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Study on the zeolite acidity and the catalytic activity by a combined method of IRMS-TPD of ammonia experiment and DFT calculation

Research Project

Project/Area Number 21360396
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research Institution財団法人名古屋産業科学研究所 (2011)
Tottori University (2009-2010)

Principal Investigator

NIWA Miki  財団法人名古屋産業科学研究所, 研究部, 上席研究員 (10023334)

Co-Investigator(Kenkyū-buntansha) KATADA Naonobu  鳥取大学, 大学院・工学研究科, 教授 (00243379)
OKUMURA Kazu  鳥取大学, 大学院・工学研究科, 准教授 (30294341)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2009: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Keywordsゼオライト / 酸性質 / アルカン / 接触分解 / アンモニア / 昇温脱離 / 密度汎関数計算 / 昇温脱離実験 / 触媒反応活性
Research Abstract

By using a combined method of IRMS-TPD of ammonia experimentand DFT calculation, the strong acidity and the catalytic activity observed were studied. Thus, three different conditions in which the catalytic cracking proceeded fast were observed ; i. e., the activity was related with the strong Lewis acidity, the enhanced Bronsted acidity, or the different reaction mechanism. The correlation between the acid strength and the activation energy for cracking was clearly observed on the HY based catalysts but not on the HZSM-5 zeolites.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (36 results)

All 2012 2011 2010 2009

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (22 results) Book (2 results)

  • [Journal Article] Ammonia IRMS-TPD measurements on Bronsted Acidity of Proton-formed SAPO-342011

    • Author(s)
      K. Suzuki, T. Nishio, N. Katada, G. Sastre, M. Niwa
    • Journal Title

      PCCP

      Volume: 13 Pages: 3311-3318

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Acidity and Cracking Activity on MgHY Zeolite2011

    • Author(s)
      M. Niwa, T. Noda, K. Suzuki, N. Morishita, N. Katada
    • Journal Title

      Microp. Mesop. Mater

      Volume: 146 Pages: 208-215

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of Strong Acidity and High Alkane Cracking Activity in Ammonium-treated USY zeolites2011

    • Author(s)
      K. Okumura, T. Tomiyama, N. Morishita, T. Sanada, K. Kamiguchi, N. Katada, M. Niwa
    • Journal Title

      Appl. Catal., A : General

      Volume: 405 Pages: 8-17

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Acidity and cracking activity on MgHY zeolite2011

    • Author(s)
      M.Niwa, T.Noda, K.Suzuki, N.Morishita, N.Katada
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 146 Issue: 1-3 Pages: 208-215

    • DOI

      10.1016/j.micromeso.2011.05.007

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of strong acidity and high-alkane-cracking activity in ammonium-treated USY zeolites2011

    • Author(s)
      K.Okumura, T.Tomiyama, N.Morishita, T.Sanada, K.Kamiguchi, N.Katada, M.Niwa
    • Journal Title

      Applied Catalysis, A : General

      Volume: 405 Issue: 1-2 Pages: 8-17

    • DOI

      10.1016/j.apcata.2011.07.007

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia IRMS-TPD Measurements on Bronsted Acidity of Proton-form ed SAPO-342011

    • Author(s)
      K.Suzuki, T.Nishio, N.Katada, G.Sastre, M.Niwa
    • Journal Title

      Physical Chemistry Chemical Physics(PCCP)

      Volume: 13 Pages: 3311-3318

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation of the cracking activity with solid acidity and adsorption property on zeolites2010

    • Author(s)
      N. Katada, K. Suzuki, T. Noda, W. Miyatani, F. Taniguchi, M. Niwa
    • Journal Title

      Appl. Catal., A : General

      Volume: 373 Pages: 208-213

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia IRMS-TPD characterization of Bronsted acid sites in medium-pore zeolites with different framework topologies2010

    • Author(s)
      N. Katada, K. Suzuki, T. Noda, M. B. Park, H.-K. Minc, S. B. Hong, M. Niwa
    • Journal Title

      Topics in Catal

      Volume: 53 Pages: 664-671

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of Acidity of HSSZ-35 by a Combined Method of IRMS-TPD Experiment and DFT Calculation2010

