Systematic Studies on the Synthesis of New Tripodal Ligands and Their Metal Complexes for the Activation of Small Molecules
| Project/Area Number |
21550034
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
TAKEDA Nobuhiro 群馬大学, 大学院・工学研究科, 准教授 (80304731)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 三脚型四座配位子 / 金属錯体 / カルコゲノエーテル配位子 / シリル配位子 / ホスフィン配位子 / セレノエーテル配位子 / 10族金属錯体 / 脱離反応 / チオエーテル配位子 / ジメチルパラジウム錯体 / C-Si結合切断反応 / 10族金属 / 五配位錯体 / 平面四配位錯体 |
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| Research Abstract |
Group 10 metal(II) complexes bearing a new tripodal tetradentate ligand, E[C_6H_4(2-YR)]_3 (1,_EYR> : E = P, Si^-; Y = O, S, Se, CH_2S (mS) ; R = i-Pr (Pr), t-Bu (Bu)), were synthesized, and their properties were systematically elucidated. In addition, we succeeded in the synthesis of dimethylpalladium complex, [PdMe_2(1_<PSPr>)], and cationic iridium complex having vacant coordination site, [IrH(1_<SimSBu>)]ClO_4. These complexes are expected to be highly reactive to small molecules such as N_2 and CO_2.
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Report
(4 results)
Research Products
(74 results)
