| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Research Abstract |
Tube-like channels were constructed by two methods ; one was by connections of metal complexes with intermolecular hydrogen bonds, and the other was by assemblies of 1D polymer complexes. The former compound showed collapse and reconstructions of the channel structures responding to the removal and re-contact of methanol, which was a part of building block of the tube frameworks. Particularly, this function was useful for adsorption of larger guest molecules induced by addition of methanol. The latter compound showed reversible structural changes of the tube-like channels responding to temperature-variation. The phase-transition properties were dependent on kinds of metal ions and guest molecules in the channels.
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