Structure analysis of porous coordination polymers with flexible framework by X-ray powder diffraction.

• Project/Area Number: 21510107
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanostructural science
• Research Institution: Osaka Prefecture University
• Principal Investigator: KUBOTA Yoshiki 大阪府立大学, 理学系・研究科, 准教授 (50254371)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
• Keywords: ナノ材料 / 多孔性材料 / ガス吸着 / 放射光粉末回折 / 精密電子密度解析 / 精密結晶構造解析 / マキシマム・エントロピー法 / 精密構造解析

Research Abstract

This study revealed the structural change in the gas adsorption process of porous coordination polymers(PCP) with flexible framework by the synchrotron powder diffraction method. It was found that a certain PCP with reporter molecules in the nanopore transformed its framework from lozenge shape to square shape with increasing the amount of adsorbate CO_2.The structure of reporter molecule in the nanopore also deformed in sync with it emitting a blue light. As a result this material was found to play role as a CO_2 sensor.

Research Products

• [Journal Article] Gas detection by structural variations of fluorescent guest molecules in a flexible porous coordination polymer (2011)
  • Author(s): Nobuhiro Yanai, Koji Kitayama, Yuh Hijikata, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Masaki Takata, Motohiro Mizuno, Takashi Uemura, Susumu Kitagawa
  • Journal Title: Nature Mater Volume: 10 Pages: 787-793
  • Peer Reviewed
• [Journal Article] Crystallization of the chalcogenide compound Sb_8Te_3 (2011)
  • Author(s): Kouichi Kifune, Tomoko Fujita, Yoshiki Kubota, Noboru Yamada, Toshiyuki Matsunaga
  • Journal Title: Acta Cryst. B Volume: 67 Pages: 381-385
  • Peer Reviewed
• [Journal Article] Reporting Structural Transformation of Soft Porous Crystals for Detection of CO_2 (2011)
  • Author(s): Nobuhiro Yanai, Koji Kitayama, Yuh Hijikata, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Masaki Takata, Motohiro Mizuno, Takashi Uemura, Susumu Kitagawa
  • Journal Title: Nature Mater. Volume: 10 Issue: 10 Pages: 787-793
  • DOI: 10.1038/nmat3104
  • Peer Reviewed
• [Journal Article] Crystallization of the chalcogenide compound Sb_8Te_3 (2011)
  • Author(s): Kouichi Kifune, Tomoko Fujita, Yoshiki Kubota, Noboru Yamada, Toshiyuki Matsunaga
  • Journal Title: Acta Cryst.B Volume: 67 Issue: 5 Pages: 381-385
  • DOI: 10.1107/s0108768111033738
  • Peer Reviewed
• [Journal Article] Control of Interpenetration for Tuning Structural Flexibility Impacts on Sorption Properties (2010)
  • Author(s): Sareeya Bureekaew, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Raita Hirose, Jungeun Kim, Kenichi Kato, Masaki Takata, Susumu Kitagawa
  • Journal Title: Angew. Chem. Int. Ed Volume: 49 Pages: 7660-7664
  • Peer Reviewed
• [Journal Article] Structural investigation of GeSb_6Te_<10> and GeBi_6Te_<10> intermetallic compounds in the chalcogenide homologous series (2010)
  • Author(s): Toshiyuki Matsunaga, Rie Kojima, Noboru Yamada, Tomoko Fujita, Kouichi Kifune, Yoshiki Kubota, Masaki Takata
  • Journal Title: Acta Cryst. B Volume: 66 Pages: 407-411
  • Peer Reviewed
• [Journal Article] Temperature responsive channel uniformity impacts on highly guest-selective adsorption in a porous coordination polymer (2010)
  • Author(s): Ryotaro Matsuda, Takashi Tsujino, Hiroshi Sato, Yoshiki Kubota, Kunimitsu Morishige, Masaki Takata
  • Journal Title: Susumu Kitagawa, Chem. Sci Volume: 1 Pages: 315-321
  • Peer Reviewed
• [Journal Article] Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer (2010)
