| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Research Abstract |
New asymmetric cycloisomerization reactions catalyzed by chiral amines have been developed to produce useful optically active furan- and pyran-containing heterobiaryl compounds with axial chirality. Novel chiral carbasugars, which would exhibit unique bioactivities, were also synthesized by using base-catalyzed rearrangement of endoperoxide. Furthermore, unprecedented optically active transition metal complexes with chirality at metal were prepared from a chiral tripodal tetradentate ligand based on tertially amine bearing three different coordination groups.
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