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Development of high power density electrode system on the basis ofconstruction of ionic conduction channel of hierarchic structure

Research Project

Project/Area Number 21360479
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionKyoto University

Principal Investigator

YAO Takeshi  京都大学, 大学院・エネルギー科学研究科, 教授 (50115953)

Co-Investigator(Kenkyū-buntansha) HIBINO Mitsuhiro  京都大学, 大学院・エネルギー科学研究科, 准教授 (20270910)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2009: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Keywordsエネルギー全般 / 複合材料・物性 / 固体イオニクス / リチウムイオン電池 / 空気電池 / 拡散係数 / イオン結晶 / 二次電池 / 酸化鉄
Research Abstract

Lithium diffusion coefficient in maghemite(γ-Fe2O3) was first and electrochemically determined. A composite material of the maghemite nanoparticles and ketjenblack, which was a structural and electrically conducting medium, was fabricated as hierarchically structural material possessing nano-and meso-scale ionic conduction channel. It was examined as cathode of lithium-air battery and exhibited good performance in terms of both reversibility and cyclability.
Iron-based layer compounds CaFeO2 and SrFeO2 were found to serve as anodes of lithium ion battery through conversion reactions. In particular, CaFeO2 showed higher specific capacity than expected on the basis on the conversion reaction, which was probably attributed to alloying reaction of calcium and lithium.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (39 results)

All 2011 2010 2009 Other

All Journal Article (4 results) (of which Peer Reviewed: 1 results) Presentation (27 results) Book (5 results) Remarks (3 results)

  • [Journal Article] Structure change analysis inγ-Fe2O3/carbon composite in the process of electrochemical lithium insertion2011

    • Author(s)
      Satoshi Yamauchi, Mitsuhiro Hibino and Takeshi Yao
    • Journal Title

      Solid State Ionics

      Volume: 191 Pages: 45-48

    • Related Report
      2011 Final Research Report
  • [Journal Article] Structure change analysis in γ-Fe_2O_3/carbon composite in the process of electrochemical lithium insertion2011

    • Author(s)
      Satoshi Yamauchi, Mitsuhiro Hibino, Takeshi Yao
    • Journal Title

      Solid State Ionics

      Volume: 191 Issue: 1 Pages: 45-48

    • DOI

      10.1016/j.ssi.2011.04.003

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 欠陥ペロブスカイト構造酸化物BaLaIn2O5. 5を電解質として用いた一室式燃料電池の開発2010

    • Author(s)
      八尾健、日比野光宏
    • Journal Title

      燃料電池

      Volume: 第10巻 Pages: 140-144

    • Related Report
      2011 Final Research Report
  • [Journal Article] 欠陥ペロブスカイト構造酸化物BaLaIn_2O_<5.5>を電解質として用いた一室式燃料電池の開発2010

    • Author(s)
      八尾健、日比野光宏
    • Journal Title

      燃料電池

      Volume: 10 Pages: 40-44

    • Related Report
      2010 Annual Research Report
  • [Presentation] 層状構造鉄系酸化物AeFeO2(Ae=Ca, Sr)のリチウムイオン電池電極としての反応特性2010

    • Author(s)
      小笠原圭佑、日比野光宏、八尾健
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-11-26
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3/キャパシタカーボン複合材料の電気化学キャパシタ特性2010

    • Author(s)
      深見賢太、日比野光宏、八尾健
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-11-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 層状構造鉄系酸化物AeFeO_2(Ae=Ca, Sr)のリチウムイオン電池電極としての反応特性2010

    • Author(s)
      小笠原圭佑、日比野光宏、八尾健
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台、情報・産業プラザ
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] γ-Fe_2O_3/キャパシタカーボン複合材料の電気化学キャパシタ特性2010

    • Author(s)
      深見賢太、日比野光宏、八尾健
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台、情報・産業プラザ
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] γ-Fe2O3/KB複合体のリチウム-空気二次電池触媒特性2010

    • Author(s)
      端野優、日比野光宏、八尾健
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-11-24
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3/KB複合体のリチウム-空気二次電池触媒特性2010

