Preparation and Characterization of New Dimensional Polymers by Fixation of Molecular Arrangement in Ionic Molecular Crystals
| Project/Area Number |
21550117
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
SUZUKI Masahito 名古屋工業大学, 大学院・工学研究科, 教授 (20179253)
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| Co-Investigator(Renkei-kenkyūsha) |
MATSUOKA Shin-ichi 名古屋工業大学, 工学部, 助教 (10432288)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 高分子合成 / 分子結晶 / イオン性結晶 / 固相重合 / 重縮合 / LB膜 / 特殊構造高分子 / 高度架橋高分子 / ポリエステル / 重付加 |
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| Research Abstract |
Ionic molecular crystals were prepared by the combinations of tri- or tetra-topic anionic molecules with cationic ones, both of which had planar or tetrahedral structures. Then, in the solid state, the ionic interactions of benzylpyridinium carboxylate were thermally transformed to covalent bonds of benzylester. The product polymers were expected to have the regular network structures. A variety of monomers were prepared and examined. Most of them gave amorphous polymers, but some cross-linked crystalline polymers were obtained, for example, from the combination of tetra-topic phorphyrine derivatives.
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Report
(4 results)
Research Products
(24 results)
