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Decomposition of lignin and lignin-carbohydrate complex(LCC) in ionic liquids

Research Project

Project/Area Number 21380111
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Wood science
Research InstitutionForestry and Forest Products Research Institute

Principal Investigator

KUBO Satoshi  独立行政法人森林総合研究所, バイオマス化学研究領域, 主任研究員 (50399375)

Co-Investigator(Kenkyū-buntansha) HASHIDA Kou  独立行政法人森林総合研究所, バイオマス化学研究領域, 主任研究員 (40353809)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2011: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Keywordsイオン液体 / リグニン / リグニン-炭水化物複合体 / 磨砕リグニン / 分解機構 / カルボニル / エノールエーテル / アルカリ処理 / 分解経路 / フェノール性/非フェノール性 / リグニン-炭水化物合体 / 分解速度 / フェノール性 / 非フェノール性 / グアイアシル / シリンギル / スレオ / エリスロ / DMSO
Research Abstract

Decomposition pathways of model compounds that have main inter-unit linkages of lignin in an imidazolium ionic liquid varied depending on the differences in the chemical structure of ionic liquids and the presence of phenolic hydroxyl groups. Model compounds of lignin-carbohydrate complex were decomposed via the similar pathway to form allyl-ether substructures. It was revealed that lignin model polymer, milled wood lignin prepared from Sugi wood, was de-polymerized in ionic liquid via the same decomposition pathways of model compounds.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (10 results)

All 2012 2010 2009 Other

All Presentation (9 results) Remarks (1 results)

  • [Presentation] リグニンの添加によるイオン液体の各プロトンのT1緩和時間の変化2012

    • Author(s)
      久保智史、橋田光、山田竜彦、菱山正二郎、細谷修二
    • Organizer
      第62回日本木材学会大会
    • Place of Presentation
      北海道大学農学部(札幌)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Structual Changes of Lignin in Ionic Liquids : A model study2010

    • Author(s)
      Kubo, Satoshi
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ロイアルハワイアンホテル(米国ホノルル市)
    • Year and Date
      2010-12-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Structual Changes of Lignin in Ionic Liquids : A model study2010

    • Author(s)
      Satoshi Kubo, Koh Hashida, Shojiro Hishiyama, Tatsuhiko Yamada, Shiuji Hosoya
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      ロイアルハワイアン(米国ホノルル市)
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Decomposition of beta-O-4 lignin model compounds in ionic liquid and aqueous alkaline medium2010

    • Author(s)
      Kubo, Satoshi
    • Organizer
      Research Progress in Paper Industry and Biorefinery
    • Place of Presentation
      華南理工大学(中国広州市)
    • Year and Date
      2010-11-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Decomposition of beta-O-4 lignin model compounds in ionic liquid and aqueous alkaline medium2010

    • Author(s)
      Satoshi Kubo, Koh Hashida, Shojiro Hishiyama, Tatsuhiko Yamada, Shiuji Hosoya
    • Organizer
      Research Progress in Paper Industry and Biorefineries
    • Place of Presentation
      華南理工大学(中国広州市)
    • Year and Date
      2010-11-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオン液体中でのリグニンモデルおよびリグニンの構造変化2010

    • Author(s)
      久保智史、橋田光、山田竜彦、菱山正二郎、細谷修二
    • Organizer
      Research Progress in Paper Industry and Biorefineries
    • Place of Presentation
      京都大学(京都市)
    • Year and Date
      2010-10-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] β-O-4型リグニン2量体モデルのイオン液体中での分解挙動-二次分解生成物の化学構造2010

    • Author(s)
      久保智史、山田竜彦、橋田光、菱山正二郎、細谷修二
    • Organizer
      第60回日本木材学会大会
    • Place of Presentation
      宮崎観光ホテル(宮崎市)
    • Year and Date
      2010-03-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] イオン液体/DMSO混合溶媒系に於けるリグニンモデル化合物の分解挙動2009

    • Author(s)
      久保智史、山田竜彦、橋田光、菱山正二郎、細谷修二
    • Organizer
      第54回リグニン討論会
    • Place of Presentation
      静岡県男女共同参画センターあざれあ(静岡市)
    • Year and Date
      2009-10-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] イオン液体中での非フェノール性β-O-4型リグニンモデル化合物の反応挙動2009

    • Author(s)
      橋田光、久保智史、山田竜彦、菱山正二郎、細谷修二
    • Organizer
      第54回リグニン討論会
    • Place of Presentation
      静岡県男女共同参画センターあざれあ(静岡市)
    • Year and Date
      2009-10-29
    • Related Report
      2009 Annual Research Report
  • [Remarks] (独)森林総合研究所第2期中期計画成果集

    • URL

      http://www.ffpri.affrc.go.jp/pubs/seikasenshu/dai2ki/documents/iab.pdf

    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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