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Research for tocotrienol recovery and biodiesel production from waste rice bran oil

Research Project

Project/Area Number 21360373
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTohoku University

Principal Investigator

YONEMOTO Toshikuni  東北大学, 大学院・工学研究科, 教授 (40125688)

Co-Investigator(Kenkyū-buntansha) SHIBASAKI Kitakawa naomi  東北大学, 大学院・工学研究科, 准教授 (00261503)
KUBO Masaki  東北大学, 大学院・工学研究科, 准教授 (50323069)
NAMASHIMA Kazunori  東北大学, 大学院・工学研究科, 助教 (50540358)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2009: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Keywordsイオン交換樹脂 / エステル化反応 / エステル交換反応 / 吸着脱離 / バイオディーゼル燃料 / ビタミンE類 / エステル化 / 脂肪酸エステル
Research Abstract

The purpose of this research is to construct a novel reaction and separation process for producing bioactive compounds, tocotrienol (vitamin E), and renewable energy, high quality biodiesel, from waste oils discharged in the vegetable oil refining process. The process consists of the esterification of free fatty acid using cation-exchange resin catalyst, the adsorption of tocotrienol on the anion-exchange resin, the desorption of tocotrienol from the resin and the transesterification of triglyceride using anion-exchange resin catalyst. The optimal conditions for continuous operation in each step were investigated and elucidated.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (28 results)

All 2012 2011 2010 2009

All Journal Article (7 results) (of which Peer Reviewed: 6 results) Presentation (19 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] A Kinetic Model Describing Antioxidation and Prooxidation of .-Carotene in the Presence of .-Tocopherol and Ascorbic Acid2011

    • Author(s)
      N. Shibasaki-Kitakawa, M. Murakami, M. Kubo, T. Yonemoto
    • Journal Title

      Journal of the American Oil Chemists' Society

      Volume: 89 Issue: 5 Pages: 815-824

    • DOI

      10.1007/s11746-011-1980-z

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Biodiesel Production form Waste Cooking Oil Using Anion-Exchange Resin as Both Catalyst and Adsorbent2011

    • Author(s)
      N. Shibasaki-Kitakawa, T. Tsuji, M. Kubo, T. Yonemoto
    • Journal Title

      Bioenergy Research

      Volume: Vol.4, No.4 Pages: 287-293

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Biodiesel Production form Waste Cooking Oil Using Anion-Exchange Resin as Both Catalyst and Adsorbent2011

    • Author(s)
      N.Shibasaki-Kitakawa, T.Tsuji, M.Kubo, T.Yonemoto
    • Journal Title

      Bioenergy Research

      Volume: 4(4) Issue: 4 Pages: 287-293

    • DOI

      10.1007/s12155-011-9148-0

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] イオン交換樹脂触媒を用いた新規なバイオディーゼル燃料製造技術の開発2010

    • Author(s)
      北川尚美、米本年邦
    • Journal Title

      化学工学

      Volume: Vol.74 Pages: 164-167

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Simple continuous production process of biodiesel fuel from oil with high content of free fatty acid using ion-exchange resin catalysts2010

    • Author(s)
      N. Shibasaki-Kitakawa, T. Tsuji, K. Chida, M. Kubo, T. Yonemoto
    • Journal Title

      Energy & Fuels

      Volume: Vol.24, No.6 Pages: 3634-3638

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simple continuous production process of biodiesel fuel from oil with high content of free fatty acid using ion-exchange resin catalysts2010

    • Author(s)
      N.Shibasaki-Kitakawa, T.Tsuji, K.Chida, M.Kubo, T.Yonemoto
    • Journal Title

      Energy & Fuels

      Volume: 24 Pages: 3634-3638

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Is Excess Methanol Addition Required To Drive Transesterification of Triglyceride toward Complete Conversion?2009

    • Author(s)
      T. Tsuji, M. Kubo, N. Shibasaki-Kitakawa, T. Yonemoto
    • Journal Title

      Energy & Fuels

      Volume: Vol.23, No.12 Pages: 6163-6167

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] イオン交換樹脂を触媒・吸着剤とした高品質バイオディーゼル燃料合成法2012

    • Author(s)
      金川恵一、中島一紀、北川尚美、米本年邦
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学(東京)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Final Research Report
  • [Presentation] イオン交換樹脂を触媒・吸着剤とした高品質バイオディーゼル燃料合成法2012

    • Author(s)
      金川恵一, 中島一紀, 北川尚美, 米本年邦
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学新宿キャンパス,東京
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 廃棄バイオマスを原料とした高品質バイオディーゼル燃料製造技術の開発2011

    • Author(s)
      北川尚美、米本年邦
    • Organizer
      INCHEM TOKYO産学官マッチングフォーラム
    • Place of Presentation
      東京ビッグサイト(東京)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 廃棄バイオマスを原料とした高品質バイオディーゼル燃料製造技術の開発2011

    • Author(s)
      北川尚美, 米本年邦
    • Organizer
      INCHEM TOKYO産学官マッチングフォーラム
    • Place of Presentation
      東京ビッグサイト,東京
    • Year and Date
      2011-11-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] High Quality Biodiesel Fuel Production from Crude Jatropha Oil without Upstream and Downstream Processing2011

