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Development of Advanced Risk-Free Process for Restoring Environmental Water Using Micro・Nano Bubbles

Research Project

Project/Area Number 21510094
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionKansai University

Principal Investigator

MUROYAMA Katsuhiko  関西大学, 先端科学技術推進機構, 研究員 (00026163)

Co-Investigator(Renkei-kenkyūsha) HAYASHI Jun' ichi  関西大学, 環境都市工学部, 准教授 (60247898)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords環境修復技術 / マイクロ・ナノバブル / 環境保全技術 / リスクフリー技術 / 浄水処理 / オゾン処理 / HO・ラジカル / フェノール / 環境修復 / p-クロロフェノール
Research Abstract

(1) The superiority of the micro-bubble treatment over the conventional milli-bubble treatment was experimentally verified based on the ozone degradation of phenolic compounds thinly dissolved in water in a 1 L bubble column reactor. The results showed that the volumetric flow rate of ozonated oxygen required for the micro-bubble treatment of ozone degradation of phenolic compounds was only 1/5 of that for the milli-bubble treatment, due to the extremely high specific interfacial area and superior ozone absorption efficiency.
(2) The bubble size distribution, the Sauter mean diameter dvs, the volumetric mass transfer coefficient kLa, and the oxygen absorption efficiency were measured for micro-bubble dispersion including about 20~60μm diameter bubbles. The values of the specific interfacial area and the values of gas absorption efficiency are markedly greater than those for the conventional milli-bubble dispersion.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (35 results)

All 2012 2011 2010 2009 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (18 results) Book (2 results) Remarks (3 results)

  • [Journal Article] Transport Properties of Micro-Bubbles in a Bubble Column2012

    • Author(s)
      K. Muroyama, Y. Oka and R. Fujiki
    • Journal Title

      J. Chem. Eng. Japan

      Volume: (in Press)

    • NAID

      130001858774

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Degradation Characteristics of Phenolic Compounds Using Micro-Bubbles of Ozonated Oxygen2012

    • Author(s)
      K, Muroyama, A. Kawabata, Y. Yamaguchi and J. Hayashi
    • Journal Title

      J. Chem. Eng. Japan

      Volume: (in Press)

    • NAID

      130001858755

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transport Properties of Micro-Bubbles in a Bubble Column2012

    • Author(s)
      K.Muroyama, Y.Oka, R.Fujiki
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: (Accepted)(In press)

    • NAID

      130001858774

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Degradation Characteristics of Phenolic Compounds Using Micro-Bubbles of Ozonated Oxygen2012

    • Author(s)
      K.Muroyama, A.Kawabata, Y.Yamaguchi, J.Hayashi
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: (Accepted)(In press)

    • NAID

      130001858755

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrodynamics and mass transfer properties of micro-bubbles in a bubble column2011

    • Author(s)
      K.Muroyama, T.Sanda, R.Fujiki, Y.Oka, S.Kubo
    • Journal Title

      The 10th Conference on Gas-Liquid and Gas-Liquid-Solid Reactor Engineering

      Volume: (USB Memory)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Addition of Hydrogen Peroxide and/or Calcium Carbonate on Ozone-Decomposition of Phenol Sparingly Dissolved in Water2011

    • Author(s)
      K.Muroyama, S.Suwa, A.Kawabata, Y.Takami, Jun'ichi Hayash
    • Journal Title

      Ozone Science & Engineering(Taylor & Francis)

      Volume: 33 Pages: 143-149

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Degradation characteristics of p-chrolophenol using ozone micro-bubbles2010

    • Author(s)
      A.Kawabata, K.Muroyama
    • Journal Title

      The 2^<nd> Asian Conference on Innovative Energy & Environmental Chemical Engineering

      Volume: 1 Pages: 535-540

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transport properties of micro-bubbles issued from a compression-dissolution type generator in a bubble column2010

    • Author(s)
      K.Muroyama, T.Sanda, S.Kubo
    • Journal Title

      The 2^<nd> Asian Conference on Innovative Energy & Environmental Chemical Engineering

      Volume: 1

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Addition of Hydrogen Peroxide and/or Calcium Carbonate on Ozone-Decomposition of Phenol Sparingly Dissolved in Water2009

    • Author(s)
      K. Muroyama, S. Suwa, A. Kawabata, Y. Takami and J. Hayashi
    • Journal Title

      Ozone Sci. & Eng.

