Regio-controlled Functionalization of Endohedral Metallofullerene
Project/Area Number |
21550032
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | University of Tsukuba |
Principal Investigator |
OINUMA Midori 筑波大学, 数理物質系, 講師 (20323256)
|
Co-Investigator(Renkei-kenkyūsha) |
AKASAKA Takeshi 筑波大学, 数理物質系, 教授 (60089810)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | 金属内包フラーレン / 可逆付加反応 / 化学修飾 / カルベン付加 / ラジカル反応 / Diels-Alder反応 |
Research Abstract |
Endohedral metallofullerenes have att racted much attention because of their novel structures and electronic and magnetic properties. In this study, I succeeded in the synthesis of new derivatives of endohedral metallofullerenes by chemical reactions, in which the substituents were regioselectively introduced onto fullerene carbon cage in a high yield. I also succeeded in the characterization of these derivativesby using of spectroscopy and a single-crystal X-ray analysis. The results in this study for functionallization of endohedral metal of ullerenes will be useful for synthesis of derivatives and developing new functional materials
|
Report
(4 results)
Research Products
(34 results)
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[Journal Article] Organosulfur-based Fullerene Materials2011
Author(s)
T.Nakahodo, M.O.Ishitsuka, Y.Takano, T.Tsuchiya, T.Akasaka, A.Herranz, N.Martin, D.M.Guldi, S.Nagase
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Journal Title
Phosphorus, Sulfur, Silicon Relat.Elem.
Volume: 186
Issue: 5
Pages: 1308-1311
DOI
Related Report
Peer Reviewed
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[Journal Article] Photochemical Addition of C_<60> with Siliranes: Synthesis and Characterization of Carbosilylated and Hydrosilylated C_<60> Derivatives2010
Author(s)
J. Nagatsuka, S. Sugitani, M. Kako, T. Nakahodo, N. Mizorogi, M.0. Ishitsuka, Y. Maeda, T. Tsuchiva, T. Akasaka, X. Gao, S. Nagase
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Journal Title
J. Am. Chem. Soc
Volume: 132
Issue: 34
Pages: 12106-12120
DOI
Related Report
Peer Reviewed
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[Journal Article] Anisotropic Magnetic Behavior of Anionic Ce@C_<82> Carbene Adducts2009
Author(s)
Y. Takano, M. Aoyagi, M. Yamada, H. Nikawa, Z. Slanina, N. Mizorogi, M. O. Ishitsuka, T. Tsuchiya, Y. Maeda, T. Akasaka, T. Kato, S. Nagase
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Journal Title
J. Am. Chem. Soc
Volume: 131
Issue: 26
Pages: 9340-9346
DOI
Related Report
Peer Reviewed
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[Presentation] Bis-functionalization of La2@C_<80>2010
Author(s)
M.O. Ishitsuka, S. Sano, H. Enoki, S.Sato, H. Nikawa, T. Tsuchiya, Z. Slanina, N. Mizorogi, T. Akasaka, S. Nagase
Organizer
PACIFICHEM 2010
Place of Presentation
Honolulu, Hawaii, U.S.A
Year and Date
2010-12-15
Related Report
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[Presentation] Organosulfur-based Fullerene Materials2010
Author(s)
T. Nakahodo, M. O. Ishitsuka, Y. Takano, T. Tsuchiya, M. A. Herranz, N. Martin, D. Guldi, S. Nagase, and T. Akasaka
Organizer
24th International Conference on the Organic Chemistry of Sulfur (ISOCS-24)
Place of Presentation
Florence, Italy
Year and Date
2010-07-25
Related Report
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[Presentation] Bis-carbene adduct of La2@C_<80>2010
Author(s)
M. O. Ishitsuka, S. Sano, H. Enoki, S.Sato, H. Nikawa, T. Tsuchiya, Z. Slanina, N. Mizorogi, T. Akasaka, S. Nagase
Organizer
217th ECS Meeting
Place of Presentation
Vancouver, Canada
Year and Date
2010-04-25
Related Report
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