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Improvement of the Functions of Monolithic Microhoneycombs Obtained through the Ice Templating Method

Research Project

Project/Area Number 21360384
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

MUKAI Shin  北海道大学, 大学院・工学研究院, 教授 (70243045)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2010: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2009: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords新規反応場 / 構造体反応場 / 化学工学 / 反応・分離工学 / セラミックス / 環境技術 / 環境材料 / ゾルーゲル / 凍結乾燥 / 有機-無機ハイブリッド
Research Abstract

This work was conducted to improve the functions of monolithic microhoneycombs obtained through the Ice Templating Method, a new micromolding technique developed by our research group. First, techniques to immobilize active species with sizes ranging from the angstrom level to the sub-micrometer level were developed. Using the developed techniques, monolithic microhoneycombs which can be used as photocatalysts, solid acid catalysts for liquid phase reactions and ion exchangers were successfully synthesized. Moreover, by using an organic-inorganic hybrid precursor, monoliths having extremely high thermal stabilities were also obtained.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (56 results)

All 2012 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (46 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Development of a Water Tolerant Solid Acid Catalyst with a Low Hydraulic Resistance Using the Ice Templating Method2011

    • Author(s)
      向井紳、村上一博、橋本昌俊、佐藤慶孝
    • Journal Title

      Chemical Engineering Transaction

      Volume: 24巻 Pages: 109-114

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Assembling of Nanoparticles Using Ice Crystals2010

    • Author(s)
      向井紳、三谷一紘、村田真哉、西原洋知、田門肇
    • Journal Title

      Mat. Chem. Phys.

      Volume: 123巻 Pages: 347-350

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of a Strong Acid Ion Exchange Resin with a Monolithic Microhoneycomb Structure Using the Ice Templating Method2010

    • Author(s)
      向井紳、佐藤慶孝
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 49巻 Pages: 10438-10441

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Studies on the Growth of Ice Crystal Templates during the Synthesis of a Monolithic Silica Microhoneycomb Using the Ice Templating Method2010

    • Author(s)
      向井紳、小野寺和房、山田泉
    • Journal Title

      Adsorption

      Volume: 17巻 Pages: 49-54

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Assembling of Nanoparticles Using Ice Crystals2010

    • Author(s)
      向井紳、三谷一紘、村田真哉、西原洋知、田門肇
    • Journal Title

      Mat.Chem.Phys.

      Volume: 123 Pages: 347-350

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a Strong Acid Ion Exchange Resin with a Monolithic Microhoneycomb Structure Using the Ice Templating Method2010

    • Author(s)
      向井紳、佐藤慶孝
    • Journal Title

      Ind.Eng.Chem.Res.

      Volume: 49 Pages: 10438-10441

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 氷晶テンプレート法による液相用固体酸触媒の低流体抵抗化2012

    • Author(s)
      村上一博、佐藤慶孝、荻野勲、向井紳
    • Organizer
      第21回化学工学・粉体工学研究発表会
    • Place of Presentation
      登別グランドホテル、(登別市)
    • Year and Date
      2012-01-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Monolithic Columns Having a Hierarchical Pore System of Micropores, Mesopores and Macropores Synthesized Using Ice Crystals as the Template2011

    • Author(s)
      向井紳
    • Organizer
      NTTHU Joint Symposium
    • Place of Presentation
      電子科技大学、(成都市、中国)
    • Year and Date
      2011-12-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Improvement of the Ammonia Recovery Ability of Magnesium Ammonium Phosphate through Morphology Controlling2011

    • Author(s)
      増田隆信、向井紳
    • Organizer
      The 9th International Conference on Separation Science and Technology
    • Place of Presentation
      グランドホテル、(済州市、韓国)
    • Year and Date
      2011-11-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Tuning the Hierarchical Pore Structure of Silica Microhoneycombs Synthesized Using the Ice Templating Method2011

    • Author(s)
      佐藤慶孝、向井紳
    • Organizer
      The 9th International Conference on Separation Science and Technology
    • Place of Presentation
      グランドホテル、(済州市、韓国)
    • Year and Date
      2011-11-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of a Carbon Disk in which Short Micropores Are Directly Connected to Short and Straight Macropores Using the Ice Templating Method2011

