| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Research Abstract |
In this study, various main-chain/side-chain type alternating copolymers containing aromatic rings in the main chains were developed by controlled radical ring-opening polymerization for the purpose of precise synthesis of alternating copolymers consisting of a combination of specific functional groups and emergence of novel functions derived from the alternating arrangement. Alternating copolymers composed of conjugated/non-conjugated monomers were also synthesized by reversible addition-fragmentation chain transfer (RAFT) copolymerization of non-conjugated N-vinyl monomers. These results indicated the feasibility to develop functional alternating copolymers with alternating arrangement of specific functional groups, such as donor and acceptor.
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