Development of photoreversible supramolecular polymer composed of hydrogen bonding

• Project/Area Number: 21550119
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Saga University
• Principal Investigator: TAKESHITA Michinori 佐賀大学, 工学系・研究科, 准教授 (40274534)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2009: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: 超分子 / フォトクロミズム / 水素結合 / エラストマー / 光アクチュエーター / 有機合成 / ソフトマテリアル

Research Abstract

Photochromic diarylethenes having ureidopyrimidinone moieties have been developed. The formation and dissociation of the hydrogen bonded supramolecular polymers composed of the diarylethenes have been accomplished by photoirradiation in the solution. Furthermore, the elastomeric film containing the diarylethene moved by photoirradiation and we also found that the film can be used as a photoactuator.

Research Products

• [Journal Article] Syntheses and Fully Diastereospecific Photochromic Reactions of Thiophenophan-1-enes Having Chiral Bridges (2012)
  • Author(s): M. Takeshita, H. Jin-nouchi
  • Journal Title: Chem. Eur. J. Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] Bidirectional Redox Molecular Switches : Electron-induced Cyclization and Cycloreversion Processes in Metacyclophanes (2012)
  • Author(s): I. Gallardo, G. Prats, G. Guirado, M. Takeshita
  • Journal Title: Chem. Eur. J. Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] Synthesis and Photochromic Properties of[ 2. 2] Thiopheno-phan-8-ene-1, 2-diol (2011)
  • Author(s): M. Takeshita, S. Yamaguchi
  • Journal Title: Chem. Lett. Volume: 40 Pages: 646-646
  • Peer Reviewed
• [Journal Article] Synthesis and Photochromic Properties of [2.2] Thiophenophan-8-ene-1, 2-diol (2011)
  • Author(s): M.Takeshita, S.Yamaguchi
  • Journal Title: Chem.Lett. Volume: 40 Issue: 6 Pages: 646-646
  • DOI: 10.1246/cl.2011.646
  • NAID: 10028244335
  • Peer Reviewed
• [Journal Article] A Fully Photoreversible Supramolecular Polymer Having a Diarylethene Photoswitch (2010)
  • Author(s): M. Takeshita, M. Hayashi, T. Miyazaki
  • Journal Title: Chem. Lett. Volume: 39 Pages: 82-82
  • NAID: 10027176825
  • Peer Reviewed
• [Journal Article] Fully diastereo-specific photochromic reaction of a thiophene-phan-1-ene (2010)
  • Author(s): M. Takeshita, H. Jin-nouchi
  • Journal Title: Chem. Commun. Volume: 46 Pages: 3994-3994
  • Peer Reviewed
• [Journal Article] Bridged Photochromic Diarylethenes Investigated by Ultrafast Absorption Spectroscopy : Evidence for Two Distinct Photocyclization Pathways (2010)
  • Author(s): S. Aloise, M. Sliwa, Z. Pawlowska, J. Dubois, O. Poizat, G. Buntinx, A. Perrier, F. Maurel, S. Yamaguchi, M. Takeshita
  • Journal Title: J. Am. Chem. Soc. Volume: 132 Pages: 7379-7379
  • Peer Reviewed
• [Journal Article] A Fully Photoreversible Supramolecular Polymer Having a Diarylethene Photoswitch (2010)
  • Author(s): M.Takeshita, M.Hayashi, T.Miyazaki
  • Journal Title: Chem.Lett. Volume: 39 Pages: 82-83
  • NAID: 10027176825
  • Peer Reviewed
• [Journal Article] Fully diastereospecific photochromic reaction of a thiophenophan-1-ene (2010)
  • Author(s): M.Takeshita, H.Jin-nouchi
  • Journal Title: Chem.Commun. Volume: 46 Pages: 3994-3995
  • Peer Reviewed
• [Journal Article] Bridged Photochromic Diarylethenes Investigated by Ultrafast Absorption Spectroscopy : Evidence for Two Distinct Photocyclization Pathways (2010)
