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Giant isotope effect on phonon and carrier in semiconductor diamond

Research Project

Project/Area Number 21360155
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

WATANABE Hideyuki  独立行政法人産業技術総合研究所, ダイヤモンド研究ラボ, 主任研究員 (50392684)

Co-Investigator(Renkei-kenkyūsha) NAKASHIMA Shinich  独立行政法人産業技術総合研究所, 先進パワーエレクトロニクス研究センター, 客員研究員 (20029226)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥14,300,000 (Direct Cost: ¥11,000,000、Indirect Cost: ¥3,300,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2010: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2009: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords電気・電子材料 / ダイヤモンド / 同位体効果 / 同位体 / 超格子 / バンドエンジニアリング / カソードルミネッセンス / ラマン散乱 / 摩擦 / 弾性率 / CVD / エキシトン
Research Abstract

We succeeded in synthesizing a stack of alternating, nano-meter thick layers of isotopically enriched^<12> C and^<13> C diamonds using microwave plasma-assisted CVD with isotopically enriched methane gases. We suggested the feasibility of synthesizing a diamond superlattice comprising very thin diamond layers whose well width is as small as 1 nm. We also found that the carriers are confined due to the band gap difference in the homojunction interface. The possibility has been raised that the confinement of phonons also occurs in the isotopic diamond superlattice. We found that, currently, isotopic diamonds have a possibility to provide an effective means for facilitating the band engineering of diamond.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (44 results)

All 2012 2011 2010 2009

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (32 results) Book (1 results)

  • [Journal Article] Optical and Spin Coherence Properties of Nitrogen-Vacancy Centers Placed in a 100 nm Thick Isotopically Purified Diamond Layer2012

    • Author(s)
      Toyofumi Ishikawa, Kai-Mei C. Fu, Charles Santori, Victor M. Acosta, Raymond G. Beausoleil, Hideyuki Watanabe, Shinichi Shikata, and Kohei M. Itoh
    • Journal Title

      Nano Lett.

      Volume: 12 Issue: 4 Pages: 2083-2087

    • DOI

      10.1021/nl300350r

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optical and Spin Coherence Properties of Nitrogen-Vacancy Centers Placed in a 100nm Thick Isotopically Purified Diamond Layer2012

    • Author(s)
      Toyofumi Ishikawa, Kai-Mei C. Fu, Charles Santori, Victor M. Acosta, Raymond G. Beausoleil, Hideyuki Watanabe, Shinichi Shikata, Kohei M. Itoh
    • Journal Title

      Nano Lett.

      Volume: 12 Pages: 2083-2087

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superlattice structures from diamond2011

    • Author(s)
      H. Watanabe and S. Shikata
    • Journal Title

      Diamond and Related Materials

      Volume: 20 Issue: 7 Pages: 980-982

    • DOI

      10.1016/j.diamond.2011.05.015

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Superlattices from diamond2010

    • Author(s)
      渡邊幸志
    • Journal Title

      MRS symposium Proceedings

      Volume: 1203 Pages: 29-34

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superlattices from diamond2009

    • Author(s)
      H. Watanabe
    • Journal Title

      MRS symposium Proceedings

      Volume: 1203 Pages: 29-34

    • URL

      http://dx.doi.org/10.1557/PROC-1203-J13-04

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Coherence of single spins coupled to a nuclear spin bath of varying density2009

    • Author(s)
      N. Mizuochi, P. Neumann, F. Rempp, J. Beck, V. Jacques, P. Siyushev, K. Nakamura, D. J. Twitchen, H. Watanabe, S. Yamasaki, F. Jelezko, J. Wrachtrup
    • Journal Title

      PHYSICAL REVIEW B

      Volume: 80 Issue: 4

    • DOI

      10.1103/physrevb.80.041201

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Isotopic Homojunction Band Engineering from Diamond2009

    • Author(s)
      H. Watanabe、C. E. Nebel、S. Shikata
    • Journal Title

      SCIENCE

      Volume: 324 Issue: 5933 Pages: 1425-1428

    • DOI

      10.1126/science.1172419

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Growth and Characteristics of Diamond Grown by Microwave Plasma Assisted CVD2009

    • Author(s)
      H. Watanabe
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 52 Pages: 351-363

    • NAID

      10025184815

    • URL

      http://dx.doi.org/10.3131/jvsj2.52.351

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Growth and Characteristics of Diamond Grown by Microwave Plasma Assisted CVD2009

    • Author(s)
      H.Watanabe
    • Journal Title

      Journal of the Vacuum Society of Japan 52

      Pages: 351-363

    • NAID

      10025184815

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isotopic Homojunction Band Engineering from Diamond2009

    • Author(s)
      H.Watanabe, C.E.Nebel, S.Shikata
    • Journal Title

      SCIENCE 324

      Pages: 1425-1428

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coherence of single spins coupled to a nuclear spin bath of varying density2009

    • Author(s)
      N.Mizuochi, P.Neumann, F.Rempp, J.Beck, V.Jacques, P.Siyushev, K.Nakamura, D.J.Twitchen, H.Watanabe, S.Yamasaki, F.Jelezko, J.Wrachtrup
    • Journal Title

