Bending of Liquid Crystal Elastomer Films with Hybrid Alignment2010

    • Author(s)
      Y.Sawa, K.Urayama, T.Takigawa
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 4362-4369

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermally Driven Giant Bending of Liquid Crystal Elastomer Films with Hybrid Alignment2010

    • Author(s)
      Y.Sawa, K.Urayama, T.Takigawa, A.DeSimone, L.Teresi
    • Journal Title

      Macromolecules 43(印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polydomain-Monodomain Transition of Randomly Disordered Nematic Elastomers with Different Cross-Linking Histories2009

    • Author(s)
      K.Urayama,E.Kohmon,M.Kojima,T.Takigawa
    • Journal Title

      Macromolecules

      Volume: 42 Issue: 12 Pages: 4084-4084

    • DOI

      10.1021/ma9004692

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrically driven director-rotation in swollen nematic elastomers as revealed by polarized Fourier transform infrared spectroscopy2009

    • Author(s)
      A. Fukunaga,K.Urayama,P.Koelsch,T.Takigawa
    • Journal Title

      Phys.Rev.E

      Volume: 79 Issue: 5 Pages: 51702-51702

    • DOI

      10.1103/physreve.79.051702

    • NAID

      120002086072

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Polydomain-Monodomain Transition of Randomly Disordered Nematic Elastomers with Different Cross-Linking Histories2009

    • Author(s)
      K.Urayama, E.Kohmon, M.Kojima, T.Takigawa
    • Journal Title

      Macromolecules 42

      Pages: 4084-4089

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal Deformation of Imprinted Twist Nematic Elastomers2009

    • Author(s)
      Y.Sawa, K.Urayama, T.Takigawa
    • Journal Title

      J.Phys.:Conf.Ser. 184

      Pages: 12022-12022

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrically Driven Director-Rotation of Swollen Nematic Elastomersas Revealed by Polarized Fourier Transform Infrared Spectroscopy2009

    • Author(s)
      A.Fukunaga, K.Urayama, P.Koelsch, T.Takigawa
    • Journal Title

      Phys.Rev.E 79

      Pages: 51702-51702

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 分子配向とマクロ変形のカップリングが生む液晶エラストマーの新規な刺激応答特性2013

    • Author(s)
      浦山健治
    • Organizer
      分子ロボティクス研究会講演会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Stretching Driven Director-Rotation in Monodomain and Polydomain Nematic Elastomers2012

    • Author(s)
      K. Urayama
    • Organizer
      Workshop on Mechanics of Soft Materials and Tissues
    • Place of Presentation
      Trieste, Italy
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Thermosensitve Helical Shape of Twist Nematic Elastomer Ribbons2012

    • Author(s)
      K. Urayama
    • Organizer
      The 4th International Conference “Smart Materials, Structures and Systems”
    • Place of Presentation
      Montecatini Terme, Italy
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] 液晶/エラストマーハイブリッド材料の多様な刺激応答特性2012

    • Author(s)
      浦山健治
    • Organizer
      日本液晶学会講演会
    • Place of Presentation
      千葉大学西千葉キャンパス
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] 液晶性付与によるエラストマーの新奇な刺激応答挙動の創出2012

    • Author(s)
      浦山健治
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Shape Selection and Variation of Twist Nematic Elastomer Ribbons2011

    • Author(s)
      K.Urayama
    • Organizer
      KIPS-ESPCI Workshop on Polymer Science
    • Place of Presentation
      京都
    • Year and Date
      2011-11-28
    • Related Report
      2011 Final Research Report
  • [Presentation] ツイスト配向液晶エラストマーリボンの形態の選択性と温度応答性2011

    • Author(s)
      浦山健治
    • Organizer
      2011年高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-28
    • Related Report
      2011 Final Research Report
  • [Presentation] ツイスト配向液晶エラストマーリボンの形態の選択性と温度依存性2011

    • Author(s)
      浦山健治
    • Organizer
      2011年液晶討論会
    • Place of Presentation
      東京
    • Year and Date
      2011-09-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Shape Selection of Twist Nematic Elastomer Films:Experimental Study2011

    • Author(s)
      K. Urayama
    • Organizer
      The 6th International Liquid Crystal Elastomer Conference
    • Place of Presentation
      Lisbon,Portugal
    • Year and Date
      2011-09-05
    • Related Report
      2011 Final Research Report
  • [Presentation] Deformation and Mesogen Reorientation of Polydomain Nematic Elastomers under Electric Fields2011

