Fluorescence Dynamics of Individual Charge-Transfer Complexes and Charge-Transfer Nanocrystals Revealed by Single Molecule Fluorescence Spectroscopy
| Project/Area Number |
21550012
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Kyoto Institute of Technology |
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Principal Investigator |
ITAYA Akira 京都工芸繊維大学, 工芸科学研究科, 教授 (80035071)
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| Co-Investigator(Kenkyū-buntansha) |
MASUO Sadahiro 関西学院大学, 理工学部, 准教授 (80379073)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 1分子計測(SMD) / 共焦点顕微鏡 / ナノ材料 / 蛍光挙動 / 電荷移動錯体 |
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| Research Abstract |
Single molecule fluorescence spectroscopy(SMRS) was applied for elucidating fluorescence dynamics of singly isolated charge-transfer(CT) complexes formed between various monocarbazolyl and dicarbazolyl compounds as donors and 1, 2, 4, 5-tetracyanobenzene as an acceptor in various polymer films. The results of simultaneous measurements(time traces of CT fluorescence intensity and lifetime) showed three patterns of time traces. The ratio of the appearance of these patterns depended on donors and polymers. These results were discussed on the basis of the chemical structure of donors and the free volume of the host polymers. SMFS was also applied to an exciplex system and CT nanocrystals. These results were also discussed.
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Report
(4 results)
Research Products
(11 results)
