Study on the Reaction Mechanism of the Reaction of Isolable Hydrido-chalcogenolato Platinum Complexes with Alkynes
| Project/Area Number |
21550035
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Saitama University |
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Principal Investigator |
ISHII Akihiko 埼玉大学, 大学院・理工学研究科, 教授 (90193242)
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| Co-Investigator(Renkei-kenkyūsha) |
NAKATA Norio 埼玉大学, 大学院・理工学研究科, 助教 (50375416)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 合成化学 / 白金 / カルコゲン元素 / アルキン / ヒドリド |
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| Research Abstract |
The hydroselenation of hydrido-selenolato Pt(II) complexes with alkynes was studied. On the basis of the results employing the complexes having a 9-triptycyl group on the selenium and triphenylphosphine or 1,2-(diphenylphosphino)ethane as the phosphorus ligand, it was revealed that the dissociation of a phosphorus ligand is essential in the initial stage. It is also discovered that the complex having triphenyl phosphite ligands reacts with phenylacetylene to yield the corresponding selenaplatinacycle and styrene.
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Report
(4 results)
Research Products
(19 results)
