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Functionalization of Silanol-based Anion Receptors

Research Project

Project/Area Number 21550127
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionYamagata University

Principal Investigator

KONDO Shin-ichi  山形大学, 理学部, 准教授 (20281503)

Co-Investigator(Kenkyū-buntansha) UNNO Masafumi  群馬大学, 大学院・工学研究科, 教授 (20251126)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsシラノール / 分子認識 / アニオン / 蛍光 / アニオン認識 / 水素結合 / 超分子化学 / 蛍光スペクトル
Research Abstract

In this study, we have synthesized functionalized silanol-based anion receptors by introduction of functional groups. Di(1-pyrenyl)silanediol was designed and synthesized for fluorescence detection of anions. Indeed, fluorescence changes at 370-420 nm as monomer emissions of pyrenyl groups was observed through isoemissive points upon the addition of anions. These results indicate that quantitative evaluation of anions can be achieved as the ratiometric fluorescence detection by the receptor.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (43 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (28 results) Remarks (4 results)

  • [Journal Article] Synthesis and photophysical properties of 2,2’-binaphthalene-based receptor bearing trimethylsilyl groups to improve the solubility2013

    • Author(s)
      S. Kondo, N. Watanabe, F. Takahashi, N. Takeda, M. Unno
    • Journal Title

      J. Incl. Phenom. Macrocycl. Chem.

      Volume: 75 Issue: 1-2 Pages: 66-70

    • DOI

      10.1007/s10847-012-0142-8

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ratiometric fluorescence detection of anions by an amide-based receptor bearing pyrenyl groups2012

    • Author(s)
      S. Kondo, S. Nakajima, M. Unno
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: (印刷中) Issue: 6 Pages: 698-700

    • DOI

      10.1246/bcsj.20120054

    • NAID

      130004059043

    • Year and Date
      2012-05-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of solubility of 2,2'-binaphthalene derivatives bearing urea groups as anion receptors and their application to a chloride selective electrode2011

    • Author(s)
      S. Kondo, H. Sonoda, T. Katsu, M. Unno
    • Journal Title

      Sens. Actuators B

      Volume: Vol.160, No.1 Issue: 1 Pages: 684-690

    • DOI

      10.1016/j.snb.2011.08.048

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anion recognition by 2,2'-binaphthalene derivatives bearing urea and thiourea groups at 8-and 8'-positions by UV-vis and fluorescence spectroscopies2011

    • Author(s)
      S. Kondo, M. Nagamine, S. Karasawa, M. Ishihara, M. Unno, Y. Yano
    • Journal Title

      Tetrahedron

      Volume: Vol.67, No.5 Issue: 5 Pages: 943-950

    • DOI

      10.1016/j.tet.2010.12.004

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photophysical properties of a 2,2'-bianthracene-based receptor bearing two aza-15-crown-5 ethers for naked-eye detection of barium ion2011

    • Author(s)
      S. Kondo, T. Takahashi, Y. Takiguchi, M. Unno
    • Journal Title

      Tetrahedron Lett

      Volume: Vol.52, No.3 Issue: 3 Pages: 453-457

    • DOI

      10.1016/j.tetlet.2010.11.091

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anion recognition by 2,2'-binaphthalene bearing imidazolium groups in MeCN2011

    • Author(s)
      S. Kondo
    • Journal Title

      Supramol. Chem

      Volume: Vol.23, No.1 & 2 Issue: 1-2 Pages: 29-36

    • DOI

      10.1080/10610278.2010.506554

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anion recognition by 2,2'-binaphthalene bearing imidazolium groups in MeCN2011

    • Author(s)
      Shin-ichi Kondo
    • Journal Title

      Supramolecular Chemistry

      Volume: 23 Pages: 29-31

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photophysical properties of a 2,2'-bianthracene-based receptor bearing two aza-15-crown-5 ethers for naked-eye detection of barium ion2011

    • Author(s)
      Shin-ichi Kondo, Takuya Takahashi, Yuji Takiguchi, Masafumi Unno
    • Journal Title

