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Measurement and control of charge transfer between organic ultrathin layers and substrates by means of in-situ real-time spectroscopy

Research Project

Project/Area Number 21360020
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionYokohama National University

Principal Investigator

TANAKA Masatoshi  横浜国立大学, 工学研究院, 教授 (90130400)

Co-Investigator(Kenkyū-buntansha) OHNO Shin-ya  横浜国立大学, 工学研究院, 特別研究教員 (00377095)
OHNO Kaoru  横浜国立大学, 工学研究院, 教授 (40185343)
YOKOYAMA Takashi  横浜市立大学, 生命ナノシステム研究科, 教授 (80343862)
YASUDA Tetuji  産業技術総合研究所, ナノエレクトロニクス部門, 研究員(部門付) (90220152)
SUZUKI Takanori  防衛大学校, 応用物理学科, 教授 (60124369)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2009: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Keywords表面・界面物性 / 光物性 / 超薄膜 / マイクロ・ナノデバイス / 超分子化学
Research Abstract

Physical properties of chemically modified silicon surfaces and the orientations ofα-sexithiophene molecules in the ultrathin overlayers were investigated by means of in-situ real-time surface reflectance spectroscopy and photoelectron spectroscopy. The relationship between the orientation and the charge transfer between molecules and substrates has been clarified. The charge transfer remarkably depends on the surface modification, which means the orientation of molecules can be controlled by the modification and substrate temperature.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (33 results)

All 2012 2011 2010 2009

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (26 results)

  • [Journal Article] Enhanced silicon oxidation on titanium-covered Si(001)2011

    • Author(s)
      S. Ohno, K. Shudo, F. Nakayama, K. Yamazaki, Y. Ichikawa, M. Tanaka, T. Okuda, A. Harasawa, I. Matsuda and A. Kakizaki
    • Journal Title

      J. Phys.: Condens. Matter

      Volume: 23

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Vacuum-ultraviolet reflectance difference spectroscopy for characterizing dielectrics-semiconductor interfaces2011

    • Author(s)
      S. Ogata, S. Ohno, M. Tanaka, T. Mori, T. Horikawa and T. Yasuda
    • Journal Title

      Thin Solid Films

      Volume: 519 Pages: 2830-2833

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced silicon oxidation on titanium-covered Si(001)2011

    • Author(s)
      S.Ohno, K.Shudo, F.Nakayama, K.Yamazaki, Y.Ichikawa, M.Tanaka, T.Okuda, A.Harasawa, I.Matsuda, A.Kakizaki
    • Journal Title

      J.Phys. : Condens.Matter

      Volume: 23 Issue: 30 Pages: 305001-305001

    • DOI

      10.1088/0953-8984/23/30/305001

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SiO^2/Si interfaces on high-index surfaces : Re-evaluation of trap densities and characterization of bonding structures2011

    • Author(s)
      S.Ogata, S.Ohno, M.Tanaka, T.Mori, T.Horikawa, T.Yasuda
    • Journal Title

      Applied Physics Letters

      Volume: 98

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction kinetics in the rapid oxide growth on Si(001)-(2x1) probed with reflectance difference spectroscopy2010

    • Author(s)
      S.Ohno, T.Ochiai, M.Morimoto, T. Suzuki, K.Shudo, M.Tanaka
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge separation dynamics at molecular heterojunction of C60 and zinc phthalocyanine2010

    • Author(s)
      Y.Kodama, K.Ohno
    • Journal Title

      Applied Physics Letters 96

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reflectance Difference Spectroscopy in Vacuum-Ultraviolet Range : Developing Measurement System and Applying to Characterization of SiO_2/Si Interfaces2010

    • Author(s)
      S.Ogata, S.Ohno, M.Tanaka, T.Horikawa, T.Yasuda
    • Journal Title

      Japanese Journal of Applied Physics 49

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 表面修飾Si(001)表面上のα-sexithiophene分子の構造と電子状態2012