    • Author(s)
      K.Urayama
    • Organizer
      The 2011 International Workshop on Physics of Poly-Domain Liquid Crystalline Elastomers
    • Place of Presentation
      Shanghai,China
    • Year and Date
      2011-06-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶/エラストマーハイブリッド材料の刺激応答特性2011

    • Author(s)
      浦山健治
    • Organizer
      ゴム技術フォーラム「ソフトマテリアルの高機能化
    • Place of Presentation
      東京
    • Year and Date
      2011-01-20
    • Related Report
      2011 Final Research Report
  • [Presentation] キラルインプリント法により作製した90度ツイスト配向液晶エラストマーリボンの形態変化と形態選択2010

    • Author(s)
      浦山健治
    • Organizer
      2010年エラストマー討論会
    • Place of Presentation
      京都
    • Year and Date
      2010-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Shape Variations of Nematic Elastomer Ribbons with Nonuniform Director Configurations2010

    • Author(s)
      Kenji Urayama
    • Organizer
      The 23rd International Liquid Crystal Conference
    • Place of Presentation
      Krakow (Poland)
    • Year and Date
      2010-07-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Shape Variations of Nematic Elastomer Ribbons with Nonuniform Director Configurations2010

    • Author(s)
      K.Urayama
    • Organizer
      The 23rd International Liquid Crystal Conference
    • Place of Presentation
      Krakow,Poland
    • Year and Date
      2010-07-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Thermal Deformations of Nematic Elastomer Ribbons with Nonuniform Director Configurations2010

    • Author(s)
      Kenji Urayama
    • Organizer
      The 5th Italian-Japanese Workshop on Liquid Crystals
    • Place of Presentation
      Cetrano (Italy)
    • Year and Date
      2010-07-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] Thermal Deformations of Nematic Elastomer Ribbons with Nonuniform Director Configurations2010

    • Author(s)
      K.Urayama
    • Organizer
      The 5th Italian-Japanese Workshop on Liquid Crystals (JILC2010)
    • Place of Presentation
      Cetrano,Italy
    • Year and Date
      2010-07-06
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶エラストマー・液晶ゲルの多様な外部刺激応答特性2009

    • Author(s)
      浦山健治
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2009-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶エラストマー・液晶ゲルの多様な外部刺激応答特性2009

    • Author(s)
      浦山健治
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      横浜市開港記念会館 (横浜市)
    • Year and Date
      2009-12-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Electro-Opto-Mechanical Effects in Liquid Crystal Elastomers and Gels2009

    • Author(s)
      浦山健治
    • Organizer
      アメリカ化学会秋季大会
    • Place of Presentation
      ワシントンDC (米国)
    • Year and Date
      2009-08-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 新しい刺激応答性ソフトマテリアル : 液晶エラストマー2009

    • Author(s)
      浦山健治
    • Organizer
      日本ゴム協会・エラストマー補強分科会
    • Place of Presentation
      大阪科学技術館 (大阪市)
    • Year and Date
      2009-07-16
    • Related Report
      2009 Annual Research Report
  • [Book] in Cross-Linked Liquid Crystalline Systems:From Rigid Polymer Networks to Elastomers,Broer,D.,Crawford,G.P.,Zumer,S.,Eds.,Taylor&Francis2011

    • Author(s)
      K. Urayama,T.Takigawa
    • Publisher
      CRC
    • Related Report
      2011 Final Research Report
  • [Book] Cross-Linked Liquid Crystalline Systems : From Rigid Polymer Networks to Elastomers, Chapter 162011

    • Author(s)
      Kenji Urayama, Toshikazu Takigawa
    • Total Pages
      12
    • Publisher
      CRC Press
    • Related Report
      2010 Annual Research Report
  • [Book] CSJ カレントレビュー01:驚異のソフトマテリアル 最新の機能性ゲル研究、第11 章 液晶ゲル2010

    • Author(s)
      浦山健治
    • Publisher
      化学同人
    • Related Report
      2011 Final Research Report
  • [Book] 驚異のソフトマテリアル 最新の機能性ゲル研究, 第11章 液晶ゲル2010

    • Author(s)
      浦山健治 (分担執筆)
    • Total Pages
      200
    • Publisher
      化学同人
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.cis.kit.ac.jp/urayama/Kenji_Urayama.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.scl.kyoto-u.ac.jp/~urayama/Kenji_Urayama.html

    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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