Control of nanoporous structures induced by fluorine-containing block copolymers and star-branched polymers

• Project/Area Number: 21550114
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Hosei University (2010-2011); Tokyo Institute of Technology (2009)
• Principal Investigator: SUGIYAMA Kenji 法政大学, 生命科学部, 准教授 (20282840)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
• Keywords: 高分子合成 / リビングアニオン重合 / パーフルオロアルキル基 / 官能基化ポリマー / 表面解析 / X線光電子分光法 / 接触角測定 / 撥油性 / 撥水性 / リビンダアニオン重合

Research Abstract

The precise syntheses of the fluorine-containing block copolymers and star-branched polymers have been successfully established on the basis of living anionic polymerization techniques. Supercritical carbon dioxide processing of the obtained polymer films induced the hydro-and oleophobic film surface formation due to the highly enrichment of fluorine components at the top of film surfaces. In addition, the phase transition behavior of nano-structures was examined under supercritical carbon dioxide conditions in order to optimize the processing conditions to control the size and shape of the nanoporous structures.

Research Products

• [Journal Article] パーフルオロアルキル基を含むポリマーの表面構造解析 (2011)
  • Author(s): 杉山賢次
  • Journal Title: 高分子 Volume: 60 Pages: 673-674
  • NAID: 10029472648
• [Journal Article] リビングアニオン重合による分岐ポリマーの精密合成 (2011)
  • Author(s): 杉山賢次
  • Journal Title: 成形加工 Volume: 23 Pages: 524-531
• [Journal Article] Facile synthes is of triblock co-and terpolymers of styrene, 2-viniylpyridine, and m ethyl methacrylate by a new methodo logy combining living anionic diblo ck copolymers with a specially desi gned linking reaction (2011)
  • Author(s): A. Hirao, Y. Matsuo, T. Oie, R. Gos eki, T. Ishizone, K. Sugiyama, A. G roeschel, A. Mueller
  • Journal Title: Macromolecules Volume: 44 Pages: 6345-6355
  • Peer Reviewed
• [Journal Article] Synth esis and morphology of new asymmetr ic star polymers of poly [4-(9, 9-dih exylfloren-2-yl) styrene]-block-poly(2-vinylpyridine) and their non-vol atile memory device applications (2011)
  • Author(s): J.-C. Hsu, C. Li, K. Sugiyama, R. M ezzenga, A. Hirao, W.-C. Chen
  • Journal Title: Soft Matter Volume: 7 Pages: 8440-8449
  • Peer Reviewed
• [Journal Article] Facile synthetic approach to exact graft(co) polymers and double-tailed polystyrene : linking reaction of living anionic polymers with specially designed in-chain-multifunctionalized polystyrenes (2011)
  • Author(s): A. Hirao, M. Uematsu, R. Kurokawa, T. Ishizone, K. Sugiyama
  • Journal Title: Macromolecules Volume: 44 Pages: 5638-5649
  • Peer Reviewed
• [Journal Article] Precise synthesis of thermo-responsive and water-sol uble star-branched polymers and sta r block copolymers by living anioni c polymerization (2011)
  • Author(s): A. Hirao, R. Inushima, T. Nakayama, T. Watanabe, H.-S. Yoo, T. Ishizon e, K. Sugiyama, T. Kakuchi, S. Carl otti, A. Deffieux
  • Journal Title: Eur. Polym. J Volume: 47 Pages: 713-722
  • Peer Reviewed