      Tetrahedron Letters

      Volume: 52 Pages: 453-457

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anion recognition by 2,2'-binaphthalene derivatives bearing urea and thiourea groups at 8- and 8'-positions by UV-vis and fluorescence spectroscopies2011

    • Author(s)
      Shin-ichi Kondo, Masanori Nagamine, Satoshi Karasawa, Masaya Ishihara, Masafumi Unno, Yumihiko Yano
    • Journal Title

      Tetrahedron

      Volume: 67 Pages: 943-950

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anion recognition by D-ribose-based receptors2010

    • Author(s)
      S. Kondo, Y. Kobayashi, M. Unno
    • Journal Title

      Tetrahedron Lett

      Volume: Vol.51, No.18 Issue: 18 Pages: 2512-2514

    • DOI

      10.1016/j.tetlet.2010.03.001

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anion recognition by D-ribose-based receptors2010

    • Author(s)
      S.Kondo, Y.Kobayashi, M.Unno
    • Journal Title

      Tetrahedron Letters 51

      Pages: 2512-2514

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 環状ビス尿素誘導体によるアニオン認識2012

    • Author(s)
      近藤慎一, 石澤悠樹, 佐竹徳
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス・矢上キャンパス
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] シラノールをアニオン認識部位としたレセプターの機能化2012

    • Author(s)
      別易, 近藤慎一
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス・矢上キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ビアリールを主骨格に有する蛍光性レセプターの開発2011

    • Author(s)
      近藤慎一
    • Organizer
      平成22年度化学系学協会東北大会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2011-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] ビアリールを主骨格に有する蛍光性レセプターの開発2011

    • Author(s)
      近藤慎一
    • Organizer
      平成22年度化学系学協会東北大会
    • Place of Presentation
      東北大学川内北キャンパス(招待講演)
    • Year and Date
      2011-09-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] リン酸二水素アニオンに高い選択性を有する蛍光アニオンレセプターの構築2011

    • Author(s)
      近藤慎一, 高井龍之介
    • Organizer
      平成22年度化学系学協会東北大会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ジ(1-ピレニル)シランジオールの合成とそのアニオンに対する会合能2011

    • Author(s)
      別易, 近藤慎一
    • Organizer
      平成22年度化学系学協会東北大会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 水素結合を利用したアニオンレセプターの構築2011

    • Author(s)
      近藤慎一
    • Organizer
      第46回有機反応若手の会
    • Place of Presentation
      水上温泉 去来荘(招待講演)
    • Year and Date
      2011-07-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] イソフタルアミドを基本骨格に有するアニオンレセプターの機能化2011

    • Author(s)
      近藤慎一, 高井龍之介
    • Organizer
      第7回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス
    • Year and Date
      2011-05-29
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Improvement of the solubility of 2,2'-binaphthalene-based receptors2010

    • Author(s)
      渡邊尚哉, 近藤慎一, 海野雅史
    • Organizer
      Pacifichem2010
    • Place of Presentation
      ホノルル・ハワイ・USA
    • Year and Date
      2010-12-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Anion recognition by silanol-based receptors2010

    • Author(s)
      近藤慎一
    • Organizer
      Pacifichem2010
    • Place of Presentation
      ホノルル・ハワイ・USA
    • Year and Date
      2010-12-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Anion recognition by silanol-based receptors2010

    • Author(s)
      近藤慎一
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      ホノルル・ハワイ・USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Improvement of the solubility of 2,2'-binaphthalene-based receptors2010

    • Author(s)
      渡邊尚哉・近藤慎一・海野雅史
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      ホノルル・ハワイ・USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] C-Hを認識部位として有する2,2'-ビナフタレン誘導体によるアニオン認識2010

    • Author(s)
      近藤慎一
    • Organizer
      平成22年度化学系学協会東北大会
    • Place of Presentation
      岩手大学工学部
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Anion Recognition by Artificial Receptors Bearing Hydroxy Groups2010