      PHYSICAL REVIEW B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 同位体ダイヤモンド超格子のラマン散乱2012

    • Author(s)
      渡邊幸志、富田卓朗、中島信一、加藤有香子、鹿田真一
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 同位体ダイヤモンド超格子からのラマン散乱2011

    • Author(s)
      渡邊幸志、富田卓朗、中島信一、加藤有香子、鹿田真一
    • Organizer
      第25回ダイヤモンドシンポジウム
    • Place of Presentation
      産業技術総合研究所(茨城)
    • Year and Date
      2011-12-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 同位体ダイヤモンド超格子からのラマン散乱2011

    • Author(s)
      渡邊幸志、富田卓朗、中島信一、加藤有香子、鹿田真一
    • Organizer
      第25回 ダイヤモンドシンポジウム
    • Place of Presentation
      産業技術総合研究所(茨城)
    • Year and Date
      2011-12-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] オフ角制御高圧高温合成IIa型基板上へのCVD単結晶ダイヤモンドの合成と電荷収集効率およびμτ積の測定2011

    • Author(s)
      今野雄太, 金子純一, 佐竹良太, 後藤拓人, 西紀彦, 藤田文行, 渡邊幸志, 茶谷原昭義, 梅澤仁, 坪内信輝, 鹿田真一, 磯辺光孝
    • Organizer
      日本原子力学会2011年秋の大会
    • Place of Presentation
      北九州国際会議場(福岡)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] Single NV centers in isotopically control led diamond films2011

    • Author(s)
      K. M. Itoh, T. Ishikawa, K. -M. C. Fu, C. Santori, P. E. Barclay, R. G. Beausoleil, R. Hirano, M. Tajima, H. Watanabe, S. Shikata
    • Organizer
      22nd European Conference on Diamond, Diamond-Like Materials, Carbon Nanotubes and Nitrides
    • Place of Presentation
      Gamisch-Partenkirchen, Bavaria, Gemany
    • Year and Date
      2011-09-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] 究極の半導体材料:ダイヤモンド2011

    • Author(s)
      渡邊幸志
    • Organizer
      VACUUM2011真空展
    • Place of Presentation
      東京ビッグサイト(東京)
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Nitrogen-vacancy centers in an isotopically controlled 12C diamond layer2011

    • Author(s)
      T. Ishikawa, K. -M. C. Fu, C. Santori, H. Watanabe, R. G. Beausoleil, S. Shikata, K. M. Itoh
    • Organizer
      6th International School and Conference on Spintronics and Quntum Information Technology
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2011-08-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] Luminescence behavior of nitrogen-doped homoepitaxial single crystal diamond by microwave plasma-assisted2011

    • Author(s)
      H. Watanabe, R. Hirano, K. Itoh, M. Tajima, S. Shikata
    • Organizer
      International Conference on New Diamond and Nano Carbons 2011
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2011-05-19
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Influence of Growth Conditions on Charge Carrier Transport Characteristics and Measurement of 14 MeV Neutron Response Function Influence of Growth Conditions on Charge Carrier Transport Characteristics and Measurement of 14 MeV Neutron Response Function2011

    • Author(s)
      F. Fujita, J. Kaneko, N. Tsubouchi, A. Kakimoto, K. Sato, Y. Konno, A. Chayahara, Y. Mokuno, H. Watanabe, S. Shikata, S. Sato.
    • Organizer
      International Conference on New Diamond and Nano Carbons 2011
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2011-05-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Growth and evaluation of self-standing CVD diamond single crystals on off-axis (001) surface of HP/HT type IIa substrates2011

    • Author(s)
      J. Kaneko, F. Fujita, Y. Konno, T. Gotoh, N. Nishi, H. Watanabe, A. Chayahara, H. Umezawa, N. Tsubouchi, S. Shikata, M. Isobe
    • Organizer
      International Conference on New Diamond and Nano Carbons 2011
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2011-05-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] オフ角制御IIa型ダイヤモンド基板を使用したCVD単結晶ダイヤモンド自立膜の合成と評価2010

    • Author(s)
      今野雄太、後藤拓人、金子純一、藤田文行、西紀彦、梅澤仁、渡邊幸志、茶谷原昭義、坪内信輝、鹿田真一
    • Organizer
      日本原子力学会北海道支部第28回研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-12-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] 同位体ダイヤモンドによるキャリアの閉じ込め2010

    • Author(s)
      渡邊幸志、鹿田真一
    • Organizer
      第24回ダイヤモンドシンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2010-11-18
    • Related Report
      2011 Final Research Report
  • [Presentation] 同位体ダイヤモンドによるキャリアの閉じ込め2010

    • Author(s)
      渡邊幸志、鹿田真一
    • Organizer
      第24回ダイヤモンドシンポジウム
    • Place of Presentation
      東京工業大学 大岡山キャンパス
    • Year and Date
      2010-11-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] オフ角制御IIa型ダイヤモンド基板を使用したCVD単結晶ダイヤモンド自立膜の合成と評価2010

