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Study on the syntheses and properties of distillable mesoionic liquids as highly polar reaction media

Research Project

Project/Area Number 21550042
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionNagoya Institute of Technology

Principal Investigator

ARAKL Shukl  名古屋工業大学, 大学院・工学研究科, 教授 (30115670)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords反応有機化学 / メソイオン / イオン液体 / 反応媒体 / 高極性液体 / インジウム反応剤 / シクロプロパン / ホモアリルアルコール
Research Abstract

Efficient synthetic methods for distillable mesoionic liquids, 1,3-dialkyltetrazolium-5-olates, have been developed. The preparations and reactions of organoindium reagents in ionic and mesoionic liquids have been studied, and it have been found that the indium reagents allylate aldehydes more effectively than in conventional organic solvents. The characteristics of mesoionic liquids as reaction media, such as high polarity and enhanced donor ability, have been revealed.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (17 results)

All 2012 2011 2010 2009 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (10 results) Remarks (4 results)

  • [Journal Article] Ionic liquid-accelerated allylation of carbonyl compounds with a catalytic amount of indium generated from in situ reduction of InCl_3 with aluminium2011

    • Author(s)
      Tsunehisa Hirashita, Yuki Sato, Dai Yamada, Fusako Takahashi, Shuki Araki
    • Journal Title

      Chemistry Letters

      Volume: 40巻 Pages: 506-507

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] メソイオン液体の設計と特性2011

    • Author(s)
      荒木修喜、平下恒久
    • Journal Title

      ファインケミカル

      Volume: 40 Pages: 6-11

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Ionic liquid-accelerated allylation of carbonyl compounds with a catalytic amount of indium generated from in situ reduction of InCl_3 with aluminium2011

    • Author(s)
      T.Hirashita, 他4名
    • Journal Title

      Chemistry Letters

      Volume: 40 Issue: 5 Pages: 506-507

    • DOI

      10.1246/cl.2011.506

    • NAID

      130004426211

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] アルコールをアルキル化剤とするテトラゾリウム-5-チオレートの選択的合成2012

    • Author(s)
      村上卓, 他3名
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] イオン液体中におけるインジウムを用いたアリル化反応2011

    • Author(s)
      高橋総子・平下恒久・荒木修喜
    • Organizer
      第42回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      長野市
    • Year and Date
      2011-11-05
    • Related Report
      2011 Final Research Report
  • [Presentation] 1,3-ジアルキルテトラゾリウムメソイオンの簡易合成法2011

    • Author(s)
      庄司卓生・鏡味克之・平下恒久・荒木修喜
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      熊本市
    • Year and Date
      2011-10-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 1,3-ジアルキルテトラゾリウムメソイオンの簡易合成法2011

    • Author(s)
      庄司卓生, 他3名
    • Organizer
      第41回複素環化学討論会
    • Place of Presentation
      熊本市民会館
    • Year and Date
      2011-10-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] イオン液体中におけるアルコールのエーテル化反応2011

    • Author(s)
      高橋総子, 他2名
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオン液体中におけるアルコールのエーテル化反応2011

    • Author(s)
      高橋総子・平下恒久・荒木修喜
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜市
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] インジウム反応剤によるジアステレオ選択的シクロプロパン化反応2010

    • Author(s)
      大森加菜子, 他2名
    • Organizer
      第41回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2010-11-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規メソイオン化合物の合成と電気化学的性質2010

    • Author(s)
      大泉省吾・平下恒久・荒木修喜
    • Organizer
      第41回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋市
    • Year and Date
      2010-11-06
    • Related Report
      2011 Final Research Report
  • [Presentation] イオン液体中におけるアリルインジウム反応剤の調製と反応2009

    • Author(s)
      佐藤優貴, 他3名
    • Organizer
      第40回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      岐阜大学
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Mesoionic Liquids as a Novel Polar Solvent2009

    • Author(s)
      Tsunehisa Hirashita, Katsuyuki Kagami, Yoshihito Takami, Yuki Kakumu, Shuki Araki
    • Organizer
      IKCOC-11
    • Place of Presentation
      京都市
    • Year and Date
      2009-11-06
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.ach.nitech.ac.jp/~organic/araki/arakiken.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.ach.nitech.ac.jp/~organic/araki/arakiken.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.ach.nitech.ac.jp/~organic/araki/arakiken.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.ach.nitech.ac.jp/~organic/araki/arakiken.html

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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