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Fabrication of Highly Ordered Nanoparticle Arrays Using Block Copolymer Nanotemplate

Research Project

Project/Area Number 21550084
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionKochi University

Principal Investigator

WATANABE Shigeru  高知大学, 教育研究部・総合科学系, 准教授 (70253333)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsブロックコポリマー / ミセル / テンプレート / 自己組織化 / 金ナノ粒子 / 局在表面プラズモン / アレイセンサ / ブロック共重合体 / ブッロク共重合体
Research Abstract

We report a simple, convenient, and inexpensive self-assembly method for nanopatterning gold nanoparticles(AuNPs) on substrates using block copolymer nanotemplates. Well-ordered monolayer films of block copolymer micelles(BCMs) were prepared by self-assembly of polystyrene-block-poly(4-vinylpyridine)(PS-b-P4VP). The films were immersed in a solution of citrate stabilized AuNPs. After immersion, the AuNPs showed hexagonal ordering on individual BCMs. In order to evaluate the possible application of these AuNP arrays in local surface plasmon resonance(LSPR) sensors, we investigated their optical response to molecular recognition phenomena at the surface of the AuNPs.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (35 results)

All 2012 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 7 results) Presentation (25 results) Remarks (1 results)

  • [Journal Article] 糖鎖集積化金ナノ粒子を用いる糖鎖-タンパク質相互作用の高感度分光分析2012

    • Author(s)
      渡辺茂, 山本修司, 合田愛理, 東優磨
    • Journal Title

      分析化学

      Volume: 16 Pages: 49-56

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 生体分子の固定化に最適な金ナノ粒子の開発2011

    • Author(s)
      渡辺茂
    • Journal Title

      BioIndustry

      Volume: 28 Pages: 42-48

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] Surface plasmon resonance scattering and absorption sensing of Concanavalin A using glycoconjugated gold nanoparticles2011

    • Author(s)
      S. Watanabe, S. Yamamoto, K. Yoshida, K. Shinkawa, D. Kumagawa, and H. Seguchi
    • Journal Title

      Supramol. Chem.

      Volume: 23 Pages: 297-303

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thioglucose-Stabilized Gold Nanoparticles as a Novel Platform for Colorimetric Bioassay Based on Nanoparticle Aggregation2010

    • Author(s)
      S. Watanabe, K. Yoshida, K. Shinkawa, D. Kumagawa, and H. Seguchi
    • Journal Title

      Colloids Surf. B

      Volume: 81 Pages: 570-577

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Simple and Convenient Method to Fabricate Hexagonally Ordered Gold Nanoparticle Arrays Using Diblock Copolymer Micelle Template2010

    • Author(s)
      S. Watanabe, S. Nakano, C. Imai, I. R. Laskar, T. Komura, S. Hadano, and T. Iyoda
    • Journal Title

      Chem. Lett.

      Pages: 902-904

    • NAID

      10027184320

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Simple and Convenient Method to Fabricate Hexagonally Ordered Gold Nanoparticle Arrays Using Diblock Copolymer Micelle Template2010

    • Author(s)
      S.Watanabe, S.Nakano, C.Imai, I.R.Laskar, T.Komura, S.Hadano, T.Iyoda
    • Journal Title

      Chem.Lett.

      Pages: 902-904

    • NAID

      10027184320

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thioglucose-Stabilized Gold Nanoparticles as a Novel Platform for Colorimetric Bioassay Based on Nanoparticle Aggregation2010

    • Author(s)
      S.Watanabe, K.Yoshida, K.Shinkawa, D.Kumagawa, H.Seguchi
    • Journal Title

      Colloids Surf.B

      Volume: 81 Pages: 570-577

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高分子ミセル自己組織化テンプレートを利用した金ナノ粒子の組織化2010

    • Author(s)
      中岡慎
    • Journal Title

      高知大学理学部物質科学科物質変換コース平成21年度卒業研究論文集 (印刷中)

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Tuning Surface Interactions to Control Shape and Array Behavior of Diblock Copolymer Micelles on a Silicon Substrate2009

    • Author(s)
      I. R. Laskar, S. Watanabe, M. Hada, H. Yoshida, J. Li, T. Iyoda
    • Journal Title

      Surf. Sci.