• [Journal Article] A supramolecular approach on using poly(fluorenyls tyrene)-block-poly-(2-vinylpyridin e): PCBM composite thin films for non-volatile memory device applications (2011)
  • Author(s): J.-C. Hsu, C.-L. Liu, W.-C. Chen, K. Sugiyama, A. Hirao
  • Journal Title: Macromol. Rapid Commun Volume: 32 Pages: 528-533
  • Peer Reviewed
• [Journal Article] Thermally robust nanocellular thin films of h igh-Tg semifluorinated block copoly mers foamed with supercritical carb on dioxide (2011)
  • Author(s): R. Zhang, C. Dutriez, K. Sugiyama, T. Ishizone, H. Yokoyama
  • Journal Title: Soft Matter Volume: 7 Pages: 4032-4038
  • Peer Reviewed
• [Journal Article] Synthesis of well-defined miktoar m star-branched polymers consisting of perfluorinated segments by a no vel methodology using soluble in-chain-benzylbromide-functionalized A B diblock copolymers as key buildin gblocks (2011)
  • Author(s): A. Abouelmagd, K. Sugiyama, A. Hirao
  • Journal Title: Macromolecules Volume: 44 Pages: 826-834
  • Peer Reviewed
• [Journal Article] Facile synthesis of triblock co- and terpolymers of styrene, 2VP, and MMA by a new methodology combining living anionic polymers with a specially designed linking reaction (2011)
  • Author(s): A.Hirao, Y.Matsuo, T.Oie, R.Goseki, T.Ishizone, K.Sugiyama, A.H.Groeschel, A.H.E.Mueller
  • Journal Title: Macromolecules Volume: 44 Issue: 16 Pages: 6346-6355
  • DOI: 10.1021/ma201352z
  • Peer Reviewed
• [Journal Article] Synthesis and morphology of new asymmetric star polymers of poly[4-(9,9-dihexylfloren-2-y)styrene]-block-poly(2-vinylpyridine) and their non-volatile memory device applications (2011)
  • Author(s): Jung-Ching Hsu
  • Journal Title: Soft Matter. Volume: 7 Issue: 18 Pages: 8440-8449
  • DOI: 10.1039/c1sm05792h
  • Peer Reviewed
• [Journal Article] Facile Synthetic Approach to Exact Graft (Co)polymers and Double-Tailed Polystyrene : Linking Reaction of Living Anionic Polymers with Specially Designed In-Chain-Multifunctionalized Polystyrenes (2011)
  • Author(s): Akira Hirao
  • Journal Title: Macromolecules Volume: 44 Issue: 14 Pages: 5638-5649
  • DOI: 10.1021/ma200956x
  • Peer Reviewed
• [Journal Article] Precise synthesis of thermo-responsive and water-soluble star-branched polymers and star-block copolymers by living anionic polymerization (2011)
  • Author(s): A.Hirao, R.Inushima, T.Nakayama, T.Watanabe, H.-S.Yoo, T.Ishizone, K.Sugiyama, T.Kakuchi, S.Carlotti, A.Deffieux
  • Journal Title: Eur.Polym.J. Volume: 47 Issue: 4 Pages: 713-722
  • DOI: 10.1016/j.eurpolymj.2010.11.003
  • Peer Reviewed
• [Journal Article] A Supramolecular Approach on Using Poly(fluorenylstyrene)-block-poly-(2-vinylpyridine) : PCBM Composite Thin Films for Non-Volatile Memory Device Applications (2011)
  • Author(s): Jung-Ching Hsu
  • Journal Title: Macromol.Rapid Commun. Volume: 32 Issue: 6 Pages: 528-533
  • DOI: 10.1002/marc.201000695
  • Peer Reviewed
• [Journal Article] Thermally robust nanocellular thin films of high-Tg semifluorinated block copolymers foamed with supercritical carbon dioxide (2011)
  • Author(s): Rui Zhang
