| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Research Abstract |
Group 10 metal(II) complexes bearing a new tripodal tetradentate ligand, E[C_6H_4(2-YR)]_3 (1,_EYR> : E = P, Si^-; Y = O, S, Se, CH_2S (mS) ; R = i-Pr (Pr), t-Bu (Bu)), were synthesized, and their properties were systematically elucidated. In addition, we succeeded in the synthesis of dimethylpalladium complex, [PdMe_2(1_<PSPr>)], and cationic iridium complex having vacant coordination site, [IrH(1_<SimSBu>)]ClO_4. These complexes are expected to be highly reactive to small molecules such as N_2 and CO_2.
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