      Volume: 603 Pages: 625-631

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] ラクトフェリン修飾金ナノ粒子のレクチン検出薬への応用2012

    • Author(s)
      東優磨,渡辺茂
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ミセルテンプレート法を利用した金ナノ粒子アレイの作製とプラズモンセンサーへの応用2012

    • Author(s)
      竹村晃一,渡辺茂
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ラクトフェリン修飾金ナノ粒子のレクチン検出薬への応用2012

    • Author(s)
      東優磨, 渡辺茂
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ミセルテンプレート法を利用した金ナノ粒子アレイの作製とプラズモンセンサーへの応用2012

    • Author(s)
      竹村晃一, 渡辺茂
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ブロックポリマーテンプレートによる金ナノ粒子アレイの作製とプラズモンセンサーへの応用2011

    • Author(s)
      竹村晃一,渡辺茂
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2011-11-12
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ラクトフェリン修飾金ナノ粒子を利用したレクチンの高感度検出2011

    • Author(s)
      東優磨,渡辺茂
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2011-11-12
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 高分子自己組織化ナノ構造テンプレートを利用したナノ粒子の集積化と応用2011

    • Author(s)
      渡辺茂,竹村晃一
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Fabrication of Gold Nanoparticles Using Diblock Copolymer Micelle Template and Their Application2011

    • Author(s)
      K. Takemura, S. Watanabe
    • Organizer
      nternational Symposium on Green Science 2011
    • Place of Presentation
      Kochi Univ., Japan
    • Year and Date
      2011-09-20
    • Related Report
      2011 Final Research Report
  • [Presentation] Fabrication of Gold Nanoparticles Using Diblock Copolymer Micelle Template and Their Application2011

    • Author(s)
      K.Takemura, S.Watanabe
    • Organizer
      International Symposium on Green Science 2011
    • Place of Presentation
      Kochi Univ./Japan
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 両親媒性ブロック共重合体の自己組織化ナノ構造テンプレートを利用した金ナノ粒子の精密配列とプラズモンセンサーへの応用2011

    • Author(s)
      渡辺茂,矢羽田達也,小村元憲,波多野慎悟,彌田智一
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 糖修飾金ナノ粒子を利用したレクチンの高感度検出2011

    • Author(s)
      山本修司,渡辺茂
    • Organizer
      日本化学会第91春季年会
    • Year and Date
      2011-03-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 指向性自己組織化法を利用した金ナノ粒子アレイの作製とプラズモンセンサーへの応用2011

    • Author(s)
      矢羽田達也,渡辺茂
    • Organizer
      日本化学会第91春季年会
    • Year and Date
      2011-03-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 糖修飾金ナノ粒子を利用したレクチンの高感度検出2011

    • Author(s)
      山本修司, 渡辺茂
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 指向性自己組織化法を利用した金ナノ粒子アレイの作製とプラズモンセンサーへの応用2011

    • Author(s)
      矢羽田達也, 渡辺茂
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金ナノ粒子を利用したバイオセンサーの開発2010

    • Author(s)
      魚谷祐樹, 山本修司, 吉田和真, 渡辺茂
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 両親媒性ブロックコポリマーの自己組織化ナノ構造テンプレートを利用した金ナノ粒子の組織化2010

    • Author(s)
      松永奈美穂, 矢羽田達也, 中岡慎, 今井千絵, 渡辺茂
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] 糖修飾金ナノ粒子を利用したレクチン検出プラズモシセンサーの開発2010

    • Author(s)
      渡辺茂, 吉田和真, 山本修司
    • Organizer
      第4回バイオ関連化学シンポジウム
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Surface Plasmon Resonance and Absorption Sensing of Saccharide-Protein Interactions Based on Glycoconjugated Gold Nanoparticles2010

    • Author(s)
      S. Watanabe, K. Yoshida, D. Kumagawa, H. Seguchi, and K. Shinkawa
    • Organizer
      Fifth International Symposium on Macrocyclic and Supramolecular Chemistry(ISMSC)
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2010-06-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Surface Plasmon Resonance and Absorption Sensing of Saccharide-Protein Interactions Based on Glycoconjugated Gold Nanoparticles2010

    • Author(s)
      S.Watanabe, K.Yoshida, D.Kumagawa, H.Seguchi, K.Shinkawa
    • Organizer
      Fifth International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC)
    • Place of Presentation
      Nara/Japan奈良県新公会堂
    • Year and Date
      2010-06-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金ナノ粒子を利用した比色検出薬の開発2010

    • Author(s)
      渡辺茂
    • Organizer
      第90春季年会(2010)
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] バイオセンシング用糖修飾金ナノ粒子の研究開発2009

    • Author(s)
      吉田和真,熊川大輔,新川桂太郎,渡辺茂
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-08
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 高分子ナノ相分離構造をテンプレートとした金ナノ粒子の組織化に関する研究2009

    • Author(s)
      松永奈美穂,渡辺茂,彌田智一
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-08
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 集積化金ナノ粒子の合成とセンシング機能評価2009

    • Author(s)
      魚谷祐樹,渡辺茂
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] グルコース修飾金ナノ粒子の合成と機能化およびレクチンの比色検出2009

    • Author(s)
      吉田和真,渡辺茂
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 金ナノ粒子を利用した高感度化学センサーの開発2009

    • Author(s)
      渡辺茂
    • Organizer
      第51回中国四国産学連携化学フォーラム
    • Place of Presentation
      高知大学
    • Year and Date
      2009-08-29
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.cc.kochi-u.ac.jp/~watanabe/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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