    • Author(s)
      向井紳、野替誠弥、八尾恭彦、山田泉
    • Organizer
      The 9th International Conference on Separation Science and Technology
    • Place of Presentation
      グランドホテル、(済州市、韓国)
    • Year and Date
      2011-11-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] 氷晶テンプレート法によるスルホ基導入カーボンマイクロハニカムの創製2011

    • Author(s)
      村上一博、佐藤慶孝、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 氷晶テンプレート法を用いたナフィオン樹脂固定化シリカマイクロハニカムの創製2011

    • Author(s)
      佐藤慶孝、村上一博、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] リン酸マグネシウムアンモニウムのモルフォロジー制御によるアンモニア回収能の向上2011

    • Author(s)
      増田隆信、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] マイクロハニカム状多孔質アルミナの創製2011

    • Author(s)
      木村佳直、増田隆信、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 氷晶テンプレート法で作製した環境分析用濃縮デバイスの高性能化2011

    • Author(s)
      佐藤峻、江口愛子、阿保和貴、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光触媒の立体成型による反応場の高次化2011

    • Author(s)
      鷹觜泰平、江口愛子、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] 氷晶テンプレート法によるマイクロハニカム状スチレン系イオン交換樹脂の創製2011

    • Author(s)
      妹尾元基、佐藤慶孝、向井紳
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学、(名古屋市)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of a Porous Alumina Monolith with a Microhoneycomb Structure Using the Ice Templating Method2011

    • Author(s)
      増田隆信、木村佳直、向井紳
    • Organizer
      EuropaCat X
    • Place of Presentation
      グラスゴー大学、(グラスゴー市、イギリス)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Controlling the Porous Properties of Silica Microhoneycombs Including Nafion^[○!R] Nanoparticles Obtained through the Ice Templating Method2011

    • Author(s)
      佐藤慶孝、村上一博、向井紳
    • Organizer
      EuropaCat X
    • Place of Presentation
      グラスゴー大学、(グラスゴー市、イギリス)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of a Tubular Radial Flow Module Equipped with a Hierarchical Pore System2011

    • Author(s)
      向井紳、江口愛子、増田隆信、山田泉
    • Organizer
      EuropaCat X (招待講演)
    • Place of Presentation
      グラスゴー大学、グラスゴー市、イギリス
    • Year and Date
      2011-08-29
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of a Tubular Radial Flow Module Equipped with a Hierarchical Pore System2011

    • Author(s)
      向井紳、江口愛子、増田隆信、山田泉
    • Organizer
      EuropaCat X
    • Place of Presentation
      グラスゴー大学、(グラスゴー市、イギリス)(招待講演)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 氷晶テンプレート法を用いた低流体抵抗ナフィオン樹脂固定化シリカの創製2011

    • Author(s)
      佐藤慶孝、村上一博、向井紳
    • Organizer
      化学工学会札幌大会2011
    • Place of Presentation
      北海道大学、(札幌市)
    • Year and Date
      2011-08-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] リン酸マグネシウムアンモニウムのマイクロ流路内固定化のための結晶成長制御法の開発2011

    • Author(s)
      佐藤慶孝、村上一博、向井紳
    • Organizer
      化学工学会札幌大会2011
    • Place of Presentation
      北海道大学、(札幌市)
    • Year and Date
      2011-08-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of a Water Tolerant Solid Acid Catalyst with a Low Hydraulic Resistance Using the Ice Templating Method2011

    • Author(s)
      向井紳、村上一博、橋本昌俊、佐藤慶孝
    • Organizer
      The Tenth International Conference on Chemical & Process Engineering
    • Place of Presentation
      Palazzo degli Affari、(フィレンツェ市、イタリア)
    • Year and Date
      2011-05-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] Performance of Silica Microhoneycombs Including Heteropoly Acids in Flow Systems2010

    • Author(s)
      向井紳、村上一博、佐藤慶孝
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2010
    • Place of Presentation
      ハワイコンベンションセンター、ホノルル市、米国
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of a Monolithic Microhoneycomb with a Low Hydraulic Resistance for the Efficient Recovery of Ammonia from Waste Water2010

    • Author(s)
      増田隆信、山田泉、向井紳
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2010
    • Place of Presentation
      ハワイコンベンションセンター、ホノルル市、米国
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルコールエージングと凍結操作を利用したシリカゲルのナノ構造制御法の開発2010

