Synthesis of pi-Conjugated Polymers with Electrically Interacting Side Chains and Their Chemical Properties

• Project/Area Number: 21550113
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: YAMAMOTO Takakazu 東京工業大学, 資源化学研究所, 特任教授 (10016743)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: 機能性高分子 / 高分子合成 / 高分子構造・物性 / パイ共役高分子 / 紫外・可視スペクトル / 蛍光スペクトル / 電気化学的応答 / 芳香族高分子 / 複素環高分子 / 自己集積化 / ポリチオフェン類 / ポリフェニレン類 / ポリチアゾール類 / 導電性 / 自己組織化 / アルキニル基 / 電荷 / アゾール

Research Abstract

Polymers consisting of aromatic rings and/or heterocycles were synthesized by organometallic polycondensation using metal complexes such as nickel complexes. The polymers contained side chains such as alkynyl groups and oligo-thiophene units. Electronic and optical properties as well as molecular assembly of the polymers were investigated.

Research Products

• [Journal Article] pi-Conjugated Polymers Consisting of 9, 10-Dihydrophenanthrene Units (2011)
  • Author(s): 山本隆一、時光亮一, ほか6名
  • Journal Title: Macromol. Chem. Phys. Volume: 212巻 Pages: 2406-2416
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of New pi-Conjugated Polymers Containing 1, 8-Naphthyridine in the Main Chain : Role of the 1, 8-Naphthyridine Units in pi-Conjugated Polymers (2011)
  • Author(s): 小泉武昭、加藤真一郎、山本隆一
  • Journal Title: J. Polym. Sci. Part A : Polym. Chem. Volume: 49巻 Pages: 4204-4212
  • Peer Reviewed
• [Journal Article] Bithiophene-Bithiazole Alternating Copolymers with Thiophene Side Chains : Synthesis by Organometallic Polycondensation and Chemical Properties of the Copolymers (2011)
  • Author(s): 山本隆一、大塚峻一, ほか6名
  • Journal Title: J. Polym. Sci. Part A : Polym. Chem. Volume: 48巻 Pages: 1508-1512
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of New pi-Conjugated Polymers Containing 1,8-Naphthyridine in the Main Chain (2011)
  • Author(s): T.-A.Koizumi, S.Kato, T.Yamamoto
  • Journal Title: J.Polym.Sci.Part A : Polym.Chem. Volume: 49 Issue: 19 Pages: 4204-4212
  • DOI: 10.1002/pola.24862
  • Peer Reviewed
• [Journal Article] pi-Conjugated Polymers Consisting of 9,10-Dihydrophenanthrene Units (2011)
  • Author(s): T.Yamamoto, et al.
  • Journal Title: Macromolecular Chemistry and Physics Volume: 212 Issue: 22 Pages: 2406-2416
  • DOI: 10.1002/macp.201100310
  • Peer Reviewed
• [Journal Article] Bithiophene-Bithiazole Alternating Copolymers with Thiophene Side Chains (2011)
  • Author(s): T.Yamamoto, et al.
  • Journal Title: J.Polym.Sci.Part A : Polym.Chem. Volume: 48 Pages: 1508-1512
  • Peer Reviewed
• [Journal Article] pi-Conjugated Poly(aryleneethynylene) s Consisting of Salophene and Ni-Salophen Units in the pi-Conjugated Main Chain : Preparation and Chemical Properties (2010)
  • Author(s): 福元博基、山根一人、加瀬由美子、山本隆一
  • Journal Title: Macromolecules Volume: 43巻 Pages: 10366-10375
  • Peer Reviewed
• [Journal Article] Synthesis of New Thiophene-Based pi-Conjugated Organic Compounds and Polymer (2010)
  • Author(s): 臼井元章、福元博基、山本隆一
  • Journal Title: Polymer, Bull. Chem. Soc. Jpn. Volume: 83巻 Pages: 11397-1399
  • NAID: 130004152681
  • Peer Reviewed
• [Journal Article] pi-Conjugated Polymers Consisting of Isothianaphthene and Dialkoxy-p-phenylene Units : Synthesis, Self-Assembly, and Chemical and Physical Properties (2010)
  • Author(s): 山本隆一、臼井元章, ほか14名
