Functionalization of Silanol-based Anion Receptors
| Project/Area Number |
21550127
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
UNNO Masafumi 群馬大学, 大学院・工学研究科, 教授 (20251126)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | シラノール / 分子認識 / アニオン / 蛍光 / アニオン認識 / 水素結合 / 超分子化学 / 蛍光スペクトル |
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| Research Abstract |
In this study, we have synthesized functionalized silanol-based anion receptors by introduction of functional groups. Di(1-pyrenyl)silanediol was designed and synthesized for fluorescence detection of anions. Indeed, fluorescence changes at 370-420 nm as monomer emissions of pyrenyl groups was observed through isoemissive points upon the addition of anions. These results indicate that quantitative evaluation of anions can be achieved as the ratiometric fluorescence detection by the receptor.
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Report
(4 results)
Research Products
(43 results)
