Hydrothermal syntheses and measurements of physical properties of novel transition metal oxides with exotic valences
Project/Area Number |
21550139
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Functional materials chemistry
|
Research Institution | Chuo University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
HARA Shigeo 中央大学, 理工学部, 助教 (60520012)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
|
Keywords | 電気 / 磁気的機能 / 水熱合成法 / 強相関系 / 遷移金属酸化物 / 物資探索 / 結晶構造解析 / 異常原子価 / 磁性 / フラストレーション / 強相関係 / 物質探索 |
Research Abstract |
In transition metal oxides with exotic valences, we can expect interesting magnetic and electric properties. In this study, we searched new materials using a hydrothermal method with which we can control redox condition in a closed system. As a result, we discovered six novel compounds. X-ray structural analyses and measurements of magnetization revealed that most of them have characteristics of a frustrated magnet in which a trivial magnetic order is suppressed because of a singular arrangement of the transition metal atoms.
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Report
(4 results)
Research Products
(40 results)