  • Journal Title: Macromol. Chem. Phys Volume: 211巻 Pages: 2138-2147
  • Peer Reviewed
• [Journal Article] Synthesis and Chiroptical Properties of pi-Conjugated Polymers Consisting of Dihydropentahelicene Units with Axial Chirality (2010)
  • Author(s): 阿部正宏、大森建、鈴木啓介、山本隆一
  • Journal Title: J. Polym. Sci. Part A : Polym. Chem Volume: 48巻 Pages: 1844-1848
  • Peer Reviewed
• [Journal Article] Molecular assembly and properties of polythiophenes (2010)
  • Author(s): 山本隆一
  • Journal Title: NPG Asia Mater Volume: 2巻 Pages: 152-155
  • Peer Reviewed
• [Journal Article] Synthesis of pi-Conjugated Polymers by Organometallic Polycondensation (2010)
  • Author(s): 山本隆一
  • Journal Title: Bull. Chem. Soc. Jpn Volume: 83巻 Pages: 431-455
  • Peer Reviewed
• [Journal Article] Synthesis and Chiroptical Properties of pi-Conjugated Polymers Consisting of Dihydropentahelicene Units with Axial Chirality (2010)
  • Author(s): M.Abe, K.Ohmori, K.Suzuki, T.Yamamoto
  • Journal Title: J.Polym.Sci.Part A : Polym.Chem. Volume: 48 Pages: 1844-1848
  • Peer Reviewed
• [Journal Article] Pi-conjugated Polymers Consisting of Isothianaphthene (2010)
  • Author(s): T.Yamamoto, et al.
  • Journal Title: Macromol.Chem.Phys. Volume: 211 Pages: 2138-2147
  • Peer Reviewed
• [Journal Article] Highly Coplanar Polythiophene with-C≡CR Side Chains : Self-Assembly, Linear and Nonlinear Optical Properties, and Piezochromism (2009)
  • Author(s): 山本隆一、佐藤貴夫, ほか17名
  • Journal Title: Bull. Chem. Soc. Jpn Volume: 82巻 Pages: 896-909
  • NAID: 10025126539
  • Peer Reviewed
• [Journal Article] pi-Conjugated poly(pyrimido[ 5, 4-d] pyrimidine-2, 6-diyl) s with two different alkylamido groups (2009)
  • Author(s): 福元博基、高月さやか、李芳燐、山本隆一
  • Journal Title: Synthesis, chemical properties, and structure, Synth. Met Volume: 159巻 Pages: 900-904
  • Peer Reviewed
• [Journal Article] Highly Coplanar Polythiophenes with -C≡C-R Side Chains : Self-Assembly, Linear and Nonlinear Optical Properties, and Piezochromism (2009)
  • Author(s): T.Yamamoto, et al.
  • Journal Title: Bull.Chem.Soc.Jpn. 82 Pages: 896-909
  • NAID: 10025126539
  • Peer Reviewed
• [Journal Article] Pi-Conjugated poly (pyrimido [5, 4-d] pyrimidine-2, 6-diyl)s with two different alkylamino groups : Synthesis, chemical properties, and structure. (2009)
  • Author(s): H.Fukumoto, et al.
  • Journal Title: Synthetic Metals 159 Pages: 900-904
  • Peer Reviewed
• [Presentation] Preparation of New pi-Conjugated Polymers by Organometallic Polycondensation (2010)
  • Author(s): 山本隆一
  • Organizer: International Conference on Science and Technology of Synthetic Metals 2010
  • Place of Presentation: 京都国際会議場
  • Year and Date: 2010-07-07
• [Presentation] 新規ジブロモピリジン誘導体の合成と応用 (2010)
  • Author(s): 熊谷尚人、福元博基、山本隆一
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-27
• [Presentation] (2009)
  • Author(s): 鯉江周作、田中玄太郎、福元博基、小泉武昭、山本隆一
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-17
• [Presentation] 4-アミノ-1,2,4-トリアゾールをン主鎖に有するπ共役高分子の合成と物性 (2009)
  • Author(s): 鯉江周作、山本隆一, ほか
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学、黒髪北地区
  • Year and Date: 2009-09-17
• [Book] Encyclopedia of Nanostructure and Nanotechnology (2011)
  • Author(s): 山本隆一, 他
  • Publisher: American Scientific Publishers
• [Book] Conjugated Polymer Synthesis (2010)
  • Author(s): 山本隆一, 他
  • Publisher: Wiley-VCH