      Volume: Vol.33 Pages: 143-149

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Addition of Hydrogen Peroxide and/or Calcium Carbonate on Ozone-Decomposition of Phenol Sparingly Dissolved in Water2009

    • Author(s)
      K.Muroyama, S.Suwa, A.Kawabata, Y.Takami, Jun'ichi Hayash
    • Journal Title

      19th IOA World Congress 2009, Aug.31-Sept.3, 2009, 5-5 Session 5(Proceedings-CD-ROM)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of oxidation-promoting additives on the ozone treatment of dilute aqueous solution of p-chlorophenol2009

    • Author(s)
      A.Kawabata, S.Suwa, K.Muroyama
    • Journal Title

      PROCEEDINGS of CHEMECA 2009, Sep.27-30, 2009, Perth, Australia, Proceedings (CD-ROM)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fundamental properties of swarm bubbles in a column containing micro-bubbles2009

    • Author(s)
      K.Muroyama, R.Yamada, S.Kubo
    • Journal Title

      PROCEEDINGS of CHEMECA 2009, Sep.27-30, 2009, Perth, Australia, Proceedings (CD-ROM)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 気泡塔におけるマイクロバブルによる酸素吸収特性の解析2012

    • Author(s)
      今井晃平、芝弘和、林順一、室山勝彦
    • Organizer
      化学工学会第77年会講演要旨集CD-ROM
    • Place of Presentation
      工学院大学、新宿キャンパス
    • Year and Date
      2012-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Oxygen Transfer Characteristics from Micro-Bubble Dispersion in a Bubble Column2012

    • Author(s)
      K. Muroyama, K. Imai, H. Shiba, and J. Hayash
    • Organizer
      The 3rd Asian Conference on Innovative Energy & Environmental Chemical Engineering(IEECE)
    • Place of Presentation
      Farglory Hotel, Hualien, TAIWAN
    • Related Report
      2011 Final Research Report
  • [Presentation] 気泡塔におけるマイクロバブルの酸素吸収特性2012

    • Author(s)
      今井晃平、芝弘和、林順一、室山勝彦
    • Organizer
      分離技術会年会2012技術・研究発表講演要旨集
    • Place of Presentation
      関西大学
    • Related Report
      2011 Final Research Report
  • [Presentation] Hydrodynamics and mass transfer properties of micro-bubbles in a bubble column2011

    • Author(s)
      K. Muroyama, T. Sanda, R. Fujiki, Y. Oka and S. Kubo
    • Organizer
      The 10th Conference on Gas-Liquid and Gas-Liquid-Solid Reactor Engineering(GLS10)
    • Place of Presentation
      Braga, Portugal, USB Memory
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロバブル気泡塔における水中の希薄フェノール類のオゾン分解特性2011

    • Author(s)
      室山勝彦、川端昭寛、山口勇次、林順一
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロバブル気泡塔の輸送現象2011

    • Author(s)
      岡祐司、林順一、室山勝彦
    • Organizer
      化学工学会第43回秋季大会講演要旨集
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 気泡塔におけるマイクロバブルによる酸素吸収特性の解析2011

    • Author(s)
      今井晃平、芝弘和、林順一、室山勝彦
    • Organizer
      化学工学会43回研究発表講演要旨集
    • Place of Presentation
      名古屋工業大学、名古屋
    • Related Report
      2011 Annual Research Report
  • [Presentation] マイクロバブル気泡塔の輸送特性2010

    • Author(s)
      室山勝彦、三田高祐、久保翔平
    • Organizer
      化学工学会第42回秋期大会
    • Place of Presentation
      同志社大・今出川キャンパス
    • Year and Date
      2010-09-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Transport properties of micro-bubbles issued from a compression-dissolution type generator in a bubble column2010