    • Author(s)
      阿保和貴、向井紳
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀、東京都江戸川区
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水晶テンプレート法によるメタノール分析用シリンジ針型濃縮デバイスの開発2010

    • Author(s)
      佐藤峻、阿保和貴、佐藤慶孝、向井紳
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀、東京都江戸川区
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水晶テンプレート法を利用したマイクロバニカム構造を有する平板状多孔質炭素の新規製造法2010

    • Author(s)
      野替誠弥、山田泉、向井紳
    • Organizer
      第37回炭素材料学会年会
    • Place of Presentation
      姫路市民会館、姫路市
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Monolithic Microhoneycombs Equipped with a Unique Hierarchical Pore System Using Ice Crystals as the Template2010

    • Author(s)
      向井紳
    • Organizer
      The 4th Korea-China International Conference on Multi-functional Materials and Applications (招待講演)
    • Place of Presentation
      ハンソ大学、ソサン市、韓国
    • Year and Date
      2010-11-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Monolithic Microhoneycombs Equipped with a Unique Hierarchical Pore System Using Ice Crystals as the Template2010

    • Author(s)
      向井紳
    • Organizer
      The 4th Korea-China International Conference on Multi-functional Materials and Applications
    • Place of Presentation
      ハンソ大学・ソサン市・韓国 招待講演
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] The Ice Templating Method : A Unique Method to Synthesize Monolithic Microhoneycombs Equipped with a Hierarchical Pore System of Micro/Mesopores and Macropores2010

    • Author(s)
      向井紳
    • Organizer
      9th Korea-Japan Symposium on Materials & Interfaces (招待講演)
    • Place of Presentation
      オーシャンリゾート、ヨース市、韓国
    • Year and Date
      2010-11-01
    • Related Report
      2011 Final Research Report
  • [Presentation] The Ice Templating Method : A Unique Method to Synthesize Monolithic Microhoneycombs Equipped with a Hierarchical Pore System of Micro/Mesonores and Macronores2010

    • Author(s)
      向井紳
    • Organizer
      9th Korea-Japan Symposium on Materials & Interfaces
    • Place of Presentation
      オーシャンリゾート、ヨース市、韓国 招待講演
    • Year and Date
      2010-11-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] ヘテロポリ酸包含シリカマイクロバニカムの流通系における利用2010

    • Author(s)
      村上一博、佐藤慶孝、向井紳
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      ベルクラシック甲府、甲府市
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水晶テンプレート法を利用したシリカ担持ナフィオン触媒の低流体抵抗化2010

    • Author(s)
      佐藤慶孝、村上一博、向井紳
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      ベルクラシック甲府、甲府市
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] リン酸マグネシウムアンモニウムを用いた低流体抵抗アンモニア回収媒体の開発2010

    • Author(s)
      増田隆信、向井紳
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学、京都市
    • Year and Date
      2010-09-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水晶テンプレート法を用いた強酸性イオン交換樹脂の低流体抵抗化2010

    • Author(s)
      佐藤慶孝、村上一博、向井紳
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学、京都市
    • Year and Date
      2010-09-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Properties of a Solid Acid Catalyst with a Monolithic Microhoneycomb Structure Synthesized Using the Ice Templating Method2010

    • Author(s)
      向井紳、村上一博、佐藤慶孝、橋本昌俊
    • Organizer
      19th International Congress of Chemical and Process Engineering
    • Place of Presentation
      コングレスホテルクラリオン、プラハ市、チエコ
    • Year and Date
      2010-08-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] Development of a Strong Acid Ion Exchange Resin with a Monolithic Microhonevcomb Structure Using the Ice Templating Method2010

    • Author(s)
      向井紳、佐藤慶孝
    • Organizer
      21st International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      ローズフィラデルフィアホテル、フィラデルフィア市、米国
    • Year and Date
      2010-06-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of a Monolith for Efficient Ammonia Recovery from Dilute Sources through the Immobilization of Magnesium Ammonium Phosphate in Microchannels2010

    • Author(s)
      増田隆信、向井紳
    • Organizer
      21st International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      ローズフィラデルフィアホテル、フィラデルフィア市、米国
    • Year and Date
      2010-06-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Studies on the Growth of Ice Crystal Templates during the Synthesis of a Monolithic Silica Microhoneycomb Usine the Ice Templating Method2010

