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Studies on Separation Analysis Based on Dynamic Flow of Solvent Clusters

Research Project

Project/Area Number 21550086
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionSaga University

Principal Investigator

TABATA Masaaki  佐賀大学, 工学系・研究科, 客員研究員 (40039285)

Co-Investigator(Kenkyū-buntansha) TAKAMUKU Toshiyuki  佐賀大学, 工学系・研究科, 准教授 (70291838)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords分離分析 / 混合溶媒 / 溶媒クラスター / イオン液体 / 高分子 / ミクロ溶媒クラスター / 中性子小角散乱 / ミクロ溶媒クラスター抽出分離分析 / キャピラリー流れ分離分析 / キャピラリー分離 / フローインジェクション / FIA
Research Abstract

Looking at solvent structure on a micro scale for the mixture of water with water-soluble organic solvent, the mixture is not homogeneous but heterogeneous, where water and organic solvent molecules self-assemble to form clusters of water and organic solvents separately. When compounds are dissolved in the mixed solvents, water-soluble compounds dissolve in water solvent clusters and organic compounds in organic solvent clusters. Two components(soluble in water and soluble in organic solvent) are automatically separated in the mixed solvent. Based on this idea new separation method has been established without a separation column by using a small capillary tube.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (43 results)

All 2012 2011 2010 2009

All Journal Article (20 results) (of which Peer Reviewed: 19 results) Presentation (22 results) Book (1 results)

  • [Journal Article] Direct Measurement of Equilibrium Constants for Water-soluble Porphyrin with Copper(II) and Cobalt(II) by Differential Pulse Anodic Stripping Voltammetry(DPASV)2012

    • Author(s)
      Md. Kutubi and Masaaki Tabata
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: (Online first) Issue: 02 Pages: 235-243

    • DOI

      10.1142/s1088424612004550

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Efficient DNA Cleavage Induced by RhIII(TMPyP)^<5+> in the Presence of Ascorbic Acid2012

    • Author(s)
      Nanda Gunawardhana, Nanda Gunawardhana, Shingo Homi and Masaaki Tabata
    • Journal Title

      International Journal of Chemistry

      Volume: (in press)

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tabata, Reductively Induced Catalytic DNA Cleavage of Water Soluble RhIII-Br8TMPyP2012

    • Author(s)
      Nanda Gunawardhana and Masaaki Tabata
    • Journal Title

      Catalysis Letters

      Volume: 141/ 12 Issue: 12 Pages: 1803-1807

    • DOI

      10.1007/s10562-011-0718-8

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chika Matsuda他3名, Effects of metal ions(Cu^<2+>, Fe^<2+>, Fe^<3+> on HPLC analysis of catechins2012

    • Author(s)
      Midori Yasuda, Masaki Tabata
    • Journal Title

      Food Chemistry

      Volume: 133 Issue: 2 Pages: 518-525

    • DOI

      10.1016/j.foodchem.2012.01.018

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Efficient DNA Cleavage Induced by RhIII(TMPyP)^<5+> in the Presence of Ascorbic Acid2012

    • Author(s)
      Nanda Gunawardhana, Nanda Gunawardhana, Shingo Homi, Masaaki Tabata
    • Journal Title

      International Journal of Chemistry

      Volume: (in press)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental Evidences for Molecular Origin of low-Q peak in Neutron/ X-ray Scattering of 1-Alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide Ionic Liquids2011

    • Author(s)
      K. Fujii, T. Takamuku
    • Journal Title

      J. Chem. Phys

      Volume: 135 Issue: 24 Pages: 244502-244502

    • DOI

      10.1063/1.3672097

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solvation Properties of Aliphatic Alcohol-Water and Fluorinated Alcohol-Water Solutions for Amide Molecules Studied by IR and NMR Techniques2011

    • Author(s)
      T. Takamuku
    • Journal Title

      J. Solution Chem

      Volume: 40 Issue: 12 Pages: 2046-2056

    • DOI

      10.1007/s10953-011-9773-4

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Clusters of Imidazolium-based Ionic Liquid in Benzene Solution2011

    • Author(s)
      T. Shimomura, T. Takamuku
    • Journal Title

      J. Phys. Chem. B

      Volume: 115 Issue: 26 Pages: 8518-8527

    • DOI

      10.1021/jp203422z

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A convenient and eco-friendly way to synthesis Pt(II)-and Pd(II)-porphyrins in ionic liquids by microwave activation2011

    • Author(s)
      N. Gunawardhana ; M. Tabata
    • Journal Title

      Environmental Communication Letters

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 溶媒特性をつくり出す分子間相互作用のミクロスコピックな観測2011

