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Development of a novel organic chemical hydride for COx-free hydrogen storage-transport-production system

Research Project

Project/Area Number 21360377
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKogakuin University

Principal Investigator

NAKAO Shin-ichi  工学院大学, 工学部, 教授 (00155665)

Co-Investigator(Kenkyū-buntansha) AKAMATSU Kazuki  工学院大学, 工学部, 助教 (50451795)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2010: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywords有機ハイドライド / 水素エネルギー / 膜反応器 / シリカ膜 / 水素キャリア / 自然エネルギー / ディストリビューター / エクストラクター / 三相界面 / 目然エネルギー
Research Abstract

We have successfully developed H_2-distributor-type membrane reactors for hydrogenation of 1-methylnaphtalene. When the membrane reactors were operated with 10mol% of 1-methylnaphtalene solution under 0.8 MPa in H_2 flow side, 0.6 MPa in feed side, and at 250℃, the conversion reached 10% in 2 min of contact time. When using conventional reactors for such hydrogenation reactions, H_2 should be dissolved in the feed solution, which requires high pressure condition such as 2 MPa or more. In this study, we showed that H_2-distributor-type membrane reactors made it possible to carry out the hydrogenation reaction of 1-methylnaphtalene under lower pressure condition.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (16 results)

All 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (6 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Effect of physically adsorbed water molecules on the H2-selective performance of a silica membrane prepared with dimethoxydiphenylsilane and its regeneration2012

    • Author(s)
      T. Saito, M. Seshimo, K. Akamatsu, K. Miyajima, S. Nakao
    • Journal Title

      Journal of Membrane Science

      Volume: Vol.392-393 Pages: 95-100

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of physically adsorbed water molecules on the H_2-selective perforemance of a silica membrane prepared with dimethoxydiohenylsilane and its regeneration2012

    • Author(s)
      T.Saito, et al
    • Journal Title

      J.Membrane Sci.

      Volume: 392-393 Pages: 95-100

    • DOI

      10.1016/j.memsci.2011.12.007

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水素分離シリカ膜を搭載した水素製造膜反応器2011

    • Author(s)
      赤松憲樹, 中尾真一
    • Journal Title

      膜(MEMBRANE)

      Volume: Vol.36, No.3 Pages: 104-112

    • NAID

      10029601825

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stable equilibrium shift of methane steam reforming in membrane reactors with hydrogen-selective silica membranes2011

    • Author(s)
      K. Akamatsu, T. Murakami, T. Sugawara, R. Kikuchi, S. Nakao
    • Journal Title

      AIChE Jour

      Volume: Vol.57, No.7 Issue: 7 Pages: 1882-1888

    • DOI

      10.1002/aic.12404

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 水素分離シリカ膜を搭載した水素製造膜反応器2011

    • Author(s)
      赤松憲樹, ら
    • Journal Title

      膜

      Volume: 36(3) Pages: 104-112

    • NAID

      10029601825

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stable Equilibrium Shift of Methane Steam Reforming in Membrane Reactors with Hydrogen-selective Silica Membranes2011

    • Author(s)
      K.Akamatsu, et al
    • Journal Title

      AIChE Journal

      Volume: 57(In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] シリカ水素分離膜の開発と水素エネルギー社会2011

    • Author(s)
      中尾真一
    • Organizer
      日本化学会東北支部秋田地区講演会
    • Place of Presentation
      秋田
    • Year and Date
      2011-12-09
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 膜分離技術の現状と将来展望2011

    • Author(s)
      中尾真一
    • Organizer
      RITE革新的CO_2膜分離技術シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2011-11-04
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] アモルファスシリカ水素分離膜の開発と水素エネルギー社会2011

    • Author(s)
      中尾真一
    • Organizer
      テクノメイトコープ10周年記念講演会
    • Place of Presentation
      大阪
    • Year and Date
      2011-07-14
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Microporous Membranes and Membrane Reactors for Hydrogen Energy Systems2011

    • Author(s)
      Shin-ichi Nakao
    • Organizer
      The Sixth Joint China/Japan Chemical Engineering Symposium
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2011-06-21
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] アモルファスシリカ水素分離膜の開発と水素エネルギーシステム2011

    • Author(s)
      中尾真一
    • Organizer
      日本ゼオン株式会社会講演会
    • Place of Presentation
      川崎
    • Year and Date
      2011-05-16
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] DMDPSをシリカ源としたシリカ膜への水蒸気の影響と膜の再生2011

    • Author(s)
      斉藤崇、瀬下雅博、赤松憲樹、中尾真一
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京
    • Year and Date
      2011-03-22
    • Related Report
      2011 Final Research Report
  • [Book] Chapter 8.2 : Hydrogen Production Technology using Amorphous Silica Membranes, Handbook of Advanced Ceramics, 2nd edition(edited by Shigeyuki Somiya and Masayuki Kaneno)2012

    • Author(s)
      Kazuki Akamatsu, Shin-ichi Nakao
    • Related Report
      2011 Final Research Report
  • [Book] Chapter 8.2 : Hydrogen Production Technology using Amorphous Silica Membranes, Handbook of Advanced Ceramics, 2nd edition (edited by Shigeyuki Somiya and Masayuki Kaneno)2012

    • Author(s)
      K.Akamatsu, et al
    • Publisher
      Elsevier(In press)
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://er-web.sc.kogakuin.ac.jp/Profiles/8/0000789/profile.html

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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