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A study on room-temperature atomic layer deposition by using radical-enhanced surface-stimulation techniques

Research Project

Project/Area Number 21510111
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionYamagata University

Principal Investigator

HIROSE Fumihiko  山形大学, 大学院・理工学研究科, 教授 (50372339)

Co-Investigator(Kenkyū-buntansha) NARITA Yuzuru  山形大学, 大学院・理工学研究科, 助教 (30396543)
Co-Investigator(Renkei-kenkyūsha) KIMURA Yasuo  東北大学, 電気通信研究所, 准教授 (40312673)
NIWANO Michio  東北大学, 電気通信研究所, 教授 (20134075)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords原子層堆積 / 酸化膜 / 堆積 / MOS / 赤外吸収分光 / 吸着 / 絶縁 / C-V / 励起 / 絶縁膜 / 酸化 / ナノ構造形成・制御
Research Abstract

To realize next-generation semiconductor devices with an atomic scale, we developed a room-temperature (RT) atomic layer deposition of SiO2 that might allow the minimum thermal budget in the LSI fabrication. In the course of the research, we directly observed fundamental reactions of source gas adsorption and oxidation. It was found that the hydroxylation process is rate-limiting in ALD at RT. To enhance it, we newly developed a plasma excited water vapor source and demonstrated that it is effective in promoting SiO2 deposition at RT. We demonstrated the RT fabrication of Ge MOS devices, where the process temperature has been desired to be decreased to RT.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (15 results)

All 2012 2011 2010 2009

All Journal Article (9 results) (of which Peer Reviewed: 7 results) Presentation (4 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] IR study of Atomic-layer-deposition of HfO_2 with tetrakis(ethylmethylamino)hafnium (TEMAH), ozone and water vapor2012

    • Author(s)
      F. Hirose, Y. Kinoshita, K. Kanomata, K. Momiyama, S. Kubota, K. Hirahara
    • Journal Title

      Applied Surface Science

      Volume: Vol.258 Pages: 7726-7731

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] IR study of Atomic-layer-deposition of HfO_2 with tetrakis (ethylmethylamino) hafnium (TEMAH), ozone and water vapor2012

    • Author(s)
      F.Hirose, Y.Kinoshita, K.Kanomata, K.Momiyama, S.Kubota, K.Hirahara
    • Journal Title

      Applied Surface Science

      Volume: 258 Issue: 19 Pages: 7726-7731

    • DOI

      10.1016/j.apsusc.2012.04.130

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 赤外吸収分光法を用いたHfO_2原子層堆積法の反応素過程評価2011

    • Author(s)
      廣瀬文彦, 木下友太, 鈴木貴彦
    • Journal Title

      信学技法

      Volume: Vol.111

    • NAID

      110008801100

    • Related Report
      2011 Final Research Report
  • [Journal Article] OHラジカル酸化法の開発とデバイス評価2011

    • Author(s)
      出貝求, 黒沢正章, 籾山克章, 鈴木貴彦, 廣瀬文彦
    • Journal Title

      信学技法

      Volume: Vol.111

    • NAID

      110008801101

    • Related Report
      2011 Final Research Report
  • [Journal Article] Growth kinetics of SiO_2 Atomic layer deposition with tris(dimethylamino)silane (TDMAS) desorption, ozone and water vapor2010

    • Author(s)
      F. Hirose, Y, Kinoshita, S. Shibuya, Y. Narita, Y. Takahashi, H. Miya, K. Hirahara, Y. Kimura, M. Niwano
    • Journal Title

      Thin Solid Films

      Volume: Vol.519 Pages: 270-275

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Growth kinetics of SiO_2 Atomic layer deposition with tris (dimethylamino) silane (TDMAS) dsorption, ozone and water vapor2010

    • Author(s)
      F.Hirose, Y, Kinoshita, S.Shibuya, H.Miya, K.Hirahara, Y.Kimura, M.Niwano
    • Journal Title

      Thin Solid Films

      Volume: 519 Pages: 270-275

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Promotion of power conversion in dye sensitized solar cells with hydroxylated TiO_2 electrodes2010

    • Author(s)
      F.Hirose, M.Shikaku, K.Kuribayashi, T.Suzuki
    • Journal Title

      J.Photopolymer Science and Technology

      Volume: 23 Pages: 287-291

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature-atomic-layer-deposition of SiO2 with tris(dimethylamino)silane (TDMAS) and ozone using a temperature controlled water vapor treatment2009

    • Author(s)
      F. Hirose, Y, Kinoshita, S. Shibuya, H. Miya, K. Hirahara, Y. Kimura, M. Niwano
    • Journal Title

      ECS transaction

      Volume: Vol.19 Pages: 417-427

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature-atomic-layer-deposition of SiO_2 with tris (dimethylamino) silane (TDMAS) and ozone using a temperature controlled water vapor treatment2009

    • Author(s)
      廣瀬文彦、木下友太、渋谷豪、成田克、宮博信、平原和弘、木村康男、庭野道夫
    • Journal Title

      ECS Transactions 19

      Pages: 417-428

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 励起水蒸気を用いた室温ALDにより作製したGe MOSキャパシタの評価2012

    • Author(s)
      出貝求, 籾山克明, 鹿又健作, 久保田繁, 廣瀬文彦
    • Organizer
      応用物理学会全国大会
    • Place of Presentation
      東京・早稲田大学
    • Year and Date
      2012-03-31
    • Related Report
      2011 Final Research Report
  • [Presentation] Room-temperature SiO2 ALD with TDMAS and plasma-excited water vapor2012

    • Author(s)
      F. Hirose
    • Organizer
      3rd International Workshop on Nanostructures & Nanoelectronics
    • Place of Presentation
      仙台・東北大学
    • Year and Date
      2012-03-22
    • Related Report
      2011 Final Research Report
  • [Presentation] 励起水蒸気を用いた室温ALDにより作製したGe MOSキャパシタの評価2012

    • Author(s)
      出貝求, 籾山克明, 鹿又健作, 久保田繁, 廣瀬文彦
    • Organizer
      2011年度春季応用物理学会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Low-temperature-atomic-layer-deposition of SiO_2 with tris (dimethylamino) silane (TDMAS) and ozone using a temperature controlled water vapor treatment2009

    • Author(s)
      廣瀬文彦
    • Organizer
      第215回ECS meeting
    • Place of Presentation
      サンフランシスコ
    • Year and Date
      2009-05-27
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 薄膜形成方法及び装置2012

    • Inventor(s)
      廣瀬文彦, 出貝求
    • Industrial Property Rights Holder
      廣瀬文彦, 出貝求
    • Industrial Property Number
      2012-026697
    • Filing Date
      2012-01-24
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 薄膜形成方法および装置2012

    • Inventor(s)
      廣瀬文彦、出貝求
    • Industrial Property Rights Holder
      廣瀬文彦、出貝求
    • Industrial Property Number
      2012-026697
    • Filing Date
      2012-01-24
    • Related Report
      2011 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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