Establishment of Extended Hypervalent Chemistry Containing Acetylene Unit Incorporated in Group 16 Elements Through Synthesis and Property Development
| Project/Area Number |
21550046
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Wakayama University |
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Principal Investigator |
HAYASHI Satoko 和歌山大学, システム工学部, 准教授 (00294306)
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| Co-Investigator(Kenkyū-buntansha) |
NAKANISHI Waro 和歌山大学, システム工学部, 教授 (80110807)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2009: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 有機典型元素 / 構造有機化学 / 理論有機化学 / NMR解析 / アセチレン結合 / ジアセチレン結合 / アントラキノン / アントラセン / ジアセチレン結 / 量子化学計算 / 第16族元素 |
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| Research Abstract |
We have developed the extended hypervalent chemistry, which consists of linearσ-type bonds in linearly aligned four or more atoms. Here, we aimed for the establishment of the novel extended hypervalent chemistry containing acetylene unit incorporated in the group 16 elements. Such novel extended hypervalent compounds were prepared that consist of linear molecular(or bond) axes surrounded by atoms helically distributed around the axes. Their structures and properties were determined. Such compounds were also prepared that consist of zig-zag type bonding schemes, which are important to clarify the nature of the novel extended hypervalent bonds. Cyclic system is also under preparation. Inclusion of smaller molecules in the compounds is planning.
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Report
(4 results)
Research Products
(58 results)
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[Journal Article] Synthesis, Structures and Ab Initio Studies of Selenium and Tellurium Bis (carbodithioates and carbothioates)2011
Author(s)
S.Kato, K.Tani, M.Ishida, J.Nonogaki, M.Ebihara, S.Hayashi, W.Nakanishi, O.Niyomura, F.Ando, J.Koketsu
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Journal Title
Dalton Transactions
Volume: 40
Issue: 32
Pages: 8156-8169
DOI
Related Report
Peer Reviewed
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