    • Author(s)
      高椋利幸
    • Journal Title

      電気化学会第78回大会

    • Related Report
      2011 Final Research Report
  • [Journal Article] A convenient and eco-friendly way to synthesize Pt(II) and Pd(II) porphyrins in ionic liquids by microwave activation2011

    • Author(s)
      Nanda Gunawardhana・Masaaki Tabata
    • Journal Title

      Environ Chem Lett

      Volume: 9 Issue: 4 Pages: 473-477

    • DOI

      10.1007/s10311-010-0304-0

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A convenient and eco-friendly way to synthesis Pt(II)- and Pd(II)- porphyrins in ionic liquids by microwave activation2011

    • Author(s)
      N.Gunawardhana ; M.Tabata
    • Journal Title

      Environmental Communication Letters

      Volume: (On line First)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Alkyl-chain Length on Mixing State of Imidazolium-based Ionic Liquid. Methanol Solutions2010

    • Author(s)
      T. Shimomura, T. Takamuku
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 12 Pages: 12316-12324

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solvation of the Amphiphilic Diol Molecule in Aliphatic Alcohol-Water and Fluorinated Alcohol-Water Solutions2010

    • Author(s)
      T. Takamuku
    • Journal Title

      J. Phys. Chem. B

      Volume: 114 Pages: 4252-4260

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced dechlorination of chlorobenznene compounds on fly ash : effects of metals, solvents, and temperature2010

    • Author(s)
      A.Ghaffar ; M.Tabata
    • Journal Title

      Green Chemistry Letters and Reviews

      Volume: 3 Pages: 179-190

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Alkyl-chain Length on Mixing State of Imidazolium-based Ionic Liquid-Methanol Solutions2010

    • Author(s)
      T.Shimomura
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 12 Pages: 12316-12324

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvation of the Amphiphilic Diol Molecule in Aliphatic Alcohol-Water and Fluorinated Alcohol-Water Solutions2010

    • Author(s)
      T.Takamuku
    • Journal Title

      J.Phys.Chem.B

      Volume: 114 Pages: 4252-4260

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Equilibrium Studies on Lithium(I) Transfer into Ionic Liquid with a Water-soluble Octabromoporphyrin(H_2(OBTMPyP)^<4+>)from Aqueous Phase.2009

    • Author(s)
      Masaaki Tabata, Takuya Shimomura
    • Journal Title

      J.Porphyrins and Phthalocyanines 13

      Pages: 849-853

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dechlorination of p-nitrochlorobenzene using fly ash ; effects of metals ; mixed solvents and temperature.2009

    • Author(s)
      Abdul Ghaffar, Masaaki Tabata.
    • Journal Title

      Reaction Kinetics and Catalysis Letters 97

      Pages: 35-41

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Water on Structure of Hydrophilic Imidazolium-based Ionic Liquid,2009

    • Author(s)
      T.Takamuku, Y.Kyoshoin, T.Shimomura, S.Kittaka, T.Yamaguchi
    • Journal Title

      J.Phys.Chem.B 113

      Pages: 10817-10824

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] イミダゾリウム系イオン液体と分子性液体の混合に関する分子論的研究2012

    • Author(s)
      高椋利幸
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松市
    • Year and Date
      2012-03-29
    • Related Report
      2011 Final Research Report
  • [Presentation] イミダゾリウム系イオン液体と分子性液体の混合に関する分子論的研究2012

    • Author(s)
      高椋利幸
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松市(依頼講演)
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] SANS法でみる分子性液体中におけるイオン液体の会合体形成2012

    • Author(s)
      高椋利幸
    • Organizer
      第3回中性子小角散乱解析法研究会
    • Place of Presentation
      大阪府
    • Year and Date
      2012-02-28
    • Related Report
      2011 Final Research Report
  • [Presentation] SANS法でみる分子性液体中におけるイオン液体の会合体形成2012

    • Author(s)
      高椋利幸
    • Organizer
      第3回中性子小角散乱解析法研究会
    • Place of Presentation
      大阪府(招待講演)
    • Year and Date
      2012-02-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] ^7Li,^<23> Na NMR法で観測した塩化アルカリ塩誘起によるアセトニトリル-水混合溶液の相分離2011

    • Author(s)
      原槙宏樹, 高椋利幸
    • Organizer
      第34回溶液化学シンポジウム
    • Place of Presentation
      名古屋市
    • Year and Date
      2011-11-16
    • Related Report
      2011 Final Research Report
  • [Presentation] ^7Li,^<23>Na NMR法で観測した塩化アルカリ塩誘起によるアセトニトリル-水混合溶液の相分離2011

