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Study on Time Resolved Molecular Orientation of Hydrogen-Bonding Polymers by Polarized ATR-FTIR Measurement under a Flow Field

Research Project

Project/Area Number 21350126
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionOsaka University

Principal Investigator

URAKAWA Osamu  大阪大学, 大学院・理学研究科, 講師 (70273539)

Co-Investigator(Kenkyū-buntansha) INOUE Tadashi  大阪大学, 大学院・理学研究科, 教授 (80201937)
SHIKATA Toshiyuki  大阪大学, 大学院・理学研究科, 准教授 (10178858)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2009: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Keywordsレオロジー / 水素結合 / ATR-FTIR / 高分子 / RHEO-ATR-FTIR / ポリビニルアルコール / ポリ酢酸ビニル / shear thinning / ストレスオーバーシュート / 非線形 / 分子間会合 / 分子配向 / FTIR / ATR / レオメーター
Research Abstract

We conducted linear and non-liner rheological measurements and also FTIR measurement under a shear flow for hydrogen(H) bonding polymer systems in the melts : random copolymer of vinly acetate and vinyl alcohol, P(VAc-VOH). Stress growth function of this system showed the shear thinning behavior successively to the stress overshoot. This result suggests that H-bonding structure break up under steady shear flow. However, RHEO-ATR-FTIR measurements on the same sample revealed that the number of hydrogen bonds did not change by applying flow fields. This result suggested two possibilities : small change in the number of H-bonds and/ or the structural change from inter-to intra-molecular H-bonds will be responsible for the shear thinning behavior.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (59 results)

All 2012 2011 2010 2009 Other

All Journal Article (22 results) (of which Peer Reviewed: 11 results) Presentation (35 results) Book (2 results)

  • [Journal Article] Glass Transition Temperature and Relaxation Temperature around Chain End of Polystyrene Determined by Site Specific Spin Labeling2012

    • Author(s)
      Y. Miwa, O. Urakawa, A. Doi, K. Yamamoto, S. Nobukawa
    • Journal Title

      J. Phys. Chem. B

      Volume: 116, 4 Pages: 1282-1288

    • Related Report
      2011 Final Research Report
  • [Journal Article] Glass Transition Temperature and β Relaxation Temperature around Chain End of Polystyrene Determined by Site Specific Spin Labeling2012

    • Author(s)
      Y.Miwa, O.Urakawa, A.Doi, K.Yamamoto, S.Nobukawa
    • Journal Title

      J.Phys.Chem.B

      Volume: 116 Issue: 4 Pages: 1282-1288

    • DOI

      10.1021/jp210630m

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative Dynamics in Polystyrene and Low-Mass Molecule Mixtures2011

    • Author(s)
      S. Nobukawa, O. Urakawa, T. Shikata, T. Inoue
    • Journal Title

      Macromolecules

      Volume: 44, 20 Pages: 8324-8332

    • Related Report
      2011 Final Research Report
  • [Journal Article] Dielectric and Viscoelastic Investigation of Segmental Dynamics of Polystyrene above GlassTransition Temperature : Cooperative Sequence Length and Relaxation Mode Distribution2011

    • Author(s)
      M. Matsumiya, A. Uno, H. Watanabe, T. Inoue, O. Urakawa
    • Journal Title

      Macromolecules

      Volume: 44, 11 Pages: 4355-4365

    • Related Report
      2011 Final Research Report
  • [Journal Article] Entanglement Dynamics in Miscible Polyisoprene/ Poly(p-tert-butylstyrene) Blends2011

    • Author(s)
      H. Watanabe, Q. Chen, Y. Kawasaki, Y. Matsumiya, T. Inoue, O. Urakawa
    • Journal Title

      Macromolecules

      Volume: 44, 6 Pages: 1570-1584

    • Related Report
      2011 Final Research Report
  • [Journal Article] Cooperative Dynamics in Polystyrene and Low-Mass Molecule Mixtures2011

    • Author(s)
      S.Nobukawa, O.Urakawa, T.Shikata, T.Inoue
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 20 Pages: 8324-8332

    • DOI

      10.1021/ma201719c

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric and Viscoelastic Investigation of Segmental Dynamics of Polystyrene above Glass Transition Temperature : Cooperative Sequence Length and Relaxation Mode Distribution2011

    • Author(s)
      Y.Matsumiya, A.Uno, H.Watanabe, T.Inoue, O.Urakawa
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 11 Pages: 4355-4365

    • DOI

      10.1021/ma200631p

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Entanglement Dynamics in Miscible Polyisoprene/Poly(p-tert-butyl styrene) Blends2011

