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Investigation of relationship between transport phenomena and spatial structure of nanoparticles in nanoparticles/polymer composite thin films

Research Project

Project/Area Number 21360375
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTohoku University

Principal Investigator

TSUKADA Takao  東北大学, 大学院・工学研究科, 教授 (10171969)

Co-Investigator(Kenkyū-buntansha) AJIRI Tadafumi  東北大学, 多元物質科学研究所, 教授 (60182995)
KUBO Masaki  東北大学, 大学院・工学研究科, 准教授 (50323069)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥13,000,000 (Direct Cost: ¥10,000,000、Indirect Cost: ¥3,000,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2010: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsナノ粒子 / 高分子 / コンポジット薄膜 / 流動 / 拡散 / 塗布 / 空間構造 / 塗布欠陥
Research Abstract

For the design and optimization of coating process of nanoparticles/polymer composite thin films and their devise manufacturing, solvent evaporation from the films and dewetting dynamics of the films during thermal annealing were observed, and the relationship between these phenomena and the spatial structure of nanoparticles in the films was investigated. The evaporation rate of organic solvent from the film was strongly affected by the presence of nanopraticles. The dewetting was suppressed by adding nanoparticles which segregated to the film surface. Brownian dynamics simulations suggested that the dispersion state of nanoparticles in solvent depends on the combination of solvent and organic molecules to modify the nanoparticle surface.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (4 results)

All 2012 2010

All Presentation (4 results)

  • [Presentation] 無機ナノ粒子/高分子コンポジット薄膜のdewetting現象と粒子空間分布との相関2012

    • Author(s)
      高橋洋祐・久保正樹・杉岡健一・塚田隆夫・南公隆・阿尻雅文
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学(東京)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 無機ナノ粒子/高分子コンポジット薄膜のアニーリング時におけるdewetting現象と粒子空間分布との相関2012

    • Author(s)
      高橋洋祐・久保正樹・杉岡健一・塚田隆夫・南公隆・阿尻雅文
    • Organizer
      第10回宮城化学工学懇話会先端研究発表会
    • Place of Presentation
      東北大学(仙台)
    • Year and Date
      2012-03-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 無機ナノ粒子/高分子コンポジット薄膜のアニーリング時のdewetting現象に及ぼすナノ粒子濃度の影響2010

    • Author(s)
      高橋洋祐・杉岡健一・塚田隆夫・南公隆・阿尻雅文
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2010-09-06
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 無機ナノ粒子/高分子コンポジット薄膜のdewetting現象に及ぼすナノ粒子濃度の影響2010

    • Author(s)
      高橋洋祐・杉岡健一・塚田隆夫・南公隆・阿尻雅文
    • Organizer
      第7回宮城化学工学懇話会先端研究発表会
    • Place of Presentation
      東北大学(仙台)
    • Year and Date
      2010-08-30
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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