    • Author(s)
      平賀健太, 豊島弘明, 大野真也, 小澤健一, 間瀬一彦, 向井孝三, 吉信淳, 田中正俊
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学,兵庫
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 超音速分子線を用いたSi高指数面初期酸化過程の解析II2012

    • Author(s)
      大野真也, 兼村瑠威, 安部壮祐, 井上慧, 百瀬辰哉, 吉越章隆, 寺岡有殿, 尾形祥一, 安田哲二, 田中正俊
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学,東京
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Si高指数面熱酸化過程における温度依存性の解析2012

    • Author(s)
      安部壮祐, 大野真也, 兼村瑠威, 吉越章隆, 寺岡有殿, 尾形祥一, 安田哲二, 田中正俊
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学,東京
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] 超音速分子線を用いたSi初期酸化促進反応における面方位依存性の解析2012

    • Author(s)
      大野真也, 井上慧, 百瀬辰哉, 兼村瑠威, 吉越章隆, 寺岡有殿, 尾形祥一, 安田哲二, 田中正俊
    • Organizer
      第25回日本放射光学会年会放射光科学合同シンポジウム
    • Place of Presentation
      鳥栖市民文化会館・中央公民館,佐賀
    • Year and Date
      2012-01-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面修飾Si(001)表面上のα-sexithiophene分子の構造と電子状態2012

    • Author(s)
      平賀健太,豊島弘明,大野真也,小澤健一,間瀬一彦,向井孝三,吉信淳,田中正俊
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Final Research Report
  • [Presentation] Real-time measurement of hydrogen adsorption process on Si(113) by means of reflectance difference spectroscopy2011

    • Author(s)
      S.Abe, S.Ohno, T.Suzuki, M.Tanaka
    • Organizer
      6 th International Symposium on Surface Science
    • Place of Presentation
      タワーホール船堀,東京
    • Year and Date
      2011-12-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面修飾Si(001)表面上のα-sexitiophene分子の吸着構造の解析2011

    • Author(s)
      豊島弘明, 井上慧, 大野真也, 向井孝三, 吉信淳, 横山崇, 田中正俊
    • Organizer
      表面・界面スペクトロスコピー2011
    • Place of Presentation
      マホロバマインズ三浦,神奈川
    • Year and Date
      2011-12-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面修飾Si(001)表面上のα-sexthiophene分子の構造と電子状態の解析2011

    • Author(s)
      豊島弘明, 井上慧, 向井孝三, 吉信淳, 大野真也, 横山崇, 田中正俊
    • Organizer
      第52回真空に関する連合講演会
    • Place of Presentation
      学習院大学
    • Year and Date
      2011-11-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面修飾Si(001)表面上のオリゴチオフェン分子の構造と電子状態2011

    • Author(s)
      豊島弘明, 井上慧, 大野真也, 向井孝三, 吉信淳, 横山崇, 田中正俊
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Si(113)表面上におけるH原子吸着過程のリアルタイム計測2011

    • Author(s)
      安部壮祐, 大野真也, 鈴木隆則, 田中正俊
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 超音速分子線を用いたSi高指数面初期酸化過程の解析2011

    • Author(s)
      大野真也, 井上慧, 百瀬辰哉, 兼村瑠威, 吉越章隆, 寺岡有殿, 尾形祥一, 安田哲二, 田中正俊
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面反射分光によるSi(001)表面上のα-sexithiophene分子配列構造の解析2011

    • Author(s)
      豊島弘明,井上彗,大野真也,横山崇,田中正俊
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] オリゴチオフェン超薄膜成長過程とSi表面終端構造との相関2010

    • Author(s)
      豊島弘明, 新江定憲, 大野真也, 横山崇, 鈴木隆則, 田中正俊
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水吸着Si(100)表面における酸化促進反応の解析2010

    • Author(s)
      新江定憲, 豊島弘明, 大野真也, 鈴木隆則, 田中正俊
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Real-time optical measurement of a-sexithiophene adsorption processes onmodified Si(001)-(2xl) surfaces2010