  • Author(s): Satoru Shimomura, Masakazu Higuchi, Ryotaro Matsuda, Ko Yoneda, Yuh Hijikata, Yoshiki Kubota, Yoshimi Mita, Jungeun Kim, Masaki Takata, Susumu Kitagawa
  • Journal Title: Nature Chem Volume: 2 Pages: 633-637
  • Peer Reviewed
• [Journal Article] Solid Solutions of Soft Porous Coordination Polymers : Fine-Tuning of Gas Adsorption Properties (2010)
  • Author(s): Tomohiro Fukushima, Satoshi Horike, Yasutaka Inubushi, Keiji Nakagawa, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: Angew. Chem. Int. Ed Volume: 49 Pages: 4820-4824
  • Peer Reviewed
• [Journal Article] Systematic Construction of Porous Coordination Pillared-Layer Structures and Their Sorption Properties (2010)
  • Author(s): Hirotoshi Sakamoto, Ryo Kitaura, Ryotaro Matsuda, Susumu Kitagawa, Yoshiki Kubota, Masaki Takata
  • Journal Title: Chem. Lett Volume: 39 Pages: 218-219
  • NAID: 10027178035
  • Peer Reviewed
• [Journal Article] Incommensurate guest adsorption in bellows-shaped one-dimensional channels of porous coordination polymers (2010)
  • Author(s): Ryotaro Matsuda, Ryo Kitaura, Yoshiki Kubota, Tatsuo C. Kobayashi, Masaki Takata, Susumu Kitagawa
  • Journal Title: Microporous and Mesoporous Materials Volume: 129 Pages: 296-303
  • Peer Reviewed
• [Journal Article] Solid Solutions of Soft Porous Coordination Polymers : Fine-Tuning of Gas Adsorption Properties (2010)
  • Author(s): Tomohiro Fukushima, Satoshi Horike, Yasutaka Inubushi, Keiji Nakagawa, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: Angew.Chem.Int.Ed. Volume: 49 Pages: 1-6
  • Peer Reviewed
• [Journal Article] Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer (2010)
  • Author(s): Satoru Shimomura, Masakazu Higuchi, Ryotaro Matsuda, Ko Yoneda, Yuh Hijikata, Yoshiki Kubota, Yoshimi Mita, Jungeun Kim, Masaki Takata, Susumu Kitagawa
  • Journal Title: Nature Chemistry Volume: 2 Pages: 633-637
  • Peer Reviewed
• [Journal Article] Temperature responsive channel uniformity impacts on highly guest-selective adsorption in a porous coordination polymer (2010)
  • Author(s): Ryotaro Matsuda, Takashi Tsujino, Hiroshi Sato, Yoshiki Kubota, Kunimitsu Morishige, Masaki Takata, Susumu Kitagawa
  • Journal Title: Chem.Sci. Volume: 1 Pages: 315-321
  • Peer Reviewed
• [Journal Article] Control of Interpenetration for Tuning Structural Flexibility Impacts on Sorption Properties (2010)
  • Author(s): Sareeya Bureekaew, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Jungeun Kim, Kenichi Kato, Masaki Takata, Susumu Kitagawa
  • Journal Title: Angew.Chem.Int.Ed. Volume: 49 Pages: 7660-7664
  • Peer Reviewed
• [Journal Article] Porous Coordination Polymer with Pyridinium Cationic Surface,[Zn_2(tpa)_2(cpb)] (2009)
  • Author(s): Masakazu Higuchi, Daisuke Tanaka, Satoshi Horike, Hirotoshi Sakamoto, Kohei Nakamura, Yohei Takashima, Yuh Hijikata, Nobuhiro Yanai, Jungeun Kim, Kenichi Kato, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: J. Am. Chem. Soc Volume: 131 Pages: 10336-10337
  • Peer Reviewed
• [Journal Article] Porous Coordination Polymer with Pyridinium Cationic Surface, [Zn_2(tpa)_2(cpb)] (2009)
  • Author(s): M.Higuchi, D.Tanaka, S.Horike, H.Sakamoto, K.Nakamura, Y.Takashima, Y.Hijikata, N.Yanai, J.Kim, K.Kato, Y.Kubota, M.Takata, S.Kitagawa
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 10336-10337
  • Peer Reviewed
• [Journal Article] Incommensurate guest adsorption in bellows-shaped one-dimensional channels of porous coordination polymers (2009)
