| Project/Area Number |
21360391
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | The University of Tokyo |
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Principal Investigator |
MIZUNO Noritaka 東京大学, 大学院・工学系研究科, 教授 (50181904)
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| Co-Investigator(Kenkyū-buntansha) |
UCHIDA Sayaka 東京大学, 大学院・総合文化研究科, 准教授 (10361510)
KAMADA Keigo 東京大学, 大学院・工学系研究科, 助教 (40451801)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
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| Keywords | 金属水酸化物錯体 / 合成 / 溶存種 / 制御 / 担持 / 金属酸化物 / 金属水酸化物 / 担持触媒 |
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| Research Abstract |
In this study, efficient heterogeneous catalysts using metal hydroxides(supported metal hydroxide catalysts) have been developed. Various kinds of functional group transformations, e. g., oxidative dehydrogenation of alcohols and amines and oxidative homocoupling of alkynes can be promoted by the concerted activation of substrates by the Lewis acid and Bronsted base sites on supported metal hydroxide catalysts. In addition, we can successfully develop novel catalytic transformations with metal hydroxide catalysts,(1) direct oxidative synthesis of nitriles from primary alcohols and ammonia,(2) N-alkylation of ammonia(or its surrogates) with alcohols to produce symmetrically substituted tertiary or secondary amines, and(3) oxidation of organic azides to nitriles.
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