    • Author(s)
      K. Muroyama, T. Sanda, and S. Kubo
    • Organizer
      The 2nd Asian Conference on IEECE
    • Place of Presentation
      Phuket, Thailand
    • Related Report
      2011 Final Research Report
  • [Presentation] Degradation characteristics of p-chlorophenol using ozone micro-bubbles2010

    • Author(s)
      A. Kawabata and K. Muroyama
    • Organizer
      The 2nd Asian Conference on IEECE
    • Place of Presentation
      Phuket, Thailand
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロバブル気泡塔の輸送特性2010

    • Author(s)
      室山勝彦、三田高祐、久保翔平
    • Organizer
      化学工学会第42回秋季大会講演要旨集
    • Place of Presentation
      同志社大学今出川キャンパス
    • Related Report
      2011 Final Research Report
  • [Presentation] オゾンを用いたp-クロロフェノールの分解特性2009

    • Author(s)
      川端昭寛、諏訪慎一、室山勝彦
    • Organizer
      化学工学会第41回秋季大会講演要旨集
    • Place of Presentation
      広島大学
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロバブル気泡塔の気液間物質移動特性2009

    • Author(s)
      久保翔平、山田遼、室山勝彦
    • Organizer
      化学工学会第41回秋季大会講演要旨集
    • Place of Presentation
      広島大学
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロバブル気泡塔の気液間物質移動特性2009

    • Author(s)
      久保翔平・山田遼・室山勝彦
    • Organizer
      化学工学会第41回秋期大会講演要旨集, E118
    • Place of Presentation
      広島大学
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] オゾンを用いたp-クロロフェノールの分解特性2009

    • Author(s)
      川端昭寛・諏訪慎一・室山勝彦
    • Organizer
      化学工学会第41回秋期大会講演要旨集, Y106
    • Place of Presentation
      広島大学
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Fundamental properties of swarm bubbles in a column containing micro-bubbles2009

    • Author(s)
      K. Muroyama, R. Yamada and S. Kubo
    • Organizer
      Proceedings of CHEMECA 2009
    • Place of Presentation
      Perth Australia
    • Related Report
      2011 Final Research Report
  • [Presentation] Effect of oxidation-promoting additives on the ozone treatment of dilute aqueous solution of p-chlorophenol2009

    • Author(s)
      A. Kawabata, S. Suwa and K. Muroyama
    • Organizer
      Proceedings of CHEMECA 2009
    • Place of Presentation
      Perth Australia
    • Related Report
      2011 Final Research Report
  • [Presentation] Effects of Addition of Hydrogen Peroxide and/or Calcium Carbonate on Ozone-Decomposition of Phenol Sparingly Dissolved in Water2009

    • Author(s)
      K. Muroyama, S. Suwa, A. Kawabata, Y. Takami and J. Hayashi
    • Organizer
      19th IOA World Congress 2009
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2011 Final Research Report
  • [Book] 化学工学便覧7版、ぬれ壁塔、気泡塔・三相流動層、気泡攪拌槽2011

    • Author(s)
      室山勝彦、化学工学会
    • Publisher
      丸善
    • Related Report
      2011 Final Research Report
  • [Book] 化学工学便覧第7版:分担執筆(気泡塔・3相流動層)(化学工学会編)2011

    • Author(s)
      室山勝彦
    • Total Pages
      9
    • Publisher
      丸善
    • Related Report
      2011 Annual Research Report
  • [Remarks] ホームページ等(現在削除)

    • URL

      http://www.cheng.kansai-u.ac.jp/CRElab/

    • Related Report
      2011 Final Research Report
  • [Remarks] 研究者のWebページ

    • URL

      http://www.cheng.kansai-u.ac.jp/CRElab/

    • Related Report
      2010 Annual Research Report
  • [Remarks] 研究者のWebページ

    • URL

      http://www.cheng.kansai-u.ac.jp/CRElab/

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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