| Project/Area Number |
21360369
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Metal making engineering
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| Research Institution | Kyoto University |
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Principal Investigator |
MURASE Kuniaki 京都大学, 大学院・工学研究科, 教授 (30283633)
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| Co-Investigator(Kenkyū-buntansha) |
SUGIMURA Hiroyuki 京都大学, 大学院・工学研究科, 教授 (10293656)
ICHII Takashi 京都大学, 大学院・工学研究科, 助教 (30447908)
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| Co-Investigator(Renkei-kenkyūsha) |
SAKAGUCHI Hiroki 鳥取大学, 大学院・工学研究科, 教授 (00202086)
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| Research Collaborator |
YANASE Kozo 京都大学, 大学院・工学研究科, 修士
FUKUDA Naoki 京都大学, 大学院・工学研究科, 修士
SHUTO Toshiya 京都大学, 工学部, 学生
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2009: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
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| Keywords | イオン液体 / 還元拡散 / 合金形成 / リチウムイオン電池 / 負極材料 / 薄膜 / 黄銅 / めっき / サイクル特性 / 室温溶融塩 / 常温溶融塩 / 電析 |
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| Research Abstract |
Layers of Cu-Sn intermetallic compounds were formed by cathodic elec-trochemical alloying of electroless Cu layers with Sn using an ionic liqui bath containing Sn2+ ions at 150°C. The technique is called "reduction-diffusion(RD)" and the intermetallics formed(i. e. Cu6Sn5 and Cu3Sn) were dependent on the alloying potential. In the present work, we investigated the perfor-mance of the Cu6Sn5 layer as an anode of Li-ion battery. The formation of brass(Cu-Zn alloy) layers was also examined and it was found that Cu-Zn phases, i. e. y-Cu5Zn8, 13'-CuZn, and/or a-Cu(Zn), which define the color of the layers, were dependent on applied potential during the alloying.
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