    • Author(s)
      H. Watanabe, Q. Chen, Y. Kawasaki, Y. Matsumiya, T. Inoue, and O. Urakawa
    • Journal Title

      Macromolecules

      Volume: vol.44 Issue: 6 Pages: 1570-1584

    • DOI

      10.1021/ma102596b

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Miscibility and Dynamics of Poly(Vinyl Acetate)/ Poly(Methyl Glycidyl Ether) Blends2011

    • Author(s)
      A.Shimizu, N.Kuki, O.Urakawa, T.Inoue
    • Journal Title

      Journal of the Society of Materials Science, Japan

      Volume: 60 Issue: 1 Pages: 19-23

    • DOI

      10.2472/jsms.60.19

    • NAID

      130000435131

    • ISSN
      0514-5163, 1880-7488
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Entanglement Dynamics in Miscible Polyisoprene/Poly(p-tert-butylstyrene)Blends2011

    • Author(s)
      Watanabe, H.; Chen, Q.; Kawasaki, Y.; Matsumiya, Y.Inoue, T.; Urakawa, O.
    • Journal Title

      Macromolecules

      Volume: 44(in press 未定)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of High Segmental Mobility at Chain Ends of Polystyrene2010

    • Author(s)
      Y. Miwa, S. Shimada, O. Urakawa, S. Nobukawa
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 7192-7199

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Evaluation of Nematic Interaction Parameter between Polymer segments and Low-Mass Molecules in Mixtures2010

    • Author(s)
      S. Nobukawa, O. Urakawa, T. Shikata, T. Inoue
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 6099-6105

    • Related Report
      2011 Final Research Report
  • [Journal Article] 高分子に溶解した低分子のダイナミクス2010

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Journal Title

      日本レオロジー学会誌

      Volume: 38 Pages: 41-46

    • NAID

      10029818684

    • Related Report
      2011 Final Research Report
  • [Journal Article] Evaluation of Nematic Interaction Parameter between Polymer Segments and Low-Mass Molecules in Mixtures2010

    • Author(s)
      Nobukawa, S.; Urakawa, O.; Shikata, T.; Inoue, T.
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 6099-6105

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高分子融液のレオロジー挙動と分子間水素結合の関係2010

    • Author(s)
      浦川理
    • Journal Title

      ケミカルエンジニアリング

      Volume: 55 Pages: 6-10

    • Related Report
      2010 Annual Research Report
  • [Journal Article] 高分子に溶解した低分子のダイナミクス2010

    • Author(s)
      浦川理・信川省吾・四方俊幸・井上正志
    • Journal Title

      日本レオロジー学会誌 38

      Pages: 41-46

    • NAID

      10029818684

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Component dynamics in miscible polymer blends : A review of recent findings2009

    • Author(s)
      H. Wtanabe, O. Urakawa
    • Journal Title

      Korea-Australia Rheology Journal

      Volume: 21 Pages: 235-244

    • Related Report
      2011 Final Research Report
  • [Journal Article] 部分ヒドロキシメチル化によるポリスチレンとシアノビフェニル液晶の相溶性の制御2009

    • Author(s)
      信川省吾, 浦川理, 四方俊幸, 井上正志
    • Journal Title

      材料

      Volume: 58 Pages: 47-52

    • NAID

      130002085578

    • Related Report
      2011 Final Research Report
  • [Journal Article] Component dynamics in miscible polymer blends : A review of recent findines2009

    • Author(s)
      Watanabe, H.Urakawa, O.
    • Journal Title

      Korrea-Australia Rheology Journal 21

      Pages: 235-244

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 誘電緩和スペクトロスコピーによる屈曲性高分子のダイナミクスに関する研究2009

    • Author(s)
      浦川理
    • Journal Title

      低温センターだより 147

      Pages: 9-24

    • NAID

      120004845697

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 部分ヒドロキシメチル化によるポリスチレンとシアノビフェニル液晶の相溶性の制御2009

    • Author(s)
      信川省吾・浦川理・四方俊幸・井上正志
    • Journal Title

      材料 58

      Pages: 47-52

    • NAID

      130002085578

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ポリ酢酸ビニル/ポリメチルグリシジルエーテル混合系の相溶性とダイナミックス

    • Author(s)
      清水梓, 浦川理, 井上正志
    • Journal Title

      材料

      Volume: Vol.60, No.1 Pages: 19-23

    • NAID

      130000435131

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 原点となった研究2012

    • Author(s)
      浦川理
    • Organizer
      関西レオロジー研究会
    • Place of Presentation
      兵庫県神戸市神戸大学(招待講演)
    • Year and Date
      2012-03-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素結合性高分子のメモリー効果2012

    • Author(s)
      浦川理
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      神奈川静雲荘
    • Year and Date
      2012-01-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 水素結合性高分子のメモリー効果2012

