Studies on Crystal Structures and Photophysical propertiea of Luminescent Multi-nuclear d10-metal Complexes
Project/Area Number |
21550065
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | University of Hyogo |
Principal Investigator |
OZAWA Yoshiki 兵庫県立大学, 大学院・物質理学研究科, 准教授 (40204200)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
|
Keywords | 銅錯体 / 銀錯体 / 多核金属錯体 / フォトルミネッセンス / 光励起構造 / 量子計算 / サーモクロミズム / 光励起構造解析 / 単結晶X線構造解析 / 金錯体 / メカノクロミズム / 高圧粉末結晶構造解析 / 放射光 / トリフェニルホスフィン |
Research Abstract |
Syntheses and photophysical properties of halogen-or sulferbridged multinuclear metal complexes have been studied. Photoluminescence thermochromism is found for the tetranucler copper(I) iodide triphenylphosphine complex. The single crystal emits green-yellow color under UV illumination at 300 K, which turns orange at 78 K. Multi-temperature X-ray structure analyses demonstrate that the photoemission energy shifts are correlated with a deformation of four-metal core. This phenomenon suggests that the emission properties of these complexes can respond to outer environments in the crystalline-or solid-states.
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Report
(4 results)
Research Products
(38 results)
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[Journal Article] Preparation, crystal structures, spectroscopic and thermal analyses of two co-crystals of[M(H_2O)_6][M(dipic)_2] and(atrH)_2[M(dipic)_2](M=Zn, Ni, dipic=dipicolinate ; atr ;=3-amino-1H-1, 2, 4-triazole) with isostructural crystal systems2012
Author(s)
Tabatabaee, M.; Tahriri, M.; Tahriri, M.; Ozawa, Y.; Neumuller, B.; Fujioka, H.; Toriumi, K.
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Journal Title
Polyhedron
Volume: 33
Issue: 1
Pages: 336-340
DOI
Related Report
Peer Reviewed
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[Journal Article] Structure and Electronic Configuration of an Iron(II) Complex in a LIESST State : A Pump and Probe Method2009
Author(s)
Sheu, C.-F.; Chen, K.; Chen, S.-M.; Wen, Y.-S.; Lee, G.-H.; Chen, J.-M.; Lee, J.-F.; Cheng, B.-M.; Sheu, H.-S.; Yasuda, N.; Ozawa, Y.; Toriumi, K.; Wang, Y.
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Journal Title
Chem. Eur. J.
Volume: 15(10)
Issue: 10
Pages: 2384-2393
DOI
Related Report
Peer Reviewed
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[Journal Article] Structure an Electronic Configuration of an Iron(II)Complex in a LIESST State : A Pump and Probe Method2009
Author(s)
Sheu, C.-F., Chen, K., Chen, S.-M., Wen, Y.-S., Lee, G.-H., Chen, J.-M., Lee, J.-F., Cheng, B.-M., Sheu, H.-S., Yasuda, N., Ozawa, Y., Toriumi, K., Wang, Y.
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Journal Title
Chemistry-A European Journal 15
Pages: 2384-2393
Related Report
Peer Reviewed
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