| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Research Abstract |
In order to synthesize organic magnetic materials with a persistent triplet carbene as a spin source, three diphenyldiazomethanes having steric protectors and coupling linkers were synthesized, and the corresponding triplet diphenylcarbenes were generated by photolysis of them and characterized. Furthermore, poly(diazo) compounds were synthesized by self-coupling reaction of the diazo compound under mild Sonogashira reaction conditions, and the corresponding polycarbenes were characterized magnetically.
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