    • Author(s)
      H.Toyoshima, S.Ohno, T.Yokoyama, M.Tanaka
    • Organizer
      18^<th> Int.Vacuum Congress
    • Place of Presentation
      北京(中国)
    • Year and Date
      2010-08-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Vacuum-Ultraviolet Reflectance Difference Spectroscopy for Characterizing Dielectrics-Semiconductor Interfaces2010

    • Author(s)
      S.Ogata, S.Ohno, M.Tanaka, T.Mori, T.Horikawa, T.Yasuda
    • Organizer
      5th Int.Conf.Spectroscopic Ellipsometry (ICSE-V)
    • Place of Presentation
      アルバニー(アメリカ)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Temperature dependence of monolayer oxide growth processes on Si(001)-(2x1) studied with optical reflectance spectroscopic methods2010

    • Author(s)
      S.Ohno, F.Mitobe, J.Koizumi, T.Suzuki, K.Shudo, M.Tanaka
    • Organizer
      5th Int.Conf.Spectroscopic Ellipsometry (ICSE-V)
    • Place of Presentation
      アルバニー(アメリカ)
    • Year and Date
      2010-05-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Si高指数面上に形成した酸化膜における界面準位密度の再検討2010

    • Author(s)
      尾形祥一, 大野真也, 田中正俊, 森貴洋, 堀川剛, 安田哲二
    • Organizer
      ゲートスタック研究会 (第15回研究会)
    • Place of Presentation
      東レ総合研修センター
    • Year and Date
      2010-01-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] Real-time optical measurement ofα-sexithiophene adsorption processes on modified Si(001)-(2x1) surfaces2010

    • Author(s)
      H. Toyoshima, S. Ohno, T. Yokoyama and M. Tanaka
    • Organizer
      18th International Vacuum Congress
    • Place of Presentation
      Beijing, China
    • Related Report
      2011 Final Research Report
  • [Presentation] Si(111)-(√3×√3)-Ag表面上に配列したオリゴチオフェン分子の低温STM観察2009

    • Author(s)
      浅利友隆, 横山崇, 大野真也, 田中正俊
    • Organizer
      第50回真空に関する連合講演会
    • Place of Presentation
      学習院大学
    • Year and Date
      2009-11-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] オリゴチオフェン超薄膜成長過程における配向変化の解析2009

    • Author(s)
      井上慧, 脇田創, 浅利友隆, 西山文貴, 横山崇, 大野真也, 田中正俊
    • Organizer
      第50回真空に関する連合講演会
    • Place of Presentation
      学習院大学
    • Year and Date
      2009-11-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] Si(111)-(√3×√3)-Ag表面上に配列したオリゴチオフェン分子のSTM観察2009

    • Author(s)
      浅利友隆, 横山崇, 大野真也, 田中正俊
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] オリゴチオフェン超薄膜成長過程の表面差分反射分光による解析2009

    • Author(s)
      井上慧, 脇田創, 浅利友隆, 西山文貴, 横山崇, 大野真也, 田中正俊
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 有機分子蒸着源の作製と表面差分反射分光による In-situ 成膜評価2009

    • Author(s)
      脇田創, 井上慧, 大野真也, 田中正俊
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Si高指数面上に形成したSiO2界面の真空紫外RDS評価 : ウエット酸化とドライ酸化の比較2009

    • Author(s)
      尾形祥一, 大野真也, 田中正俊, 堀川剛, 安田哲二
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] In-situ real-time observation of α-sexithiophene thin film formation by surface differential reflectance spectroscopy2009

    • Author(s)
      M.Tanaka, S.Wakita, S.Ohno, K.Inoue, T.Asari, F.Nishiyama, T.Yokoyama
    • Organizer
      European Conference on Surface Science 26
    • Place of Presentation
      パルマ (イタリア)
    • Year and Date
      2009-08-31
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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