Direct observation of the proton/hydrogen-atom transfer reaction under the restricted initial configuration
| Project/Area Number |
21550016
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
ISHIKAWA Haruki 神戸大学, 大学院・理学研究科, 准教授 (80261551)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | プロトン移動反応 / 水素結合クラスター / 赤外分光 / 共鳴2光子イオン化 / 蛍光励起スペクトル / フェノール-ペプチドクラスター / フェノールーペプチドクラスター |
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| Research Abstract |
We have planned to investigate the proton-transfer reaction along the peptides. Using neutral hydrogen-bonded cluster as a precursor, the initial configuration of the reaction can be restricted. In the present study, phenol-amino acid clusters are used as the precursor, where phenol acts as the proton donor. We have recorded resonance-enhanced two-photon ionization and infrared spectra and calculated the optimized structures and their energies. At the present, there are some problems in the cluster production method. Thus, we are planning to continue this study.
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Report
(4 results)
Research Products
(8 results)