    • Author(s)
      近藤慎一
    • Organizer
      Post 5th International Symposium on Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-06-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Anion Recognition by Artificial Receptors Bearing Hydroxy Groups2010

    • Author(s)
      近藤慎一
    • Organizer
      Post 5th International Symposium on Macrocyclic and Supramolecular Chemistry 2010
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-06-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Anion Recognition by Artificial Receptors Bearing Hydroxy Groups2010

    • Author(s)
      近藤慎一
    • Organizer
      5th International Symposium on Macrocyclic and Supramolecular Chemistry、2010
    • Place of Presentation
      奈良新公会堂
    • Year and Date
      2010-06-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Anion Recognition by Artificial Receptors Bearing Hydroxy Groups2010

    • Author(s)
      近藤慎一
    • Organizer
      5th International Symposium on Macrocyclic and Supramolecular Chemistry 2010
    • Place of Presentation
      奈良新公会堂
    • Year and Date
      2010-06-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] 2,2'-ビアントラセン骨格を有する蛍光レセプターの合成及び評価2010

    • Author(s)
      高橋卓也, 近藤慎一, 海野雅史
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス・東大阪市
    • Year and Date
      2010-03-27
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 2,2'-ビナフタレンを主骨格に有するレセプターの溶解性の向上2010

    • Author(s)
      渡邉尚哉, 近藤慎一, 海野雅史
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス・東大阪市
    • Year and Date
      2010-03-27
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] リボースを用いたアニオンレセプターの構築2010

    • Author(s)
      小林優, 近藤慎一, 海野雅史
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス・東大阪市
    • Year and Date
      2010-03-27
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] シラノールを有するアニオンレセプターの構築2009

    • Author(s)
      近藤慎一, 海野雅史
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学工学部桐生キャンパス・桐生市
    • Year and Date
      2009-09-28
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 水素結合を利用したアニオンレセプターの構築2009

    • Author(s)
      近藤慎一
    • Organizer
      第46回有機反応若手の会
    • Place of Presentation
      水上温泉去来荘
    • Year and Date
      2009-07-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 2,2'-ビナフタレンを主骨格に有するレセプターへのトリメチリシリル基の導入2009

    • Author(s)
      渡邊尚哉, 近藤慎一, 海野雅史
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学陽東キャンパス・宇都宮市
    • Year and Date
      2009-05-31
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 2,2'-ビアントラセン骨格を有する蛍光レセプターの合成及び評価2009

    • Author(s)
      高橋卓也, 近藤慎一, 海野雅史
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学陽東キャンパス・宇都宮市
    • Year and Date
      2009-05-30
    • Related Report
      2011 Final Research Report
  • [Presentation] 糖を用いたアニオンレセプターの構築2009

    • Author(s)
      小林優, 近藤慎一, 海野雅史
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学陽東キャンパス・宇都宮市
    • Year and Date
      2009-05-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 水酸基を有するアニオンレセプターの機能化2009

    • Author(s)
      今村仁美, 近藤慎一, 海野雅史
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学陽東キャンパス・宇都宮市
    • Year and Date
      2009-05-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] ビアリールをクロモフォアとして有するレセプターの設計と合成2009

    • Author(s)
      近藤慎一, 中台康則, 高橋卓也, 渡邊尚哉, 海野雅史
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学陽東キャンパス・宇都宮市
    • Year and Date
      2009-05-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 2,2'ビアントラセン骨格を有する蛍光レセプターの合成及び評価2009

    • Author(s)
      高橋卓也・近藤慎一・海野雅史
    • Organizer
      第5回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      宇都宮大学陽東キャンパス・宇都宮市
    • Year and Date
      2009-05-30
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www-kschem0.kj.yamagata-u.ac.jp/~kondo/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www-kschemO.kj.yamagata-u.ac.jp/~kondo/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www-kschem0.kj.yamagata-u.ac.jp/~kondo/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www-kschem0.kj.yamagata-u.ac.jp/~kondo/

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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