Investigation of Kaleidoscopic Reactivities of Bis(triarylgermyl) bis(dimethylphenylphosphine) platinum(II)
| Project/Area Number |
21550066
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | C-H活性化 / ゲルマニウムー白金錯体 / 万華鏡反応 / 14族元素-白金錯体 / ゲルマニウム置換白金錯体 / 立体的要因 / 電子的要因 / C-H都合活性化 / トランス体からの還元的脱離反応 / X-線結晶構造解析 / 高周期14族元素 / 還元的脱離 / 炭素-水素結合の活性化 / 白金錯体 / 遷移金属錯体触媒 / 素反応過程 / 新概念 |
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| Research Abstract |
Toly-substituted germyl platinum complexes were prepared and their complexes were characterized by NMR method and X-ray analysis. These complexes underwent smooth cis-trans isomerization, C-H activation, aryl group migration and reductive elimination(Kaleidoscopic reactivates). To get information of kaleidoscopic reactivities of o-toly-substituted germylplatinum complexes(II), synthesis and reactivities of[o-tolMe2Ge] 2PtL2 and(o-tol) 2MeGe] 2PtL2(L=PhMe2P) as model complexes, were prepared and their reactivities were examined. Synthesis and reactivities of aryl-substituted silyl platinum complexes were also examined.
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Report
(4 results)
Research Products
(11 results)
