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Elucidation of Luminescence Mechanism of a Perovskite-type Oxide Phosphor with the Aid of a Monolayer-Forming Technique

Research Project

Project/Area Number 21540333
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics I
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

IKEGAMI Keiichi  独立行政法人産業技術総合研究所, ナノシステム研究部門, 副研究部門長 (50356416)

Co-Investigator(Renkei-kenkyūsha) TAKASHIMA Hiroshi  独立行政法人産業技術総合研究所, 電子光技術研究部門・酸化物デバイスグループ, 主任研究員 (10357353)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords光物性 / ペロブスカイト型酸化物蛍光体 / エネルギー移動 / 単分子膜 / 酸化物蛍光体 / ペロブスカイト蛍光体 / 電界発光 / 蛍光寿命 / LB膜
Research Abstract

We tried to elucidate the luminescence mechanism of a representative perovskite oxide phosphor of PCSTO with the aid of a monolayer-forming technique. The experiments revealed that both the UV and carrier-injection excitations create the same excited state of Pr, that both excitations need ca. 4 eV, and that in the carrier-injection case the recombination with the carriers(carrying opposite charges) trapped at the PCSTO/electrode interface is crucial. Consequently, it is supposed that not the transport of the excitons themselves, but the energy transfer from them excites Pr.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (29 results)

All 2012 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (17 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Nonlinear Electrical Properties of Thin Films of a Light-Emitting Perovskite-Type Oxide Pr_0.002(Ca_0.6Sr_0.4)_0.997TiO_32012

    • Author(s)
      池上敬一、陸明、大野龍造、米川公博、三浦登、高島浩
    • Journal Title

      Procedia Engineering

      Volume: Vol.36 Pages: 388-395

    • DOI

      10.1016/j.proeng.2012.03.057

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nonlinear Electncal Properties of Thin Films of a Light-Emitting Perovskite-Type Oxide Pr_<0.002>(Ca_<0.6>Sr_<0.4>)_<0.997>TiO_32012

    • Author(s)
      池上敬一、陸明、大野龍造、米川公博、三浦登、高島浩
    • Journal Title

      Procedia Engineering

      Volume: (掲載確定)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Langmuir and Langmuir-Blodgett Films of Organic Dye-Inorganic Nanosheet Hybrids2011

    • Author(s)
      バン・スンヒュク、星靖、蛯名武雄、池上敬一
    • Journal Title

      Transactions of the Material Research Society of Japan

      Volume: Vol.36 Pages: 149-152

    • NAID

      130005004115

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Langmuir and Langmuir-Blodgett Films of Organic Dye-Inorganic Nanosheet Hybrids2011

    • Author(s)
      バン スンヒュク、星靖、蛯名武雄、池上敬一
    • Journal Title

      Trans.Mater.Soc.Jpn.

      Volume: Vol.36 Pages: 149-152

    • NAID

      130005004115

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Metal-Insulator-Metal Junction with Metallic Conductive Langmuir-Blodgett Films2011

    • Author(s)
      望月健吾、大貫等、池上敬一、今久保達郎、和泉充
    • Journal Title

      Physics Procedia

      Volume: Vol.14 Pages: 134-138

    • DOI

      10.1016/j.phpro.2011.05.026

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of Anionic Nanosheets from Their Dilute Colloidal Suspensions onto Gas-Liquid Interfaces with and without a Langmuir Film of Cationic Surfactant2010

    • Author(s)
      池上敬一、手塚裕之、星靖、蛯名武雄、高島浩
    • Journal Title

      Langmuir

      Volume: Vol.26 Issue: 4 Pages: 2514-2520

    • DOI

      10.1021/la902788b

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared Reflection-Absorption Spectra of Calcium Icosanate Langmuir-Blodgett Films Observed by Using Zinc Oxide-Based Transparent Electrode and Gold2010

    • Author(s)
      杉本崇、池上敬一、吉山孝志、前島圭剛、柴田肇、反保衆志、仁木栄
    • Journal Title

      Transactions of the Material Research Society of Japan

      Volume: 35 Pages: 323-326

    • NAID

      130003398932

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of Anionic Nanosheets from Their Dilute Colloidal Suspensions onto Gas-Liquid Interfaces with and without a Langmuir Film of Cationic Surfactant2010

    • Author(s)
      池上敬一, 他
    • Journal Title

      Langmuir 26

      Pages: 2514-2520

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] いろいろな色2009

    • Author(s)
      池上敬一
    • Journal Title

      日仏工業技術 55

      Pages: 4-7

    • Related Report
      2009 Annual Research Report
  • [Presentation] 国際同位体標準炭酸塩の微小領域における均質性評価ー超高解像度環境解析に向けて2012

    • Author(s)
      池上敬一、陸明、大野龍造、米川公博、三浦登、高島浩
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Pr_<0.002>(Ca_<0.6>Sr_<0.4>)_<0.997>TiO_3ペロブスカイト蛍光体薄膜の非線形導電現象2012

    • Author(s)
      池上敬一、陸明、大野龍造、米川公博、三浦登、高島浩
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京、早稲田大学
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] ラングミュア・ブロジェット法を用いた金属酸化物-有機単分子膜複合体の作製と応用2012

    • Author(s)
      池上敬一
    • Organizer
      1st Workshop on New Frontiers in Ferroelectrics
    • Place of Presentation
      国立日高青年の家(北海道)
    • Year and Date
      2012-02-22
    • Related Report
      2011 Final Research Report
  • [Presentation] ラングミュア・ブロジェット法を用いた金属酸化物-有機単分子膜複合体の作製と応用2012

