Study on the structure of metal complexes in the excited states by circularly polarized luminescence
| Project/Area Number |
21550067
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Seikei University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TSUKUDA Toshiaki 山梨大学, 教育人間科学部, 准教授 (70372943)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 金属錯体化学 / 光化学 / d10金属錯体 / 発光スペクトル / CDスペクトル / CPLスペクトル / 円偏光 / パラジウム錯体 / 銅錯体 / 発光 / 金属錯体 / 励起状態 / ジホスフィン |
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| Research Abstract |
Sensitivity of the circularly polarized luminescence instrument has been enhanced. CPL spectra of some palladium(0), platinum(0), and copper(I) complexes were observed for the first time using the instrument. The structures of the complexes have been discussed based on the results of the CPL spectra as well as the CD spectra of the complexes, and the results of quantum chemical calculations. Very strong CPL signal has been obtained for a europium complex bearing tridentate ligands.
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Report
(4 results)
Research Products
(12 results)