    • Author(s)
      端野優、日比野光宏、八尾健
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台、情報・産業プラザ
    • Year and Date
      2010-11-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] γ-Fe_2O_3のリチウム挿入後結晶構造経時解析2010

    • Author(s)
      朴陞原、織田真也、薮塚武史、日比野光宏、八尾健
    • Organizer
      第51回電池討論会
    • Place of Presentation
      名古屋、愛知県産業労働センター
    • Year and Date
      2010-11-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Crystal Structure Change Analysis with Time for Li inserted γ-Fe_2O_32010

    • Author(s)
      Masaya Oda, Seungwon Park, Takeshi Yabutsuka, Mitsuhiro Hibino, Takeshi Yao
    • Organizer
      218th Electrochemical Society Meeting
    • Place of Presentation
      米国、ラスベガス
    • Year and Date
      2010-10-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] (Plenary) Study for Lithium Ion Rechargeable Battery Material2010

    • Author(s)
      Takeshi Yao
    • Organizer
      Joint International Conference Innovations for Environmental Actions Symposium and 7th Sustainable Energy and Environment (SEE) Forum Meeting "Innovations for Renewable Energy"
    • Place of Presentation
      ベトナム、ハノイ(招待講演)
    • Year and Date
      2010-09-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Crystal Structure Analysis with Time for Lithium Inserted γ-Fe_2O_3 with Various Insertion Rate2010

    • Author(s)
      Seungwon Park, Masaya Oda, Takeshi Yabutsuka, Mitsuhiro Hibino , Takesbi Yao
    • Organizer
      Joint International Conference Innovations for Environmental Actions Symposium and 7th Sustainable Energy and Environment (SEE) Forum Meeting "Innovations for Renewable Energy"
    • Place of Presentation
      ベトナム、ハノイ
    • Year and Date
      2010-09-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] 一室式燃料電池の開発2010

    • Author(s)
      八尾健、日比野光宏
    • Organizer
      環境ビジネスシーズ発表会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Crystal Structure Study of γ-Fe_2O_3 Cathode with Time for Lithium Insertion2010

    • Author(s)
      Seungwon Park, Masaya Oda, Takeshi Yabutsuka, Mitsuhiro Hibino , Takeshi Yao
    • Organizer
      第2回GCOE国際シンポジウム
    • Place of Presentation
      京都大学、おうばくプラザ
    • Year and Date
      2010-08-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] γ-Fe_2O_3/KB複合体を電極触媒として用いたリチウム-空気二次電池の充放電挙動2010

    • Author(s)
      端野優、日比野光宏、八尾健
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-31
    • Related Report
      2011 Final Research Report
  • [Presentation] リチウム挿入γ-Fe_2O_3の結晶構造経時解析-リチウム挿入停止後γ-Fe_2O_3/ABの構造解析-2010

    • Author(s)
      織田真也, 朴陞原, 藪塚武史, 日比野光宏, 八尾健
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山大学
    • Year and Date
      2010-03-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] γ-Fe_2O_3/炭素複合体を電極触媒として用いたリチウム-空気二次電池の充放電挙動2010

    • Author(s)
      端野優, 日比野光宏, 八尾健
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山大学
    • Year and Date
      2010-03-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] リチウムイオン二次電池高容量負極としてのγ-Fe_2O_3/炭素複合体の開発2010

    • Author(s)
      亀山恭平, 日比野光宏, 八尾健
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山大学
    • Year and Date
      2010-03-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] リチウムイオン二次電池高容量負極としてのγ-Fe_2O_3/KB複合体の開発2010

    • Author(s)
      亀山恭平、端野優、日比野光宏、八尾健、今井義博
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-30
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3/炭素複合体へのリチウムイオン挿入における速度論的反応解析2009

    • Author(s)
      日比野光宏、川田浩史、島大祐、薮塚武史、八尾健
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪
    • Year and Date
      2009-12-07
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3/炭素複合体へのリチウムイオン挿入における速度論的反応解析2009