  • Journal Title: Soft Matter. Volume: 7 Issue: 8 Pages: 4032-4038
  • DOI: 10.1039/c0sm00736f
  • Peer Reviewed
• [Journal Article] Synthesis of Well-Defined Miktoarm Star-Branched Polymers Consisting of Perfluorinated Segments by a Novel Methodology Using Soluble In-Chain-Benzyl Bromide-Functionalized AB Diblock Copolymers as Key Building Blocks (2011)
  • Author(s): Ahmed Abouelmagd
  • Journal Title: Macromolecules Volume: 44 Pages: 826-834
  • Peer Reviewed
• [Journal Article] Synthesis of new star-shaped polymers with styre ne-fluorene conjugated moieties and their multicolor luminescent order ed microporous films (2010)
  • Author(s): J.-C. Hsu, K. Sugiyama, Y.-C. Chiu, A. Hirao, W.-C. Chen
  • Journal Title: Macromolecules Volume: 43 Pages: 7151-7158
  • Peer Reviewed
• [Journal Article] Synthesis of well-defined(AB) n multiblock copolymers compos ed of polystyrene and poly(methyl m ethacrylate) segments using special ly designed living AB diblock copol ymer anion (2010)
  • Author(s): K. Sugiyama, T. Oie, A. Abouelmagd, A. Hirao
  • Journal Title: Macromolecules Volume: 43 Pages: 1403-1410
  • Peer Reviewed
• [Journal Article] Synthesis of New Star-Shaped Polymers with Styrene-Fluorene Conjugated Moieties and Their Multicolor Luminescent Ordered Microporous Films (2010)
  • Author(s): J.-C.Hsu, K.Sugiyama, Y.-C.Chiu, A.Hirao, W.-C.Chen
  • Journal Title: Macromolecules Volume: 43 Pages: 7151-7158
  • Peer Reviewed
• [Journal Article] Synthesis of Well-Defined (AB)n Multiblock Copolymers Composed of Polystyrene and Poly(methyl methacrylate) Segments Using Specially Designed Living AB Diblock Copolymer Anion (2010)
  • Author(s): K.Sugiyama, T.Oie, A.Abou E1-Magd, A.Hirao
  • Journal Title: Macromolecules Volume: 43 Pages: 1403-1410
  • Peer Reviewed
• [Journal Article] Precise synt hesis of exact graft copolymers, po ly(methyl methacrylate)-exact graft-polystyrene, by iterative methodol ogy using a specially designed in-c hain-functionalized AB diblock copo lymer anion (2009)
  • Author(s): A. Hirao, K. Murano, R. Kurokawa, T. Watanabe, K. Sugiyama
  • Journal Title: Macromolecules Volume: 42 Pages: 7820-7827
  • Peer Reviewed
• [Journal Article] Synthe sis and self-assembly behavior of poly(fluorenystyrene)-block-poly(2-v inylpyridine) block copolymers and their blends with SWCNT's (2009)
  • Author(s): C. Li, J.-C. Hsu, K. Sugiyama, A. H irao, W.-C Chen, R. Mezzenga
  • Journal Title: Macromole cules Volume: 42 Pages: 5793-5801
  • Peer Reviewed
• [Journal Article] Non-volatile me mory devices based on polystyrene d erivatives with electron-donating o ligofluorene pendent moieties (2009)
  • Author(s): C.-L. Liu, J.-C. Hsu, W.-C. Chen, K. Sugiyama, A. Hirao
  • Journal Title: Appl. Mater. Interface Volume: 1 Pages: 1974-1979
  • Peer Reviewed
• [Journal Article] Synthesis of well-defined block copolymers an d star-branched polymers by using terminal 1, 3-butadiene functionalized polymers as reactive building blocks (2009)
  • Author(s): K. Sugiyama, K. Inoue, T. Higashiha ra, H. Hayashi, A. Hirao