    • Author(s)
      池上敬一
    • Organizer
      1st Workshop on New Frontiers in Ferroelectrics
    • Place of Presentation
      北海道、国立日高青年の家(招待講演)
    • Year and Date
      2012-02-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Nonlinear Electrical Current Observed for Thin Films based on a Llght-Emitting Perovskite-Type Oxide Pr_<0.002>(Ca_<0.6>Sr_<0.4>)_<0.997>TiO_3 Directly Sandwiched by Electrodes2011

    • Author(s)
      池上敬一、陸明、大野龍造、米川公博、三浦登、高島浩
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      神奈川、波止場会館
    • Year and Date
      2011-12-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Luminescent Strontium Stannate Films Epitaxially Grown on a Seed-Layer Based on an Organic-Inorganic Hybrid Langmuir-Blodgett Monolayer2011

    • Author(s)
      手塚裕之、高島浩、池上敬一, 南條弘、蛯名武雄、水上富士夫
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      神奈川、波止場会館
    • Year and Date
      2011-12-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Nonlinear Electrical Properties of Thin Fims of a Light-Emitting Perovskite-Type Oxide Pr_<0.002>(Ca_<0.6>Sr_<0.4>)_<0.997>TiO_32011

    • Author(s)
      池上敬一、陸明、大野龍造、米川公博、三浦登、高島浩
    • Organizer
      国際材料研究学会連盟2011年アジア会議(IUMRS-ICA2011)
    • Place of Presentation
      台北(台湾)、台北南港展覧館
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] ペロブスカイト型酸化物CaSrTiO3:Pr単層膜EL素子の発光特性2011

    • Author(s)
      米川公博、大野龍造、三浦登、高島浩、池上敬一
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道、北海道大学
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Fatty-Acid Langmuir-Blodgett Films Deposited on ZnO-Based Transparent Electrodes2010

    • Author(s)
      杉本崇、吉山孝志、前島圭剛、柴田肇、反保衆志、仁木栄、池上敬一
    • Organizer
      第20回日本MRS学術シンポジウム
    • Place of Presentation
      横浜開港記念会館(神奈川県)
    • Year and Date
      2010-12-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] IR Characterization of an Organic-Surfactant-Inorganic-Nanosheet Hybrid LB Films2010

    • Author(s)
      星靖、蛯名武雄、高島浩、池上敬一
    • Organizer
      第20回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化センター(神奈川県)
    • Year and Date
      2010-12-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Langmuir and Langmuir-Blodgett Films of Organic Dye-Inorganic Nanosheet Hybrids2010

    • Author(s)
      バンスンヒュク、星靖、蛯名武雄、池上敬一
    • Organizer
      第20回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化センター(神奈川県)
    • Year and Date
      2010-12-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] N(C_<18>H_<37>)_2(CH_3)_2-Ca_2Nb_3O_<10>ナノシート複合LB膜のIR2010

    • Author(s)
      池上敬一、星靖、蛯名武雄、高島浩
    • Organizer
      応用物理学会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] ZnO-Based Transparent Electrodes as Substrates for Infrared Reflection-Absorption Spectroscopy Characterization of Organized Molecular Films2010

    • Author(s)
      池上敬一、杉本崇、吉山孝志、前島圭剛、柴田肇、反保衆志、仁木栄
    • Organizer
      13th Int.Conf.Organized Molecular Films
    • Place of Presentation
      ケベック市(カナダ)
    • Year and Date
      2010-07-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ca_2Nb_3O_10ナノシートの希薄懸濁液から気水界面への吸着現象II2010

    • Author(s)
      池上敬一, 他
    • Organizer
      第57回 応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] LB法を用いた有機無機ナノ複合体の作成2010

    • Author(s)
      池上敬一
    • Organizer
      電気学会「有機薄膜及び複合膜のナノ界面物性とデバイス・センサ応用調査専門委員会」第12回委員会
    • Place of Presentation
      東京海洋大学(東京都)
    • Year and Date
      2010-02-05
    • Related Report
      2011 Final Research Report
  • [Presentation] LB法を用いた有機無機ナノ複合体の作成2010

    • Author(s)
      池上敬一
    • Organizer
      電気学会 有機薄膜及び複合膜のナノ界面物性とデバイス・センサ応用調査専門委員会 第12回委員会
    • Place of Presentation
      東京海洋大学(東京都)
    • Year and Date
      2010-02-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ca_2Nb_3O_10ナノシートの希薄懸濁液から気水界面への吸着現象2009

    • Author(s)
      池上敬一, 他
    • Organizer
      第70回 応用物理学会学術講演会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Remarks] (1)池上敬一、高島浩、茨城工業高等専門学校(本科生13名+引率教官3名)見学会受入、2010年12月27日、産業技術総合研究所(茨城県)アウトリーチ活動

    • Related Report
      2011 Final Research Report
  • [Remarks] (2)池上敬一、東京海洋大学海洋工学部海洋電子機械工学科(1年生8名+引率教官1名)見学会受入、2011年10月30日、産業技術総合研究所(茨城県)アウトリーチ活動

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] ラングミュア・ブロジェット絶縁薄膜およびその作成方法2010

    • Inventor(s)
      池上敬一、杉本崇、蛯名武雄、星靖大貫等、望月健吾
    • Industrial Property Rights Holder
      産業技術総合研究所、東京海洋大学
    • Industrial Property Number
      2010-047499
    • Filing Date
      2010-03-04
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2020-05-15  

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