    • Author(s)
      向井紳、小野寺和房、山田泉
    • Organizer
      10th International Conference on Fundamentals of Adsorption
    • Place of Presentation
      淡路夢舞台国際会議場、淡路市
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 氷晶テンプレート法を利用したマイクロハニカム構造を有するディスク状多孔質炭素の創製2009

    • Author(s)
      野替誠弥、山田泉、向井紳
    • Organizer
      第36回炭素材料学会年会
    • Place of Presentation
      仙台市戦災復興記念館仙台市
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 環境分析用メタノール吸着材に関する検討2009

    • Author(s)
      阿保和貴、江口愛子、山田泉、向井紳
    • Organizer
      第23回日本吸着学会研究表会
    • Place of Presentation
      豊橋技術科学大学豊橋市
    • Year and Date
      2009-11-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] マイクロ流路内in situ合成によるリン酸マグネシウムアンモニウムの分散固定化2009

    • Author(s)
      増田隆信、山田泉、向井紳
    • Organizer
      第25回ゼオライト研究表会
    • Place of Presentation
      西日本総合展示場新館展示場北九州市
    • Year and Date
      2009-11-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 氷晶テンプレート法を利用したラジアルフロー誘導型モノリス体の創製2009

    • Author(s)
      江口愛子、増田隆信、山田泉、向井紳
    • Organizer
      第25回ゼオライト研究表会
    • Place of Presentation
      西日本総合展示場新館展示場北九州市
    • Year and Date
      2009-11-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 氷晶テンプレート法によるマイクロハニカム状強酸性イオン交換樹脂モノリス体の創製2009

    • Author(s)
      佐藤慶孝、山田泉、向井紳
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      シーガイヤ、宮崎市
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 氷晶テンプレート法で作製した微量環境物質濃縮デバイス用多孔質シリカの特性解析2009

    • Author(s)
      江口愛子、阿保和貴、向井紳
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学 東広島市
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 冷媒上昇型氷晶テンプレート法によるマイクロハニカム状シリカモノリス体の製造2009

    • Author(s)
      八尾恭彦、村田真哉、山田泉、向井紳
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学 東広島市
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Structural Characteriaztion of Monolithic Silica Microhoneycombs Synthesized Using the Ice Templating Method2009

    • Author(s)
      向井紳、小野寺和房、村田真哉、山田泉
    • Organizer
      Europacat 2009
    • Place of Presentation
      サラマンカ大学、サラマンカ市、スペイン
    • Year and Date
      2009-08-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis of a Monolithic Microhoneycomb from Zeolite Particles Using the Ice Template Method : Effect of the Si/AI Ratio of Zeolites2009

    • Author(s)
      村田真哉、橋本昌俊、山田泉、向井紳
    • Organizer
      Post Conference of the International Symposium on Zeolites and Microporous Crystals
    • Place of Presentation
      洞爺湖万世閣ホテル洞爺湖町
    • Year and Date
      2009-08-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Properties of Zeolite Monoliths Synthesized Using the Ice Template Method2009

    • Author(s)
      向井紳、村田真哉、小野寺和房、橋本昌俊、山田泉
    • Organizer
      International Symposium on Zeolites and Microporous Crystals(ZMPC2009)
    • Place of Presentation
      早稲田大学 東京都新宿区
    • Year and Date
      2009-08-04
    • Related Report
      2009 Annual Research Report
  • [Book] AIDIC Conference Series2011

    • Author(s)
      向井紳, 他
    • Publisher
      Associazione Italiana di Ingegneria Chimica (AIDIC)
    • Related Report
      2011 Final Research Report
  • [Book] AIDIC Conference Series, Volume 102011

    • Author(s)
      向井紳、村上一博、橋本昌俊、佐藤慶孝(分担執筆)
    • Total Pages
      7
    • Publisher
      Associazione Italiana di Ingegneria Chimica (AIDIC)
    • Related Report
      2011 Annual Research Report
  • [Book] Handbook of Hydrogels : Properties, Preparation and Applications (Chapter 16)2009

    • Author(s)
      向井紳, 他
    • Publisher
      Nova Science Publishers
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://mde-cp.eng.hokudai.ac.jp/index.html

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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