  • Journal Title: Reactive and Functional Polymers Volume: 69 Pages: 480-492
  • Peer Reviewed
• [Journal Article] Living anionic polymerization of styrene derivati ves para-substituted withπ-conjug ated oligo(fluorene) moieties (2009)
  • Author(s): K. Sugiyama, A. Hirao, J.-C. Hsu, Y.-C. Tung, W.-C. Chen
  • Journal Title: Macro molecules Volume: 42 Pages: 4053-4062
  • Peer Reviewed
• [Journal Article] Precise Synthesis of Exact Graft Copolymers, Poly(methyl methacrylate)-2 exact graft-polystyrene, by Iteraive Methodoloy Using a Specially 3 Designed In-Chain-Functionalized AB Diblock Copolymer Anion (2009)
  • Author(s): Akira Hirao, Kota Murano, Ryosuke Kurokawa, Takumi Watanabe, Kenji Sugiyama
  • Journal Title: Macromolecules 42 Pages: 7820-7827
  • Peer Reviewed
• [Journal Article] Synthesis and Self-Assembly Behavior of Poly(fluorenystyrene)-block-Poly(2-vinylpyridine)Block Copolymers and Their Blends with SWCNT's (2009)
  • Author(s): Chaoxu Li, Jung-Ching Hsu, Kenji Sugiyama, Akira Hirao, Chen Wen-Chang, Mezzenga Raffaele
  • Journal Title: Macromolecules 42 Pages: 5793-5801
  • Peer Reviewed
• [Journal Article] Non-volatile Memory Devices Based on Plystyrene Derivatives with Electron-Donating Oligofluorene Pendent Moieties (2009)
  • Author(s): Cheng-Liang Liu, Jung-Ching Hsu, Wen-Chang Chen, Kenji Sugiyama, Akira Hirao
  • Journal Title: Appl. Mater. Interface 1 Pages: 1974-1979
  • Peer Reviewed
• [Journal Article] Synthesis of well-defined block copolymers and star-branched polymers by using terminal 1,3-butadiene functionalized polymers as reactive building blocks (2009)
  • Author(s): Kenji Sugiyama, Kyouichi Inoue, Tomoya Higashihara, Hiromi Hayashi, Akira Hirao
  • Journal Title: Reactive and Functional Polymers 69 Pages: 480-492
  • Peer Reviewed
• [Journal Article] Living Anionic Polymerization of Styrene Derivatives para-Substituted with π-Conjugated Oligo(fluorene)Moieties (2009)
  • Author(s): Kenji Sugiyama, Akira Hirao, Jung-Ching Hsu, Yi-Chih Tung, Wen-Chang Chen
  • Journal Title: Macromolecules 42 Pages: 4053-4062
  • Peer Reviewed
• [Presentation] ブロックコポリマーの超臨界二酸化炭素中における高膨潤状態での相転移挙動 (2011)
  • Author(s): 新海智照, 横山英明, 伊藤耕三, 酒井康博, 杉山賢次
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-28
• [Presentation] 超臨界二酸化炭素によるブロック共重合体のモルフォロジー転移と膨潤のin-situ測定 (2011)
  • Author(s): 伊藤真陽, 酒井康博, 伊藤耕三, 杉山賢次, 横山英明
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-28
• [Presentation] 末端にパーフルオロアルキル化アゾベンゼンを有するポリスチレンの合成 (2011)
  • Author(s): 蔵重麻純, 杉山賢次
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学
  • Year and Date: 2011-08-30
• [Presentation] 側鎖にパーフルオロアルキル化アゾベンゼンを含むメタクリル酸メチルの重合 (2011)
  • Author(s): 相澤麻美子, 杉山賢次
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学
  • Year and Date: 2011-08-30
• [Presentation] イオン結合性末端パーフルオロアルキル化ポリスチレンの合成 (2011)
  • Author(s): 山田岳史, 杉山賢次
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学
  • Year and Date: 2011-08-30
• [Presentation] パーフルオロアルキル基を含む水溶性ポリメタクリル酸2-(2-メトキシエトキシ)エチルの合成 (2011)
  • Author(s): 佐藤友紀, 杉山賢次