    • Author(s)
      浦川理
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      神奈川県足柄下群静雲荘
    • Year and Date
      2012-01-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素結合性高分子の非線形レオロジー2011

    • Author(s)
      清水梓, 浦川理, 井上正志
    • Organizer
      レオロジー討論会
    • Place of Presentation
      群馬県桐生市市民文化会館
    • Year and Date
      2011-10-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素結合性高分子のレオロジー挙動の解析(メモリー効果)2011

    • Author(s)
      浦川理, 清水梓, 藤田美穂, 井上正志
    • Organizer
      高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-29
    • Related Report
      2011 Final Research Report
  • [Presentation] 水素結合性高分子のレオロジー挙動の解析(メモリー効果)2011

    • Author(s)
      浦川理, 清水梓, 藤田美穂, 井上正志
    • Organizer
      高分子討論会
    • Place of Presentation
      岡山市岡山大学
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 会合性高分子の非線形レオロジーと水素結合形態の関係2011

    • Author(s)
      清水梓, 浦川理, 井上正志
    • Organizer
      高分子討論会
    • Place of Presentation
      岡山市岡山大学
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] ポリ(酢酸ビニル-ビニルアルコール)共重合体を含むポリマーブレンドの相溶性とレオロジー2011

    • Author(s)
      浦川理
    • Organizer
      ポバール会
    • Place of Presentation
      京都大学
    • Year and Date
      2011-07-02
    • Related Report
      2011 Final Research Report
  • [Presentation] ポリ(酢酸ビニル-ビニルアルコール)共重合体を含むポリマーブレンドの相溶性とレオロジー2011

    • Author(s)
      浦川理
    • Organizer
      ポバール会
    • Place of Presentation
      京都市京都大学(招待講演)
    • Year and Date
      2011-07-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 会合性高分子の水素結合形態とレオロジー挙動2011

    • Author(s)
      清水梓, 浦川理, 井上正志
    • Organizer
      高分子年次大会
    • Place of Presentation
      大阪市大阪国際会議場
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子中に溶解した低分子の協同的分子運動-成分ダイナミクスの相関2011

    • Author(s)
      信川省吾, 浦川理, 井上正志, 四方俊幸
    • Organizer
      高分子年次大会
    • Place of Presentation
      大阪市大阪国際会議場
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] ポリスチレン鎖末端のダイナミクスとガラス転移2011

    • Author(s)
      浦川理, 土井章成, 信川省吾, 井上正志, 三輪洋平
    • Organizer
      レオロジー年会
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2011-05-19
    • Related Report
      2011 Final Research Report
  • [Presentation] ポリスチレン鎖末端のダイナミクスとガラス転移2011

    • Author(s)
      浦川理, 土井章成, 信川省吾, 井上正志, 三輪洋平
    • Organizer
      レオロジー年会
    • Place of Presentation
      京都市京都リサーチパーク
    • Year and Date
      2011-05-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子に溶解した低分子のダイナミックス: Nematic Interactionに関する考察2011

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      群馬KKR水上
    • Year and Date
      2011-01-30
    • Related Report
      2011 Final Research Report
  • [Presentation] 高分子に溶解した低分子のダイナミックス:Nematic Interactionに関する考察2011

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      KKR水上(群馬)
    • Year and Date
      2011-01-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Miscibility and Dynamics of Hydrogen-Bonding Polymer Blends2010

    • Author(s)
      Urakawa, O.; Fujita, M.; Shikata, T.; Inoue T.
    • Organizer
      Physical Chemistry Seminar
    • Place of Presentation
      University of Wisconsin.(USA)
    • Year and Date
      2010-11-01
    • Related Report
      2011 Final Research Report
  • [Presentation] Miscibility and Dynamics of Hydrogen-Bonding Polymer Blends2010

    • Author(s)
      Urakawa, O.; Fujita, M.; Shikata, T.; Inoue T.
    • Organizer
      Physical Chemistry Seminar
    • Place of Presentation
      University of Wisconsin(Wisconsin), (USA)
    • Year and Date
      2010-11-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rheological Behavior of Hydrogen Bonding Polymer Melts : Comparison withthe Sticky Rouse Model2010

    • Author(s)
      Urakawa, O.; Fujita, M.; Shikata, T.; Inoue T.
    • Organizer
      International Symposium on Non-Equilibrium Soft Matter
    • Place of Presentation
      NIST(USA)
    • Year and Date
      2010-10-29
    • Related Report
      2011 Final Research Report
  • [Presentation] Rheological Behavior of Hydrogen Bonding Polymer Melts : Comparison with the Sticky Rouse Model2010