    • Author(s)
      K. Suzuki, N. Katada, M. Niwa
    • Journal Title

      Catal. Lett

      Volume: 140 Pages: 134-139

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of Acidity of H-SSZ-35 by a Combined Method of IRMS-TPD ExDeriment and DFT Calculation2010

    • Author(s)
      K.Suzuki, N.Katada, M.Niwa
    • Journal Title

      Catalysis Letters

      Volume: 140 Pages: 134-139

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ammonia IRMS-TPD characterization of Bronsted acid sites in mediumpore zeolites with different framework topologies2010

    • Author(s)
      N.Katada, K.Suzuki, T.Noda, M.B.Park, H.-K.Min, S.B.Hong, M.Niwa
    • Journal Title

      Topics in Catalysis 53

      Pages: 664-671

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation of the cracking activity with solid acidity and adsorption property on zeolites2009

    • Author(s)
      N.Katada, K.Suzuki, T.Noda, W.Miyatani, F.Taniguchi, M.Niwa
    • Journal Title

      Applied Catalysis, A : General, 373

      Pages: 208-213

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] アンモニウム塩水溶液処理によるUSYゼオライトでの強酸点の発現およびY型ゼオライトのクラッキング活性と酸強度の相関2012

    • Author(s)
      奥村和,冨山卓哉,森下奈実,片田直伸,丹羽幹
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ZSM-5ゼオライトの水蒸気処理によるパラフィン分解活性の向卜(1)-高温でのマイルドスチーミングによる強い酸点の発現2011

    • Author(s)
      曽田智子,森下奈実,玉川博康,片田直伸,丹羽幹
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] ZSM-5ゼオライトの水蒸気処理によるパラフィン分解活性の向卜(2)-アンモニア共存下での処理による反応機構の変化2011

    • Author(s)
      森下奈実,玉川博康,片田直伸,丹羽幹
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] ZSM-5ゼオライトの永蒸気処理によるパラフィン分解活性の向上(1)-高温でのマイルドスチーミングによる強い酸点の発現2011

    • Author(s)
      曽田智子・森下奈実・玉川博康・片田直伸・丹羽幹
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] ZSM-5ゼオライトの水蒸気処理によるパラフィン分解活性の向上(2)-アンモニア共存下での処理による反応機構の変化2011

    • Author(s)
      森下奈実・玉川博康・片田直伸・丹羽幹
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] IRMS-TPD study : Strong acid site of USY zeolite created by the posttreatment of NH_4NO_3 and its application2011

    • Author(s)
      K. Okumura, T. Tomiyama, N. Katada, M. Niwa
    • Organizer
      5th International FEZA Conference
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      2011-07-04
    • Related Report
      2011 Final Research Report
  • [Presentation] IRMS-TPD study : Strong acid site of USY zeolite created by the post-treatment of NH_4NO_3 and its application2011

    • Author(s)
      K.Okumura, T.Tomiyama, N.Katada, M.Niwa
    • Organizer
      5th International FEZA Conference
    • Place of Presentation
      Convention Center, Valencia, Spain
    • Year and Date
      2011-07-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Strong Brtnsted acid site in HZSM-5 created by mild steaming(Invited)2011

    • Author(s)
      M. Niwa, S. Sota, N. Katada
    • Organizer
      13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-05-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Strong Bronsted Acid Site in HZSM-5 Created by Mild Steaming2011

    • Author(s)
      M.Niwa, S.Sota, N.Katada
    • Organizer
      13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Seogwipo KAL Hotel, Jeju, Korea(Invited)
    • Year and Date
      2011-05-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] Characterization and catalytic cracking activity of USY zeolite2011

    • Author(s)
      M. Niwa
    • Organizer
      The 12th Kuwait/Japan Joint Symposium
    • Place of Presentation
      Kuwait city, Kuwait
    • Related Report
      2011 Final Research Report
  • [Presentation] Characterization and catalytic cracking activity of USY zeolite2011

    • Author(s)
      Miki Niwa
    • Organizer
      The 12^<th> Kuwait/Japan Joint Symposium
    • Place of Presentation
      Kuwait city, Kuwait
    • Related Report
      2010 Annual Research Report
  • [Presentation] Measurement of the acidity of zeolites to solve the problems of the acidsite generation and the cracking catalysis2010

