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Emergence of multifunctional property correlations induced bythe order structure formation of polypeptide helix.

Research Project

Project/Area Number 21550141
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionTokyo Polytechnic University

Principal Investigator

HIEJIMA Toshihiro  東京工芸大学, 工学部, 准教授 (30288112)

Co-Investigator(Renkei-kenkyūsha) UCHIDA Takayuki  東京工芸大学, 工学部, 教授 (80203537)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsポリペプチド / 有機EL素子 / 超分子化学 / 高分子構造・物性 / らせん磁性 / 超分子科学 / ライオトロピック液晶 / 励起子 / らせんスピン / 交差相関物性 / 反強磁性相互作用
Research Abstract

Helical poly(L-glutamate) with carbazole(Cz) side chains(PCELG) was synthesized as a hole-transport material for a dye-doped polymer electroluminescence(EL) device. For green and blue light, EL devices using PCELG(PCELG device) was found to exhibit luminance efficiencies comparable to those using poly(N-vinyl carbazole)(PVK). The maximal efficiencies of PCELG devices strongly depend on the casting solvents used during the film-forming process, which amount to the 20 times at the maximum. We pointed out that the solvent dependence of PCELG device attributed to the aggregation structure of PCELG chain at around the interface of the emitter layer/ITO electrode from the ellipsometric analysis.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (39 results)

All 2011 2010 2009

All Journal Article (14 results) (of which Peer Reviewed: 12 results) Presentation (25 results)

  • [Journal Article] TEMPOラジカル置換型ポリグルタメートの立体配座解析とESR解析2011

    • Author(s)
      金子純平・比江島俊浩
    • Journal Title

      ポリイミド・芳香族高分子最近の進歩2011

      Volume: 1 Pages: 122-125

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] カルバゾイル置換型ポリグルタメートを用いた有機EL発光とその起源2011

    • Author(s)
      高見澤陽介・内田孝幸・川畑州一・比江島俊浩
    • Journal Title

      ポリイミド・芳香族高分子最近の進歩2011

      Volume: 1 Pages: 118-121

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] Ellipsometric Determination of the optical properties of carbazole-containing poly(L-glutamate) thin film prepared from the different solvents2010

    • Author(s)
      T. Hiejima, Y. Takamizawa, T. Uchida and S. Kawabata
    • Journal Title

      Thin Solid Films

      Volume: 519(9) Issue: 9 Pages: 2972-2977

    • DOI

      10.1016/j.tsf.2010.12.048

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nonuniform site-charge distribution and fluctuations of charge order in the metallic state of α-(BEDT-TTF)_2I_32010

    • Author(s)
      Y. Yue, K. Yamamoto, M. Uruichi, C. Nakano, K. Yakushi, S. Yamada, T. Hiejima, A. Kamamoto
    • Journal Title

      Phys. Rev. B

      Volume: 82 Issue: 7

    • DOI

      10.1103/physrevb.82.075134

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared and Raman Studies of α-(BEDT-TTF)_2MHg(SCN)_4 with M=K and NH_4 at Low Temperature-the breaking of the inversion symmetry due to the charge-ordering fluctuation2010

    • Author(s)
      T. Hiejima, S. Yamada, M. Uruichi K. Yakushi
    • Journal Title

      Physica B

      Volume: 405 Issue: 11 Pages: S153-S156

    • DOI

      10.1016/j.physb.2010.01.114

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multicolor Single-Layer Electroluminescence Device Using Poly(l-Glutamate) for Hole Transport2010

    • Author(s)
      T. Hiejima, Y. Takamizawa, Y. Tanaka, K. Ueda, T. Uchida
    • Journal Title

      J. Polym. Sci. Part B ; Polym. Phys

      Volume: 48 Issue: 4 Pages: 496-502

    • DOI

      10.1002/polb.21912

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Order-disorder type of charge-ordering phase transition in narrow-bandwidth compound, α'-(BEDT-TTF)_2IBr_22010

    • Author(s)
      Y. Yue, C. Nakano, K. Yamamoto, M. Uruichi, K. Yakushi, T. Hiejima, A. Kawamoto
    • Journal Title

      Physica B

      Volume: 405 Issue: 11 Pages: S232-S236

    • DOI

      10.1016/j.physb.2010.01.082

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 主鎖型液晶の液晶形成能に及ぼすネマチックコンホメーションの効果2010

    • Author(s)
      比江島俊浩
    • Journal Title

      高分子論文集

      Volume: 67 Pages: 254-262

    • NAID

      10026213572

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared and Raman Studies of α-(BEDT-TTF)_2MHg(SCN)_4 with M=K and NH_4 at Low Temperature-the breaking of the inversion symmetry due to the charge-ordering fluctuation2010

    • Author(s)
      Toshihiro Hiejima, Shigeaki Yamada, Mikio Uruichi, Kyuya Yakushi
    • Journal Title