    • Author(s)
      Urakawa, O.; Fujita, M.; Shikata, T.; Inoue T.
    • Organizer
      International Symposium on Non-Equilibrium Soft Matter 2010
    • Place of Presentation
      NIST (Maryland), (USA)(招待講演)
    • Year and Date
      2010-10-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子/低分子混合系の複屈折とネマチック相互作用2010

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Organizer
      高分子討論
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 高分子/低分子混合系の複屈折とネマチック相互作用2010

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Organizer
      高分子討論会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Effect of Intermolecular Hydrogen Bonds on Rheological Behavior in Polymer Melts2010

    • Author(s)
      Urakawa, O.; Fujita, M.; Shikata, T.; Inoue T.
    • Organizer
      Pacific Rim Conference on Rheology
    • Place of Presentation
      Hokkaido University
    • Year and Date
      2010-08-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Effect of Intermolecular Hydrogen Bonds on Rheological Behavior in Polymer Melts2010

    • Author(s)
      Urakawa, O.; Fujita, M.; Shikata, T.; Inoue T.
    • Organizer
      Pacific Rim Conference on Rheology 2010
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-08-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水素結合する高分子のレオロジー:スティッキーラウスモデルとの比較2010

    • Author(s)
      浦川理, 藤田美穂, 生田博義, 四方俊幸, 井上正志
    • Organizer
      レオロジー年会
    • Place of Presentation
      東京大学
    • Year and Date
      2010-05-14
    • Related Report
      2011 Final Research Report
  • [Presentation] 水素結合する高分子のレオロジー:スティッキーラウスモデルとの比較2010

    • Author(s)
      浦川理, 藤田美穂, 生田博義, 四方俊幸, 井上正志
    • Organizer
      レオロジー年次大会
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2010-05-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] 会合性高分子のレオロジー2010

    • Author(s)
      浦川理
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      ウェルサンピア新潟
    • Year and Date
      2010-01-30
    • Related Report
      2011 Final Research Report
  • [Presentation] 会合性高分子のレオロジー2010

    • Author(s)
      浦川理
    • Organizer
      高分子基礎研究会
    • Place of Presentation
      ウェルサンピア新潟(新潟)
    • Year and Date
      2010-01-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Dynamics of polymer/ low mass molecule mixtures2009

    • Author(s)
      Urakawa, O., Fujita M., Ikuta H, Shikata T., Inoue T.
    • Organizer
      Osaka University Macromolecular Symposium
    • Place of Presentation
      Osaka University
    • Year and Date
      2009-12-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Dynamics of polymer/low mass molecule mixtures2009

    • Author(s)
      浦川理
    • Organizer
      Osaka University Macromolecular Symposium
    • Place of Presentation
      大阪大学(大阪)
    • Year and Date
      2009-12-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高分子/低分子混合系のダイナミクスに関する分子サイズの効果2009

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Organizer
      レオロジー討論会
    • Place of Presentation
      宇部全日空ホテル
    • Year and Date
      2009-10-05
    • Related Report
      2011 Final Research Report
  • [Presentation] 高分子/低分子混合系のダイナミクスに関する分子サイズの効果2009

    • Author(s)
      浦川理
    • Organizer
      レオロジー討論会
    • Place of Presentation
      宇部全日空ホテル(山口)
    • Year and Date
      2009-10-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高分子/低分子混合系のダイナミクスに関する協同性と階層性2009

    • Author(s)
      浦川理, 信川省吾, 四方俊幸, 井上正志
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 高分子/低分子混合系のダイナミクスに関する協同性と階層性2009

    • Author(s)
      浦川理
    • Organizer
      高分子討論会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水素結合性高分子ブレンドの相溶性と分子運動特性2009

    • Author(s)
      浦川理
    • Organizer
      東海高分子研究会
    • Place of Presentation
      長良川観光ホテル石金
    • Year and Date
      2009-09-05
    • Related Report
      2011 Final Research Report
  • [Presentation] 水素結合性高分子ブレンドの相溶性と分子運動特性2009

    • Author(s)
      浦川理
    • Organizer
      東海高分子研究会
    • Place of Presentation
      長良川観光ホテル石金(岐阜)
    • Year and Date
      2009-09-05
    • Related Report
      2009 Annual Research Report
  • [Book] ナノポリマーアロイの相溶性と混練条件の最適化,第2章,第4節ポリマーアロイにおける相図の書き方と活かし方2010

    • Author(s)
      浦川理
    • Publisher
      技術情報協会
    • Related Report
      2011 Final Research Report
  • [Book] ナノポリマーアロイの相溶化と混練条件の最適化(第2章, 第4節)2010

    • Author(s)
      浦川理, 他31名
    • Publisher
      技術情報協会
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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