  • Author(s): R.Matsuda, R.Kitaura, Y.Kubota, T.C.Kobayashi, M.Takata, S.Kitagawa
  • Journal Title: Microporous and Mesoporous Materials 129 Pages: 296-303
  • Peer Reviewed
• [Journal Article] Systematic Construction of Porous Coordination Pillared-Layer Structures and Their Sorption Properties (2009)
  • Author(s): H.Sakamoto, R.Kitaura, R.Matsuda, S.Kitagawa, Y.Kubota, M.Takata
  • Journal Title: Chem.Lett. 39 Pages: 218-219
  • NAID: 10027178035
  • Peer Reviewed
• [Presentation] Ab-initio structure determination of[Cu(dhbc)_2(dpa)] n as high CO_2 adsorption materials (2011)
  • Author(s): Yohei Sato, Yoshiki Kubota, Yasutaka Inubushi, Masaki Takata
  • Organizer: The 11th Tamura Memorial Symposium
  • Place of Presentation: Osaka Prefecture University(Sakai)
  • Year and Date: 2011-12-03
• [Presentation] Ab-initio structure determination of [Cu(dhbc)_2(dpa)]_n as high CO_2 adsorption materials (2011)
  • Author(s): Yohei Sato, Yoshiki Kubota, Yasutaka Inubushi, Masaki Takata
  • Organizer: The 11th Tamura Memorial Symposium
  • Place of Presentation: 大阪府立大学(堺市)
  • Year and Date: 2011-12-03
• [Presentation] 非整合な電荷密度波を示すCuV_2S_4の結晶構造解析 (2011)
  • Author(s): 河口彰吾, 久保田佳基, 石橋広記
  • Organizer: 日本結晶学会
  • Place of Presentation: 北海道大学(札幌市)
  • Year and Date: 2011-11-24
• [Presentation] Structural Analysis of Spinel Compound CuV_2S_4 with Incommensurate Charge-Density Wave (2011)
  • Author(s): Shogo Kawaguchi, Yoshiki Kubota, Naruki Tsuji, Jungeun Kim, Kenichi Kato, Masaki Takata, Hiroki Ishibashi
  • Organizer: International Conference on Strongly Correlated Electron Systems
  • Place of Presentation: University of Cambridge(Cambridge, UK)
  • Year and Date: 2011-08-31
• [Presentation] Structural Analysis of Spinel Compound CuV_2S_4 with Incommensurate Charge-Density Wave (2011)
  • Author(s): Shogo Kawaguchi, Yoshiki Kubota, Naruki Tsuji, Jungeun Kim, Kenichi Kato, Masaki Takata, Hiroki Ishibashi
  • Organizer: International Conference on Strongly Correlated Electron Systems
  • Place of Presentation: University of Cambridge (Cambridge, UK)
  • Year and Date: 2011-08-31
• [Presentation] 酸素分子が吸着したゼオライトの構造相転移 (2011)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 日本放射光学会
  • Place of Presentation: つくば国際会議場(つくば市)
  • Year and Date: 2011-01-10
• [Presentation] 酸素分子が吸着したゼオライトの構造相転移 (2011)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 第24回日本放射光学会年会・放射光科学合同シンポジウム
  • Place of Presentation: つくば国際会議場(つくば市)
  • Year and Date: 2011-01-10
• [Presentation] Molecular arrangement and magnetic properties of O_2 in the nanoporous materials (2011)
  • Author(s): Yoshiki Kubota, Akihiro Hori, Tatsuo C. Kobayashi, Ryotaro Matsuda, Kouichi Kindo, Kenichi Kato, Masaki Takata, Susumu Kitagawa
  • Organizer: XXII Congress of the International Union of Crystallography
  • Place of Presentation: Palacio Municipal de Congresos(Madrid, Spain)
• [Presentation] Incommensurate structure analyses of Bi-Te and Sb-Te binary system (2011)
  • Author(s): Kazuyuki Shakudo, Kouichi Kifune, Yoshiki Kubota, Toshiyuki Matsunaga, Noboru Yamada, Masaki Takata
  • Organizer: XXII Congress of the International Union of Crystallography
  • Place of Presentation: Palacio Municipal de Congresos(Madrid, Spain)
• [Presentation] Molecular arrangement and magnetic properties of O_2 in the nanoporo us materials (2011)
  • Author(s): Yoshiki Kubota, Akihiro Hori, Tatsuo C.Kobayashi, Ryotaro Matsuda, Kouichi Kindo, Kenichi Kato, Masaki Takata, Susumu Kitagawa
  • Organizer: XXII Congress of the International Union of Crystallography
