Preparation and Reactivity of Coordinatively Unsaturated Low Valent Noble Metal Clusters with Imido and Phosphinidene Ligand
| Project/Area Number |
21550064
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TAKEMOTO Shin 大阪府立大学, 大学院・理学系研究科, 教授 (20347511)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 有機金属化学 / クラスター錯体 / ルテニウム / 架橋イミド配位子 / 架橋アミド配位子 / 架橋ヒドリド配位子 / 配位不飽和クラスター / スタニレン配位子 / 架橋アルキリジン配位子 / 架橋ビニリデン配位子 / アルキン / 環化付加 / メタラサイクル / 白金 / カーバイド / フィッシャー・トロプシュ反応 / エチリデン |
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| Research Abstract |
Novel homo-and heterometallic clusters of ruthenium, cobalt, and platinum containing bridging imido-or phosphinidene ligands were prepared and both spectroscopically and crystallographically characterized. Unique transformation of substrate molecules including CO, CNR, and alkynes on the cluster readily proceeded on the clusters to give a series of new type of ligand sets via C-C, C-N, and C-H bond formation and C-H bond cleavage.
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Report
(4 results)
Research Products
(49 results)