    • Author(s)
      金子純一、後藤拓人、藤田文行、梅澤仁、渡邊幸志、茶谷原昭義、坪内信輝、鹿田真一
    • Organizer
      第24回ダイヤモンドシンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 合成条件と使用基板がホモエピタキシャルCVD単結晶ダイヤモンドの電荷キャリア輸送特性に与える影響2010

    • Author(s)
      金子純一、垣本明徳、今野雄太、藤田文行、後藤拓人、内信輝、杢野由明、茶谷原昭義、梅澤仁、渡邊幸志、鹿田真一
    • Organizer
      第24回ダイヤモンドシンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of nitrogen-doped homoepitaxial single crystal diamond by microwave plasma-assisted chemical vapor deposition2010

    • Author(s)
      H. Watanabe
    • Organizer
      Artificial atoms in diamond
    • Place of Presentation
      Cambridege, MA, USA
    • Year and Date
      2010-11-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of nitrogen-doped homoepitaxial single crystal diamand by microwave plasma-assisted chemical vapor deposition2010

    • Author(s)
      渡邊幸志
    • Organizer
      Artificial atoms in diamond
    • Place of Presentation
      Cambridege, MA, USA
    • Year and Date
      2010-11-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] 同位体ダイヤモンドによるキャリアの閉じ込め2010

    • Author(s)
      渡邊幸志、鹿田真一
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2010-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Superlattices from diamond2010

    • Author(s)
      H. Watanabe
    • Organizer
      21st European Conference on Diamond, Diamond-Like Materials, Carbon Nanotubes, and Nitrides
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-09-15
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 同位体ダイヤモンドによるキャリアの閉じ込め2010

    • Author(s)
      渡邊幸志、鹿田真一
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学 文教キャンパス
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 合成条件と使用基板がホモエピタキシャルCVD単結晶ダイヤモンドの電荷キャリア輸送特性に与える影響2010

    • Author(s)
      垣本明徳、今野雄太、金子純一、藤田文行、後藤拓人、本間彰、古坂道弘、坪内信輝、杢野由明、茶谷原昭義、梅澤仁、渡邊幸志、鹿田真一
    • Organizer
      日本原子力学会2010年秋の大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 材料の王様:ダイヤモンド!2010

    • Author(s)
      渡邊幸志
    • Organizer
      VACUUM2010-真空展
    • Place of Presentation
      東京ビッグサイト東京国際展示場
    • Year and Date
      2010-09-01
    • Related Report
      2011 Final Research Report
  • [Presentation] 材料の王様:ダイヤモンド!2010

    • Author(s)
      渡邊幸志
    • Organizer
      VACUUM2010-真空展
    • Place of Presentation
      東京ビッグサイト 東京国際展示場
    • Year and Date
      2010-09-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] Homojunction band engineering using isotope diamond2010

    • Author(s)
      H. Watanabe、S. Shikata
    • Organizer
      30th International Conference on the Physics of Semiconductors
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2010-07-29
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Charge carrier confinement in diamond superlattices2010

    • Author(s)
      H. Watanabe
    • Organizer
      SBDD XV
    • Place of Presentation
      Hasselt, Belgium
    • Year and Date
      2010-02-23
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Superlattices from diamond2009

    • Author(s)
      H. Watanabe
    • Organizer
      2009MRS fall meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2009-12-03
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] ダイヤモンドを用いた同位体ホモ接合バンドエンジニアリング2009

    • Author(s)
      渡邊幸志、鹿田真一
    • Organizer
      ダイヤモンドシンポジウム
    • Place of Presentation
      千葉工業大学
    • Year and Date
      2009-11-18
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 12Cと13C同位体ホモエピタキシャルダイヤモンド薄膜からのカソードルミネッセンス(V)2009

    • Author(s)
      渡邊幸志、鹿田真一
    • Organizer
      応用物理学会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-10
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 12Cと13C同位体ホモエピタキシャルダイヤモンド薄膜からのカソードルミネッセンス(IV)2009

    • Author(s)
      渡邊幸志、鹿田真一
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-10
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 同位体ダイヤモンド2009

    • Author(s)
      渡邊幸志
    • Organizer
      グローバルCOE「ナノサイエンスを拓く量子物理学拠点」
    • Place of Presentation
      東京工業大学
    • Year and Date
      2009-06-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Cathodoluminescence study of 12C/13C diamond multi-layered films2009

    • Author(s)
      H. Watanabe, S. Shikata
    • Organizer
      New Diamond and Nano Carbons Conference(NDNC2009)
    • Place of Presentation
      Traverse City, Michigan USA
    • Year and Date
      2009-06-11
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 12Cと13C同位体ホモエピタキシャルダイヤモンド薄膜からのカソードルミネッセンス(III)2009

    • Author(s)
      渡邊幸志、中島信一、鹿田真一
    • Organizer
      応用物理学会
    • Place of Presentation
      筑波大学
    • Year and Date
      2009-04-01
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Book] NEW DIAMOND100 Vol.27 2050年のダイヤモンド将来展望6.ダイヤモンドを用いた量子ネットワークの構築2011

    • Author(s)
      水落憲和、渡邊幸志
    • Publisher
      株式会社オーム社
    • Related Report
      2011 Final Research Report 2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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