    • Author(s)
      原槙宏樹
    • Organizer
      第34回溶液化学シンポジウム
    • Place of Presentation
      名古屋市
    • Year and Date
      2011-11-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 溶媒特性をつくり出す分子間相互作用のミクロスコピックな観測2011

    • Author(s)
      高椋利幸
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜(招待講演)
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] EFFECTS OF METAL IONS(Cu^<2+>, Fe^<2+>, Fe^<3+>) ON HPLC ANALYSIS OF CATECHINS2011

    • Author(s)
      Midori Yasuda, , Chika Matsuda, Ayumi Ohshiro, Kuniyo Inouye, Masaaki Tabata
    • Organizer
      International Congress on Analytical Sciences
    • Place of Presentation
      京都市
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロ波エネルギーによる発光錯体の高速、高効率合成とその分析評価2011

    • Author(s)
      松村竹子・増田嘉孝・中島理一郎・田端正明・山下文子・鵜飼佑輝・田畑英恒・清水尚登
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋市
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] EFFECTS OF METAL IONS (Cu^<2+>, Fe^<2+>, Fe^<3+>) ON HPLC ANALYSIS OF CATECHINS2011

    • Author(s)
      Midori Yasuda, Chika Matsuda, Ayumi Ohshiro, Kuniyo Inouye, Masaaki Tabata
    • Organizer
      International Congress on Analytical Sciences 2011
    • Place of Presentation
      京都市
    • Related Report
      2011 Annual Research Report
  • [Presentation] アスベスト繊維の常温分解過程におけるXANES法によるイオウの酸化状態の研究2011

    • Author(s)
      田端正明・大谷亮太・岡島敏浩・庄野章文・納富啓一
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋市
    • Related Report
      2011 Annual Research Report
  • [Presentation] 硝酸をマトリックスモディファイヤーとして添加した有明海水中の微量鉄の定量2011

    • Author(s)
      綿貫岳人・西本潤・田端正明
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋市
    • Related Report
      2011 Annual Research Report
  • [Presentation] X線および中性子散乱によるミクロからメゾスケールにおける溶液構造の研究2010

    • Author(s)
      高椋利幸
    • Organizer
      第33回溶液化学シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2010-11-17
    • Related Report
      2011 Final Research Report
  • [Presentation] X線および中性子散乱によるミクロからメゾスケールにおける溶液構造の研究2010

    • Author(s)
      高椋利幸
    • Organizer
      第33回溶液化学シンポジウム
    • Place of Presentation
      京都(招待講演)
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Capillary flow separation using aqueous mixed solvents of ionic liquids2010

    • Author(s)
      M. Tabata ; K. Fujii ; C. Thiraporn
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Hawaii, USA.
    • Related Report
      2011 Final Research Report
  • [Presentation] Effects of water-soluble polymers on a capillary flow analysis using aqueous mixed solvents2010

    • Author(s)
      M. Tabata ; K. Fujii ; C. Thiraporn
    • Organizer
      The 16 International Conference on Flow Injection Analysis
    • Place of Presentation
      Thailand
    • Related Report
      2011 Final Research Report
  • [Presentation] Effects of water-soluble polymers on a capillary flow analysis using aqueous mixed solvents2010

    • Author(s)
      M.Tabata ; K.Fujii ; C.Thiraporn
    • Organizer
      The 16 International Conference on Flow Injection Analysis
    • Place of Presentation
      Thaiand
    • Related Report
      2010 Annual Research Report
  • [Presentation] Capillary flow separation using aqueous mixed solvents of ionic liquids2010

    • Author(s)
      M.Tabata ; K.Fujii ; C.Thiraporn
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Hawaii, USA(招待講演)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 分離試薬としてのイオン液体、水溶性有機溶媒2009

    • Author(s)
      田端正明
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道、札幌
    • Related Report
      2011 Final Research Report
  • [Presentation] 分離試薬としてのイオン液体、水溶性有機溶媒2009

    • Author(s)
      田端正明
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高分子を含むイオン液体のキャピラリー分離分析法の機能向上と溶媒構造2009

    • Author(s)
      藤井健太・Charoenraks Thiraporn・田端正明
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] イオン液体/水混合溶媒のミクロ溶媒クラスター抽出分離 : 高分子の効果2009

    • Author(s)
      田端正明・Charoenraks Thirapom・藤井健太
    • Organizer
      第70回分析化学討論会
    • Place of Presentation
      和歌山大学
    • Related Report
      2009 Annual Research Report
  • [Book] 錯体の溶液化学2012

    • Author(s)
      横山、田端編
    • Publisher
      三共出版
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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