    • Author(s)
      丹羽幹
    • Organizer
      第20回キャラクタリゼーション講習会
    • Place of Presentation
      大分市
    • Year and Date
      2010-10-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] MgHY : A catalyst active for cracking of alkane based on the strong Lewis acidity2010

    • Author(s)
      T. Noda, K. Suzuki, T. Kitahara, N. Katada, M. Niwa
    • Organizer
      16th International Zeolite Conference
    • Place of Presentation
      Sorrento, Italy
    • Related Report
      2011 Final Research Report
  • [Presentation] Alkaline earth cation exchanged Y zeolite for cracking of alkane ; acidity and activity studied by IRMS-TPD of ammonia and DFT calculation2010

    • Author(s)
      Noda, K. Suzuki, T. Kitahara, N. Katada, M. Niwa
    • Organizer
      6th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      札幌
    • Related Report
      2011 Final Research Report
  • [Presentation] ゼオライト触媒の機能と活性-固体酸性,形状選択性および金属担持機能-2010

    • Author(s)
      丹羽幹
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府
    • Related Report
      2011 Final Research Report
  • [Presentation] Generation of the solid acidity on zeolites, metal oxide monolayer and heteropoly acid derived catalysts and its application2010

    • Author(s)
      M. Niwa
    • Organizer
      International Symposium on Biomass Conversion-Fundamentals and Applications-
    • Place of Presentation
      宮崎
    • Related Report
      2011 Final Research Report
  • [Presentation] MgHY : A Catalyst Active for Cracking of Alkane Based on the Strong Lewis Acidity2010

    • Author(s)
      T.Noda, K.Suzuki, T.Kitahara, N.Katada, M.Niwa
    • Organizer
      16^<th> International Zeolite Conference
    • Place of Presentation
      Sorrento, Italy
    • Related Report
      2010 Annual Research Report
  • [Presentation] Alkaline earth cation exchanged Y zeolite for cracking of alkane; acidity and activity studied by IRMS-TPD of ammonia and DFT calculation2010

    • Author(s)
      T.Noda, K.Suzuki, T.Kitahara, N.Katada, M.Niwa
    • Organizer
      6^<th> Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      札幌市
    • Related Report
      2010 Annual Research Report
  • [Presentation] 特別講演:ゼオライト触媒の機能と活性-固体酸性,形状選択性および金属担持機能-2010

    • Author(s)
      丹羽幹
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府市
    • Related Report
      2010 Annual Research Report
  • [Presentation] Generation of the solid acidity on zeolites, metal oxide monolayer and heteropoly acid derived catalysts and its application2010

    • Author(s)
      Miki Niwa
    • Organizer
      International Symposium on Biomass Conversion-Fundamentals and Applications-
    • Place of Presentation
      宮崎市
    • Related Report
      2010 Annual Research Report
  • [Presentation] Measurements of zeolite acidity by temperature programmed desorption of ammonia and the catalytic cracking activity2009

    • Author(s)
      M. Niwa
    • Organizer
      ZMPC2009(International Symposium on Zeolites and Microporous Crystals)
    • Place of Presentation
      早稲田大学,東京
    • Year and Date
      2009-08-07
    • Related Report
      2011 Final Research Report
  • [Presentation] Measurements of zeolite acidity by temperature programmed desorption of ammonia and the catalytic cracking activity2009

    • Author(s)
      M.Niwa
    • Organizer
      ZMPC 2009 (International symposium on zeolites and microporous crystals)
    • Place of Presentation
      早稲田大学,東京
    • Year and Date
      2009-08-07
    • Related Report
      2009 Annual Research Report
  • [Book] Characterization and Design of Zeolite Catalysts2010

    • Author(s)
      M. Niwa, N. Katada, K. Okumura
    • Total Pages
      184
    • Publisher
      Springer
    • Related Report
      2011 Final Research Report
  • [Book] Characterization and Design of Zeolite Catalysts2010

    • Author(s)
      M.Niwa, N.Katada, K.Okumura
    • Total Pages
      184
    • Publisher
      Springer
    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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