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学
  • Year and Date: 2011-08-30
• [Presentation] シンナモイル基を有する含フッ素ポリマーフィルム表面の安定化 (2011)
  • Author(s): 山田真也, 杉山賢次
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学
  • Year and Date: 2011-08-30
• [Presentation] シンナモイル基を有する含フッ素ポリマーフィルム表面の安定化 (2011)
  • Author(s): 山田真也, 杉山賢次
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: 大阪国際会議場
  • Year and Date: 2011-05-25
• [Presentation] イオン結合性末端パーフルオロアルキル化ポリスチレンの合成 (2011)
  • Author(s): 山田岳史, 杉山賢次
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: 大阪国際会議場
  • Year and Date: 2011-05-25
• [Presentation] リビングアニオン重合法を用いた新規のシークエンシャルトリブロック共重合体の精密合成 (2010)
  • Author(s): 尾家俊行, 杉山賢次, 松尾悠里, 平尾明
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] Precise Synthe sis of Architectural Polymers by Us ing Chain-Functionalized AB Diblock Copolymers (2010)
  • Author(s): A. Abouelmagd, K. Sugiyama, K. Mura no, T. Oie, A. Hirao
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] 超臨界二酸化炭素によるブロック共重合体の圧力誘起モルフォロジー転移 (2010)
  • Author(s): 伊藤真陽, 酒井康博, 横山英明, 伊藤耕三, 杉山賢次
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] フッ素を含むブロックコポリマーの超臨界二酸化炭素選択膨潤:二酸化炭素の選択性の影響 (2010)
  • Author(s): 新海智照, 酒井康博, 横山英明, 伊藤耕三, 杉山賢次
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] m-(ヒドロキシ(tert-ブチル)アミノ)スチレンの保護とアニオン重合 (2010)
  • Author(s): 田中俊資, 杉山賢次, 平尾明
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] Precise Synthesis of Architectural Polymers by Using Chain-Functionalized AB Diblock Copolymers (2010)
  • Author(s): A.Abou Elmagd, K.Sugiyama, K.Murano, T.Oie, A.Hirao
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] Synthesis of Well-defined Multiblock Copolymers by Means of Living Anionic Polymer ization Based on Iterative Methodol ogy (2010)
  • Author(s): K. Sugiyama
  • Organizer: 2010 Japan-Taiwan Bilateral Pol ymer Symposium
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-07-01
• [Presentation] Synthesis of Well-defined Multiblock Copolymers by Means of Living Anionic Polymerization Based on Iterative Methodology (2010)
  • Author(s): Kenji Sugiyama
  • Organizer: 2010 Japan-Taiwan Bilateral Polymer Symposium
  • Place of Presentation: Hokkaido University
  • Year and Date: 2010-07-01
• [Presentation] 構造が厳密に制御されたグラフト共重合体の合成と溶液挙動 (2010)
  • Author(s): 村野耕太, 上松正弘, 黒川良介, 杉山賢次, 平尾明
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-26
• [Presentation] ポリ(フェロセニルメチルメタクリレート)セグメントを含むスターポリマーの精密合成 (2010)
  • Author(s): 平野智之, 小座間洋子, 杉山賢次, 平尾明
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-26
• [Presentation] 超臨界二酸化炭素によるフッ素を含むブロック共重合体薄膜のモルフォロジー変化 (2010)
  • Author(s): 伊藤真陽, 酒井康博, 横山英明, 伊藤耕三, 杉山賢次
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-26
• [Presentation] Precise synthesis of ex act graft copolymers via new method ology based on living anionic polym erization (2010)
  • Author(s): A. Abouelmagd, K. Murano, K. Sugiyam a, A. Hirao
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-26
• [Presentation] 構造が厳密に制御されたグラブト共重合体の合成と溶液挙動 (2010)
  • Author(s): 村野耕太, 上松正弘, 黒川良介, 杉山賢次, 平尾明