    • Author(s)
      N. Shibasaki-Kitakawa, K. Kanagawa, K. Nakashima, T. Yonemoto
    • Organizer
      2011 AIChE Annual Meeting
    • Place of Presentation
      Minneapolis Convention Center(Minneapolis, MN, USA)
    • Year and Date
      2011-10-18
    • Related Report
      2011 Final Research Report
  • [Presentation] High Quality Biodiesel Fuel Production from Crude Jatropha Oil without Upstream and Downstream Processing2011

    • Author(s)
      N.Shibasaki-Kitakawa, K.Kanagawa, K.Nakashima, T.Yonemoto
    • Organizer
      2011 AIChE Annual Meeting
    • Place of Presentation
      Minneapolis, USA
    • Year and Date
      2011-10-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 遊離脂肪酸残渣油を原料としたバイオディーゼル燃料合成2011

    • Author(s)
      井原亨、北川尚美、中島一紀、米本年邦
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 遊離脂肪酸残渣油を原料としたバイオディーゼル燃料合成2011

    • Author(s)
      井原亨, 北川尚美, 中島一紀, 米本年邦
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学,名古屋
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Continuous Production of High Quality Biodiesel from Vegetable Oils with High Fatty Acid Content Using Ion-exchange Resin Catalysts2011

    • Author(s)
      N. Shibasaki-Kitakawa, T. Yonemoto
    • Organizer
      The 12th The International Conference on QiR
    • Place of Presentation
      Bali, Indonesia
    • Year and Date
      2011-07-06
    • Related Report
      2011 Final Research Report
  • [Presentation] Continuous Production of High Quality Biodiesel from Vegetable Oils with High Fatty Acid Content Using Ion-exchange Resin Catalysts2011

    • Author(s)
      N.Shibasaki-Kitakawa, T.Yonemoto
    • Organizer
      The 12^<th> The International Conference on QiR
    • Place of Presentation
      Bali Indonesia(招待講演)
    • Year and Date
      2011-07-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Production Process of High Quality Biodiesel Using Ion-exchange Resin Catalysts without Upstream and Downstream Processing2011

    • Author(s)
      N. Shibasaki-Kitakawa, T. Yonemoto
    • Organizer
      The World Conference on Oilseed Processing, Fats & Oils Processing, Biofuels & Applications
    • Place of Presentation
      Izmir, Turkey
    • Year and Date
      2011-06-22
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 副生物の除去工程を必要としない高品質バイオディーゼル燃料合成法2011

    • Author(s)
      金川恵一、久保正樹、北川尚美、米本年邦
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京農工大学(東京)
    • Year and Date
      2011-03-24
    • Related Report
      2011 Final Research Report
  • [Presentation] 副生物の除去工程を必要としない高品質バイオディーゼル燃料合成法2011

    • Author(s)
      金川恵一、久保正樹、北川尚美、米本年邦
    • Organizer
      化学工学会76年会
    • Place of Presentation
      東京農工大学小金井キャンパス,東京
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Production of high-quality biodiesel fuel from waste cooking oil using anion-exchange resin catalyst2010

    • Author(s)
      N. Shibasaki-Kitakawa, T. Tsuji, M. Kubo, T. Yonemoto
    • Organizer
      2010 AIChE Annual Meeting
    • Place of Presentation
      Salt Palace Convention Center(Salt Lake City, UT, USA)
    • Year and Date
      2010-11-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Production of high-quality biodiesel fuel from waste cooking oil using a nion-exchange resin catalyst2010

    • Author(s)
      N.Shibasaki-Kitakawa, T.Tsuji, M.Kubo, T.Yonemoto
    • Organizer
      2010 AIChE Annual Meeting
    • Place of Presentation
      Salt Palace Convention Center, Salt Lake City, UT, USA
    • Year and Date
      2010-11-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 遊離脂肪酸高含有油を原料としたイオン交換樹脂法による簡便なバイオディーゼル燃料連続生産プロセスの構築2010

    • Author(s)
      北川尚美
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      2010-03-27
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] イオン交換樹脂触媒法による廃食油からの高純度バイオディーゼル燃料生産2010

    • Author(s)
      北川尚美、辻崇裕、久保正樹、米本年邦
    • Organizer
      化学工学会第75年会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2010-03-18
    • Related Report
      2011 Final Research Report
  • [Presentation] イオン交換樹脂触媒を利用したバイオディーゼル燃料製造技術の開発2009

    • Author(s)
      北川尚美
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島)、招待講演
    • Year and Date
      2009-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] イオン交換樹脂触媒を利用したバイオディーゼル燃料製造技術の開発2009

    • Author(s)
      北川尚美
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(東広島)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 脂肪酸エステルの製造方法およびバイオディーゼル燃料2012

    • Inventor(s)
      北川尚美・米本年邦・井原亨・(三菱化学)高柳弘昭
    • Industrial Property Rights Holder
      (株)東北テクノアーチ、三菱化学(株)
    • Industrial Property Number
      2012-021989
    • Filing Date
      2012-02-03
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 脂肪酸エステルの製造方法およびバイオディーゼル燃料2012

    • Inventor(s)
      (東北大)北川尚美・米本年邦・井原亨・(三菱化学)高柳弘昭
    • Industrial Property Rights Holder
      (株)東北テクノアーチ,三菱化学(株)
    • Industrial Property Number
      2012-021989
    • Filing Date
      2012-02-03
    • Related Report
      2011 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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