  • Author(s): S.Aloise, M.Sliwa, Z.Pawlowska, J.Dubois, O.Poizat, G.Buntinx, A.Perrier, F.Maurel, S.Yamaguchi, M.Takeshita
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 7379-7390
  • Peer Reviewed
• [Journal Article] A Fully Photoreversible Supramolecular Polymer Having a Diarylethene Photoswitch (2010)
  • Author(s): M.Takeshita, M.Hayashi, T.Miyazaki
  • Journal Title: Chem.Lett. 39 Pages: 82-83
  • NAID: 10027176825
  • Peer Reviewed
• [Journal Article] Fully diastereospecific photochromic reaction of a thiophenophan-1-ene (2010)
  • Author(s): M.Takeshita, H.Jin-nouchi
  • Journal Title: Chem.Commun. (印刷中)
  • Peer Reviewed
• [Journal Article] Electronically triggered conversion between metacyclophan-1-ene and dihydropyrene molecular systems (2009)
  • Author(s): I. Gallardo, G. Guirado, G. Prats, M. Takeshita
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 11 Pages: 1502-1502
  • Peer Reviewed
• [Journal Article] Synthesis and Photochromic Properties of Thiophenophan-1-nes Having Polyether Bridge (2009)
  • Author(s): M. Takeshita, C. Tanaka, T. Miyazaki, Y. Fukushima, M. Nagai
  • Journal Title: New J. Chem. Volume: 33 Pages: 1433-1433
  • Peer Reviewed
• [Journal Article] Syntheses and Photochromic Properties of Metacyclothiophenophan-1-enes (2009)
  • Author(s): M. Takeshita, H. Jin-nouchi, J. Ishikawa
  • Journal Title: Chem. Lett. Volume: 38 Pages: 982-982
  • NAID: 10025547213
  • Peer Reviewed
• [Journal Article] Electronically triggered conversion between metacyclophan-1-ene and dihydropyrene molecular systems (2009)
  • Author(s): I.Gallardo, G.Guirado, G.Prats, M.Takeshita
  • Journal Title: Phys.Chem.Chem.Phys. 11 Pages: 1502-1507
  • Peer Reviewed
• [Journal Article] Synthesis and Photochromic Properties of Thiophenophan-1-enes Having Polyether Bridge (2009)
  • Author(s): M.Takeshita, C.Tanaka, T.Miyazaki, Y.Fukushima, M.Nagai
  • Journal Title: New J.Chem. 33 Pages: 1433-1438
  • Peer Reviewed
• [Journal Article] Syntheses and Photochromic Properties of Metacyclothiophenophan-1-enes (2009)
  • Author(s): M.Takeshita, H.Jin-nouchi, J.Ishikawa
  • Journal Title: Chem.Lett. 38 Pages: 982-983
  • NAID: 10025547213
  • Peer Reviewed
• [Journal Article] Syntheses and Fully Diastereospecific Photochromic Reactions of Thiophenophan-1-enes Having Chiral Bridges
  • Author(s): M.Takeshita, H.Jin-nouchi
  • Journal Title: Chem.Eur.J Volume: (印刷中)
  • Peer Reviewed
• [Presentation] Photo-responsive supramolecular polymer having a diarylethene photoswitch (2011)
  • Author(s): Michinori Takeshita
  • Organizer: International Symposium on Stimuli-Responsive Materials
  • Place of Presentation: Hattiesburg, USA
  • Year and Date: 2011-10-25
• [Presentation] Photo-responsive supramolecular polymer having a diarylethene photoswitch (2011)
  • Author(s): Michinori Takeshita
  • Organizer: International Symposium on Stimuli-Responsive Materials
  • Place of Presentation: Hattiesburg, USA(基調講演)
  • Year and Date: 2011-10-25
• [Presentation] [2.2]シクロファン-エン-1,2-ジオール類の合成とフォトクロミック反応 (2011)
  • Author(s): 廣渡拓也、山口翔平、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-08
• [Presentation] フォトクロミックチオフェノファン-1-エンのポリマー化 (2011)
  • Author(s): 松岡俊宏、柿添仁志、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-08