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-26
• [Presentation] Precise synthesis of exact graft copolymers via new methodology based on living anionic polymerization (2010)
  • Author(s): A.Abou Elmagd, K.Murano, K.Sugiyama, A.Hirao
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-26
• [Presentation] 鎖中に官能基を有するポリマーアニオンを用いたグラフト共重合体の精密合成 (2009)
  • Author(s): 村野耕太, 黒川良介, 杉山賢次, 平尾明
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-16
• [Presentation] 鎖末端に官能基を有するブロック共重合体を用いた(AB) nマルチブロック共重合体の合成 (2009)
  • Author(s): 尾家俊行, A. Abouelmagd, 杉山賢次, 平尾明
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-16
• [Presentation] ブロックコポリマーテンプレートと超臨界二酸化炭素によるナノ多孔体薄膜の創成と構造解析 (2009)
  • Author(s): 横山英明, 伊藤真陽, 酒井康博, 伊藤耕三, 杉山賢次
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-16
• [Presentation] 鎖末端に官能基を有するブロック共重合体を用いた(AB)nマルチブロック共重合体の合成 (2009)
  • Author(s): 尾家俊行, Abou El-Magd Ahmed, 杉山賢次, 平尾明
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-16
• [Presentation] フェロセニルメチルメタクリレートのリビングアニオン重合 (2009)
  • Author(s): 平野智之, 杉山賢次, 平尾明
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-16
• [Presentation] α-フェニルアクリロイル基とアニオンリビングポリマーを用いた新規繰り返し法による星型ポリ(メチルメタクリレート)の合成 (2009)
  • Author(s): 井上享一, 江原清登, 杉山賢次, 平尾明
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] リビングアニオン重合を用いた新規水溶性非対称スターポリマーの精密合成 (2009)
  • Author(s): 中山貴文, 犬島玲子, 杉山賢次, 平尾明, A. Deffieux
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] AB二元ブロック共重合体を用いた多段(AB) nブロック共重合体の精密合成 (2009)
  • Author(s): 尾家俊行, A. Abouelmagd, 杉山賢次, 平尾明
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] リビングアニオン重合を基にした構造が制御されたグラフトポリマーの精密合成 (2009)
  • Author(s): 黒川良介, 杉山賢次, 平尾明
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] フッ素を含むブロック共重合体の超臨界二酸化炭素中におけるモルフォロジー変化 (2009)
  • Author(s): 伊藤真陽, 眞弓皓一, 酒井康博, 横山英明, 伊藤耕三, 大坂昇, 柴山充弘, 杉山賢次
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] AB二元ブロック共重合体を用いた多段(AB)nブロック共重合体の精密合成 (2009)
  • Author(s): 尾家俊行, Abou El-Magd Ahmed, 杉山賢次, 平尾明
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] フェロセニルメチルメタクリレートのリビングアニオン重合 (2009)
  • Author(s): 平野智之, 杉山賢次, 平尾明
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-27
• [Presentation] 分子量及び分岐点間距離が厳密に制御されたグラフト共重合体の合成 (2009)
  • Author(s): 村野耕太, 黒川良介, 杉山賢次, 平尾明
  • Organizer: 第58回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場
  • Year and Date: 2009-05-02
• [Book] Complex Macromolecular Arch itectures : Synthesis Characterizat ion, and Self-Assembly (2011)
  • Author(s): H. Yokoyama, K. Sugiyama
• [Book] Complex Macromolecular Architectures : Synthesis, Characterization, and Self-Assembly (2011)
  • Author(s): Hideaki Yokoyama
  • Total Pages: 21
  • Publisher: John Wiley & Sons
• [Book] 高分子の合成(上)-ラジカル重合・カチオン重合・アニオン重合- (2010)
  • Author(s): 澤本光男, 上垣外正己, 佐藤浩太郎, 青島貞人, 金岡鐘局, 平尾明, 杉山賢次
  • Publisher: 講談社
• [Book] 分子から材料までどんどんつながる高分子 (2009)
  • Author(s): 渡辺順次, 足立馨, 打田聖, 久保山敬一, 黒木重樹, 杉山賢次, 戸木田雅利, 中嶋健, 早川晃鏡
  • Publisher: 丸善
• [Book] 分子から材料までどんどんつながる高分子 (2009)
  • Author(s): 渡辺順次, 足立馨, 打田聖, 久保山敬一, 黒木重樹, 杉山賢次, 戸木田雅利, 中嶋健, 早川晃鏡
  • Total Pages: 214
  • Publisher: 丸善株式会社