  • Place of Presentation: Palacio Municipal de Congresos (Madrid, Spain)
• [Presentation] Incommensurate structure analyses of Bi-Te and Sb-Te binary system (2011)
  • Author(s): Kazuyuki Shakudo, Kouichi Kifune, Yoshiki Kubota, Toshiyuki Matsunaga, Noboru Yamada, Masaki Takata
  • Organizer: XXII Congress of the International Union of Crystallography
  • Place of Presentation: Palacio Municipal de Congresos (Madrid, Spain)
• [Presentation] 吸着酸素分子の磁性が誘起するゼオライトの構造相転移 (2010)
  • Author(s): 久保田佳基, 鰐川泰, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 日本結晶学会
  • Place of Presentation: 大阪大学(吹田市)
  • Year and Date: 2010-12-03
• [Presentation] 吸着酸素分子の磁性が誘起するゼオライトの構造相転移 (2010)
  • Author(s): 久保田佳基, 鰐川泰, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 日本結晶学会 平成22年度年会
  • Place of Presentation: 大阪大学(吹田市)
  • Year and Date: 2010-12-03
• [Presentation] MFIゼオライトに吸着した酸素分子の配列構造 (2010)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 日本物理学会
  • Place of Presentation: 大阪府立大学(堺市)
  • Year and Date: 2010-09-26
• [Presentation] MFIゼオライトに吸着した酸素分子の配列構造 (2010)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 日本物理学会 2010年秋季大会
  • Place of Presentation: 大阪府立大学(堺市)
  • Year and Date: 2010-09-26
• [Presentation] 多孔性配位高分子Cu-CHDに吸着したO2の磁性と構造の相関 (2010)
  • Author(s): 堀彰宏, 小林達生, 久保田佳基, 松尾晶, 金道浩一, 金延恩, 加藤健一, 高田昌樹, 坂本裕俊, 松田亮太郎, 北川進
  • Organizer: 日本物理学会
  • Place of Presentation: 岡山大学(岡山市)
  • Year and Date: 2010-03-22
• [Presentation] MFIゼオライトに吸着した酸素分子の配列構造 (2010)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 桑名加菜子, 小林達生, 白曼雅子, 仲井和之, 金廷恩, 加藤健一, 高田昌樹, 松田亮太郎, 北川進
  • Organizer: 日本物理学会
  • Place of Presentation: 岡山大学(岡山市)
  • Year and Date: 2010-03-22
• [Presentation] 多孔性配位高分子Cu-CHDに吸着したO_2の磁性と構造の相関 (2010)
  • Author(s): 堀彰宏, 小林達生, 久保田佳基, 松尾晶, 金道浩一, 金延恩, 加藤健一, 高田昌樹, 坂本裕俊, 松田亮太郎, 北川進
  • Organizer: 日本物理学会
  • Place of Presentation: 岡山大学
  • Year and Date: 2010-03-22
• [Presentation] 多孔性金属錯体CuBDTのO_2ガス吸着構造 (2010)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 小林達生, 高田昌樹, 北川進
  • Organizer: 日本放射光学会
  • Place of Presentation: イーグレ姫路(姫路市)
  • Year and Date: 2010-01-08
• [Presentation] 多孔性金属錯体CID-4に吸着した酸素分子の整列構造 (2010)
  • Author(s): 宮村真理子, 久保田佳基, 堀彰宏, 小林達生, 高田昌樹, 田中大輔, 北川進
  • Organizer: 日本放射光学会
  • Place of Presentation: イーグレ姫路(姫路市)
  • Year and Date: 2010-01-08
• [Presentation] 多孔性金属錯体CID-4に吸着した酸素分子の整列構造 (2010)
  • Author(s): 宮村真理子, 久保田佳基, 堀彰宏, 小林達生, 高田昌樹, 田中大輔, 北川進
  • Organizer: 日本放射光学会
  • Place of Presentation: イーグレ姫路
  • Year and Date: 2010-01-08
• [Presentation] 多孔性金属錯体CuBDTのO_2ガス吸着構造 (2010)
  • Author(s): 鰐川泰, 久保田佳基, 堀彰宏, 小林達生, 高田昌樹, 北川進
  • Organizer: 日本放射光学会
  • Place of Presentation: イーグレ姫路
  • Year and Date: 2010-01-08
• [Presentation] 多孔性金属錯体のナノ細孔に吸着した酸素分子の整列構造と磁性 (2009)
  • Author(s): 久保田佳基
  • Organizer: 日本結晶学会
  • Place of Presentation: 関西学院大学西宮上ヶ原キャンパス(西宮市)
  • Year and Date: 2009-12-06
• [Presentation] 多孔性金属錯体のナノ細孔に吸着した酸素分子の整列構造と磁性 (2009)
  • Author(s): 久保田佳基
  • Organizer: 日本結晶学会
  • Place of Presentation: 関西学院大学西宮上ヶ原キャンパス
  • Year and Date: 2009-12-06
• [Presentation] 多孔性金属錯体Cd(bpndc)(bpy)に吸着した酸素分子の整列構造と磁性II (2009)
  • Author(s): 宮村真理子, 南方千晴, 鰐川泰, 久保田佳基, 堀彰宏, 戸田洋平, 鈴木雄太, 小林達生, 松尾晶, 金道浩一, 高田昌樹, 田中大輔, 北川進
  • Organizer: 日本物理学会
  • Place of Presentation: 熊本大学黒髪キャンパス(熊本市)
  • Year and Date: 2009-09-27
• [Presentation] 多孔性金属錯体Cd(bpndc)(bpy)に吸着した酸素分子の整列構造と磁性II (2009)
  • Author(s): 宮村真理子, 南方千晴, 鰐川泰, 久保田佳基, 堀彰宏, 戸田洋平, 鈴木雄太, 小林達生, 松尾晶, 金道浩一, 高田昌樹, 田中大輔, 北川進
  • Organizer: 日本物理学会
  • Place of Presentation: 熊本大学黒髪キャンパス
  • Year and Date: 2009-09-27