| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Research Abstract |
With the intention of exploring new diradical species which show dynamic interconversion between recombination and bond cleavage, possible precursor compounds were designed, prepared and characterized. Among those, a spiro-cyclohexadienone compound was found to undergo unusual photoinduced rearrangements via a diradical intermediate. Dynamic proton migration was found in some imino-enamine compounds and in precursor compound for galvinoxyl radicals.
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