    • Author(s)
      日比野光宏, 川田浩史, 島大祐, 八尾健
    • Organizer
      第35回固体イオニクス討論会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] γ-Fe_2O_3/KB複合体のリチウムイオン二次電池負極特性2009

    • Author(s)
      端野優、日比野光宏、今井義博、八尾健
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3/KB複合体リチウムイオン二次電池正極の充放電と速度論的反応解析2009

    • Author(s)
      川田浩史、日比野光宏、八尾健
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3へのリチウムインターカレーションと拡散特性2009

    • Author(s)
      島大祐、日比野光宏、八尾健
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] γ-Fe_2O_3/KB複合体のリチウムイオン二次電池負極特性2009

    • Author(s)
      端野優, 日比野光宏, 八尾健, 今井義博
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京農工大
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] γ-Fe_2O_3/KB複合体リチウムイオン二次電池正極の充放電と速度論的反応解析2009

    • Author(s)
      川田浩史, 日比野光宏, 八尾健
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京農工大
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] γ-Fe_2O_3へのリチウムインターカレーションと拡散特性2009

    • Author(s)
      島大祐, 日比野光宏, 八尾健
    • Organizer
      2009年電気化学秋季大会
    • Place of Presentation
      東京農工大
    • Year and Date
      2009-09-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] γ-Ferric Oxide/Carbon Composite Synthesized by Aqueous Solution Method as a Cathode for Lithium-Ion Batteries2009

    • Author(s)
      日比野光宏, 八尾健
    • Organizer
      Zero-Carbon Energy Kyoto 2009, The 1st International Symposium : Kyoto University Global COE Program
    • Place of Presentation
      京都
    • Year and Date
      2009-08-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Cathode Property of γ-Fe_2O_3/carbon Composite Fabricated by Aqueous Solution Method for Lithium-ion Battery2009

    • Author(s)
      Mitsuhiro Hibino, Naomi Okazaki, Hiroshi Kawada, Takeshi Yao
    • Organizer
      17th Conference on Solid State Ionics
    • Place of Presentation
      カナダ国トロント
    • Year and Date
      2009-07-03
    • Related Report
      2009 Annual Research Report
  • [Book] リチウム二次電池部材写真集-表面形状、分散状態、内部構造、組成分布、劣化状態の観察-」,第2章負極、第六節γ-Fe2O3/炭素複合体の高分解能観察-導電助剤との混合・接触状況2011

    • Author(s)
      八尾健
    • Publisher
      技術情報協会
    • Related Report
      2011 Final Research Report
  • [Book] 「リチウム二次電池部材 写真集-表面形状、分散状態、内部構造、組成分布、劣化状態の観察-」,第2章負極、第六節γ-Fe_2O_3/炭素複合体の高分解能観察-導電助剤との混合・接触状況-2011

    • Author(s)
      八尾健
    • Total Pages
      110
    • Publisher
      技術情報協会
    • Related Report
      2010 Annual Research Report
  • [Book] リチウムイオン電池の科学-ホスト・ゲスト系電極の物理化学からナノテク材料まで2011

    • Author(s)
      工藤徹一、日比野光宏、本間格
    • Total Pages
      235
    • Publisher
      内田老鶴圃
    • Related Report
      2010 Annual Research Report
  • [Book] リチウムイオン電池の科学-ホスト・ゲスト系電極の物理化学からナノテク材料まで2010

    • Author(s)
      工藤徹一、日比野光宏、本間格
    • Publisher
      内田老鶴圃
    • Related Report
      2011 Final Research Report
  • [Book] "γ-Ferric Oxide/Carbon Composite Synthesized by Aqueous Solution Method as a Cathode for Lithium-Ion batteries", pp. 31-38, Zero-Carbon Energy Kyoto 2009, Proceedings of the First International Symposium of Global COE Program(editor T. Yao.)2010

    • Author(s)
      M.Hibino, T.Yao
    • Total Pages
      390
    • Publisher
      Springer, Japan
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://fssc.energy.kyoto-u.ac.jp/index.ht

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://fssc.energy.kyoto-u.ac.jp/index.htm

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://fssc.energy.kyoto-u.ac.jp/index.htm

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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