• [Presentation] チオフェン環の4位にフェニル基をもつチオフェノファン-1-エンの合成とフォトクロミズム (2011)
  • Author(s): 八丁菜津美、高垣祐司、木下武治、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-08
• [Presentation] アゾチオフェンの合成 (2011)
  • Author(s): 山田豪、北村崇、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-08
• [Presentation] チオフェノファン-1-エン類の完全ジアステレオ特異的フォトクロミック反応 (2011)
  • Author(s): 竹下道範、陣内裕継
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-07
• [Presentation] ポリエーテル鎖を持ったチオフェノファン-1-エン類のフォトクロミック挙動 (2011)
  • Author(s): 和田雄太、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-07
• [Presentation] チオフェノファン-1-エン類の環状n量体の開発とフォトクロミズム (2011)
  • Author(s): 北村崇、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-06
• [Presentation] 光スイッチをもった3点水素結合性超分子ポリマーの開発 (2011)
  • Author(s): 柿添仁志、倉成利幸、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-06
• [Presentation] ナフタレン環を有するジアリールエテン類の合成とフォトクロミズム (2011)
  • Author(s): 松田祐二、村上和斗、和田雄太、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-06
• [Presentation] フォトクロミック水素結合性超分子エラストマーフィルムの開発 (2011)
  • Author(s): 木下武治、宮崎貴志、竹下道範
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2011-09-06
• [Presentation] Photodriven Supramolecular Polymer Composed of a Diarylethene Photoswitch and Multiple Hydrogen Bonding Sites (2011)
  • Author(s): Michinori Takeshita
  • Organizer: International Conference on Materials for Advanced Technologies
  • Place of Presentation: Singapore
  • Year and Date: 2011-06-11
• [Presentation] チオフェノファン-1-エン類のジアステレオ特異的フォトクロミック反応 (2011)
  • Author(s): 竹下道範、陣内裕継
  • Organizer: 日本化学会春季年会
  • Place of Presentation: 東京
• [Presentation] DIASTEREOSPECIFIC PHOTOCHROMIC REACTIONS OF THIOPHENOPHAN-1-ENES (2010)
  • Author(s): Michinori Takeshita, Hirotsugu Jin-nouchi
  • Organizer: IUPAC Photochemistry
  • Place of Presentation: Ferrara, Italy
  • Year and Date: 2010-11-05
• [Presentation] フォトクロミックチオフェノファン-1-エン類の開発 (2010)
  • Author(s): 竹下道範
  • Organizer: 「フォトクロミズム」特定領域研究公開シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2010-01-23
• [Presentation] Stereospecific Photochromic Reactions of Cyclophan-1-enes (2010)
  • Author(s): Michinori Takeshita
  • Organizer: Third Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 横浜
• [Presentation] Diastereospecific Photochromic Reactions of Thiophenophan-1-enes (2010)
  • Author(s): Michinori Takeshita
  • Organizer: IUPAC Photochemistry
  • Place of Presentation: フェラーラ(イタリア)
• [Presentation] Photochromic Property of a Supramolecular Elastomeric Film Composed of a Diarylethene Having Hydrogen Bonding Moieties (2010)
  • Author(s): Takeharu Kinoshita, Michinori Takeshita
  • Organizer: Third Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 横浜
• [Presentation] Photochromism of Polymers Modified with Metacyclophan-1-enes (2010)
  • Author(s): Shouhei Yamaguchi, Michinori Takeshita
  • Organizer: Third Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 横浜
• [Presentation] Development of Thiophenophan-1-enes which Perform Diastereospecific Photochromic Reaction (2010)
  • Author(s): Hirotsugu Jin-nouchi, Michinori Takeshita
  • Organizer: Third Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 横浜
• [Presentation] Preparation and Photochromic Properties of Thiophenophan-1-enes Having Polyether Bridge (2010)
  • Author(s): Yuta Wada, Michinori Takeshita
