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Investigation of Kaleidoscopic Reactivities of Bis(triarylgermyl) bis(dimethylphenylphosphine) platinum(II)

Research Project

Project/Area Number 21550066
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionGakushuin University

Principal Investigator

MOCHIDA Kunio  学習院大学, 理学部, 教授 (20118772)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
KeywordsC-H活性化 / ゲルマニウムー白金錯体 / 万華鏡反応 / 14族元素-白金錯体 / ゲルマニウム置換白金錯体 / 立体的要因 / 電子的要因 / C-H都合活性化 / トランス体からの還元的脱離反応 / X-線結晶構造解析 / 高周期14族元素 / 還元的脱離 / 炭素-水素結合の活性化 / 白金錯体 / 遷移金属錯体触媒 / 素反応過程 / 新概念
Research Abstract

Toly-substituted germyl platinum complexes were prepared and their complexes were characterized by NMR method and X-ray analysis. These complexes underwent smooth cis-trans isomerization, C-H activation, aryl group migration and reductive elimination(Kaleidoscopic reactivates). To get information of kaleidoscopic reactivities of o-toly-substituted germylplatinum complexes(II), synthesis and reactivities of[o-tolMe2Ge] 2PtL2 and(o-tol) 2MeGe] 2PtL2(L=PhMe2P) as model complexes, were prepared and their reactivities were examined. Synthesis and reactivities of aryl-substituted silyl platinum complexes were also examined.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (11 results)

All 2011 2010 2009

All Journal Article (9 results) (of which Peer Reviewed: 6 results) Presentation (2 results)

  • [Journal Article] Lewis Base Complexes of an Enantiomeric Germanium(II) Cation Bearing a Bis(oxazoline) Ligand2011

    • Author(s)
      H. Arii, F. Nakadate, K. Mochida, and T. Kawashima
    • Journal Title

      Organometallics

      Volume: 30 Pages: 4471-4474

    • Related Report
      2011 Final Research Report
  • [Journal Article] Ployhedral and Spiro Platinum-Silyl Clusters Bearing Phosphine Ligands2011

    • Author(s)
      H. Arii, T. Takahashi, M. Nanjo, and K. Mochida
    • Journal Title

      Organometallics

      Volume: 30 Pages: 917-920

    • Related Report
      2011 Final Research Report
  • [Journal Article] ジシランの逐次的なSi-H, Si-Si結合活性化を利用した白金.ケイ素暮らしたーの合成2011

    • Author(s)
      有井, 持田
    • Journal Title

      有合化

      Volume: 69 Pages: 1099-1108

    • Related Report
      2011 Final Research Report
  • [Journal Article] ジシランの逐次的なSi-H,Si-SI結合活性化を利用した白金-ケイ素クラスタ-合成2011

    • Author(s)
      有井秀和、持田邦夫
    • Journal Title

      有機合成化学協会誌

      Volume: 69 Pages: 1099-1108

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polyhedral and Spiro Platinum-Silyl Clusters Bearing Phosphine Ligands2011

    • Author(s)
      H.Arii, M.Takahashi, M.Nanjo, K.Mochida
    • Journal Title

      Organometalics

      Volume: 30 Pages: 917-920

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Base Complexes of an Enantiomeric Germaniumu (II) Cation Bearing a Bis(oxazolin) Ligand2011

    • Author(s)
      H.Arii, F.Nakadate, K.Mochida, T.Kawashima
    • Journal Title

      Organometallics

      Volume: 30 Pages: 4471-4474

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of mon- and dinuclear silylplatinum complexes bearing a diphosphino ligands via stepwise bond activation of unsymmetric disilanes2010

    • Author(s)
      H.Arii, M.Takahashi, M.Nanjo, K.Mochida
    • Journal Title

      Dalton Transactions

      Volume: 39 Pages: 6434-6440

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthsesis and Structure of a Trinuclear Platinum Complex with μ3-Silylene Ligands Derived from a Disilane2009

    • Author(s)
      有井秀和
    • Journal Title

      Organometallics 28

      Pages: 4629-4631

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic and Structural Characterization of Copper-Germylene Complexes Bearing an lsopropyl-Substituted B-Diketiminate Ligand2009

    • Author(s)
      有井秀和
    • Journal Title

      Organometallics 28

      Pages: 4909-4911

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation]2010

    • Organizer
      環太平洋交際会議
    • Place of Presentation
      ハワイ
    • Related Report
      2011 Final Research Report
  • [Presentation]2010

    • Organizer
      錯体化学討論会
    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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