  • Organizer: Third Japanese-French Joint Seminar on Organic Photochromism
  • Place of Presentation: 横浜
• [Presentation] フォトクロミック水素結合性超分子エラストマーフィルムのフォトクロミック特性 (2010)
  • Author(s): 木下武治、宮崎貴志、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] ジアステレオ特異的フォトクロミック反応を行うチオフェノファン-1-エン類の開発 (2010)
  • Author(s): 陣内裕継、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] フォトクロミックナフタレノファン-1-エン類およびフォトクロミックナフタレノチオフェノファン-1-エン類の合成とフォトクロミズム (2010)
  • Author(s): 村上和斗、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] メタシクロファン-1-エン類を修飾したポリマーのフォトクロミズム (2010)
  • Author(s): 山口翔平、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] ポリエーテル鎖を持つチオフェノファン-1-エン類の合成とフォトクロミック特性 (2010)
  • Author(s): 和田雄太、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] 光スイッチをもった三点水素結合性超分子ポリマーの開発 (2010)
  • Author(s): 柿添仁志、木下武治、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] 大環状チオフェノファンのn量体の開発とフォトクロミック挙動 (2010)
  • Author(s): 北村崇、和田雄太、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] チオフェノファン-S,S'-テトラオキシド体の合成とフォトクロミズム (2010)
  • Author(s): 児玉知洋、陣内裕継、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] π電子共役を拡張したチオフェノファン-1-エン誘導体の合成とフォトクロミズム (2010)
  • Author(s): 高垣祐司、山口翔平、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 熊本
• [Presentation] ポリマーに結合したフォトクロミックシクロファン-1-エン類のフォトクロミズム (2010)
  • Author(s): 山口翔平、中村武史、古賀健、竹下道範
  • Organizer: 日本化学会年会
  • Place of Presentation: 大阪
• [Presentation] 3点水素結合部位を持ったジアリールエテンの合成と超分子形成 (2010)
  • Author(s): 倉成利幸・宮崎貴志・竹下道範
  • Organizer: 日本化学会年会
  • Place of Presentation: 大阪
• [Presentation] フォトクロミック水素結合性超分子エラストマーフィルムの開発 (2010)
  • Author(s): 木下武治・宮崎貴志・竹下道範
  • Organizer: 日本化学会年会
  • Place of Presentation: 大阪
• [Presentation] メタシクロチオフェノファン-1-エン類の合成とフォトクロミズム (2010)
  • Author(s): 陣内裕継・石川潤・竹下道範
  • Organizer: 日本化学会年会
  • Place of Presentation: 大阪
• [Presentation] ジアステレオ特異的フォトクロミック反応を行うチオフェノファン-1-エン類の開発 (2010)
  • Author(s): 陣内裕継・竹下道範
  • Organizer: 日本化学会年会
  • Place of Presentation: 大阪
• [Presentation] ポリエーテル鎖を持つチオフェノファン-1-エン類の合成とフォトクロミック特性 (2010)
  • Author(s): 和田雄太・岩出洋・竹下道範
  • Organizer: 日本化学会年会
  • Place of Presentation: 大阪
• [Presentation] Syntheses and photo-chromic properties of thiophenophan-1-enes bearing polyether bridges (2009)
  • Author(s): Michinori Takeshita
  • Organizer: The IV joint International Symposium on Macrocyclic & Supramolecular Chemistry
  • Place of Presentation: マーストリヒト(オランダ)
• [Presentation] Syntheses and photochromic properties of thiophenophan-1-enes bearing polyether bridges (2009)
  • Author(s): Michinori Takeshita
  • Organizer: The IV joint International Symposium on Macrocychc & Supramolecular Chemistry
  • Place of Presentation: マーストリヒト(オランダ)
• [Presentation] フォトクロミックナフタレノファン-1-エン類およびフォトクロミックナフタレノチオフェノファン-1-エン類の合成 (2009)
  • Author(s): 村上和斗、中村武史、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
• [Presentation] メタシクロチオフェノファン-1-エン類の合成とフォトクロミズム (2009)
  • Author(s): 陣内裕継、石川潤、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
• [Presentation] ポリマーに結合したフォトクロミックシクロファン-1-エン類のフォトクロミズム (2009)
  • Author(s): 山口翔平、中村武史、古賀健、竹下道範
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
• [Book] チオフェノファン-1-エン類のフォトクロミズム、フォトクロミズムの新展開と光メカニカル機能材料 (2011)
  • Author(s): 竹下道範
  • Publisher: シーエムシー出版
• [Book] フォトクロミズムの新展開と光メカニカル機能材料 (2011)
  • Author(s): 竹下道範, 他(共著)
  • Publisher: シーエムシー出版
• [Remarks]
  • URL: http://extwww.cc.saga-u.ac.jp/~michi/