      Physica B

      Volume: 405

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonuniform site-charge distribution and fluctuations of charge order in the metallic state of α-(BEDT-TTF)_2I_32010

    • Author(s)
      Yue Yue, Kaoru Yamamoto, Mikio Uruichi, Chikako Nakano, Kyuya Yakushi, Shigeaki Yamada, Toshihiro Hiejima, Atsushi Kamamoto
    • Journal Title

      Phys.Rev.B

      Volume: 82

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Order-disorder type of charge-ordering phase transition in narrow-band width compound, α'-(BEDT-TTF)_2IBr_22010

    • Author(s)
      Yue Yue, Chikako Nakano, Kaoru Yamamoto, Mikio Uruichi, Kyuya Yakushi, Toshihiro Hiejima, A.Kawamoto
    • Journal Title

      Physica B

      Volume: 405

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multicolor Single-Layer Electroluminescence Device Using Poly(L-Glutamate)for Hole Transport.2010

    • Author(s)
      Hiejima, Toshihiro ; Takamizawa Yosuke ; Tananka Yoshinori, Ueda, Kenji ; Uchida, Takayuki
    • Journal Title

      J.Polym.Sci.Part B ; Polym.Phys. 48

      Pages: 496-502

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of casting solvents on characteristics of organic EL devices containing poly(L-glutamate) as hole-transport material2009

    • Author(s)
      T. Hiejima, Y. Takamizawa, Y. Tananka, K. Ueda, T. Uchida
    • Journal Title

      Synth. Met

      Volume: 156 Issue: 9-10 Pages: 986-989

    • DOI

      10.1016/j.synthmet.2009.02.042

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of casting solvents on characteristics of organic EL devices containing poly(L-glutamate)as hole-transport material2009

    • Author(s)
      Hiejima, Toshihiro ; Takamizawa Yosuke ; Tananka Yoshinori, Ueda, Kenji ; Uchida, Takayuki
    • Journal Title

      Synthetic Metals 159

      Pages: 986-989

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] ESR studies and Electron transfer properties of TEMPO radical pendant poly(L-glutamine) exhibited lyotropic liquid crystalline phase, Joint of Morino Lecture and International Workshop2011

    • Author(s)
      J. Kaneko, T. Hiejima
    • Organizer
      Spectroscopy on Photoinduced Functions of Electrons and Spins in Biology and Material Science
    • Place of Presentation
      Tokyo Tech Front, Tokyo Institute of Technology, Ookayama
    • Year and Date
      2011-10-13
    • Related Report
      2011 Final Research Report
  • [Presentation] 液晶相を発現するTEMPOラジカル置換型ポリ(L-グルタミン)の輸送特性2011

    • Author(s)
      金子純平、比江島俊浩
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Related Report
      2011 Final Research Report
  • [Presentation] カルバゾイル基置換型ポリグルタメートの示す光学特性の膜厚依存性とEL効率への影響2011

    • Author(s)
      比江島俊浩、高見澤陽介、内田孝幸、川畑州一
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] TEMPOラジカル置換型ポリ(L-グルタミン酸)誘導体の立体配座解析と磁気特性2011

    • Author(s)
      金子純平、比江島俊浩
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 液晶相を発現するTEMPOラジカル置換型ポリ(L-グルタミン)の輸送特性2011

    • Author(s)
      金子純平・比江島俊浩
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学津島キャンパス
    • Related Report
      2011 Annual Research Report
  • [Presentation] TEMPOラジカル基置換型ポリグルタメートの立体配座解析とESR解析2010

    • Author(s)
      金子純平、比江島俊浩
    • Organizer
      第18回日本ポリイミド・芳香族系高分子会議
    • Place of Presentation
      東京工芸大学
    • Year and Date
      2010-11-26
    • Related Report
      2011 Final Research Report
  • [Presentation] カルバゾイル基置換型ポリグルタメートを用いた有機EL発光とその起源2010

    • Author(s)
      高見澤陽介、内田孝幸、川畑州一、比江島俊浩
    • Organizer
      第18回日本ポリイミド・芳香族系高分子会議
    • Place of Presentation
      東京工芸大学
    • Year and Date
      2010-11-26
    • Related Report
      2011 Final Research Report
  • [Presentation] カルバゾイル基置換型ポリグルタメートを用いた有機EL発光とその起源2010

    • Author(s)
      高見澤陽介・内田孝幸・川畑州一・比江島俊浩
    • Organizer
      第18回日本ポリイミド・芳香族系高分子会議
    • Place of Presentation
      東京工芸大学厚木キャンパス
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] TEMPOラジカル基置換型ポリグルタメートの立体配座解析とESR解析2010

    • Author(s)
      金子純平・比江島俊浩
    • Organizer
      第18回日本ポリイミド・芳香族系高分子会議
    • Place of Presentation
      東京工芸大学厚木キャンパス
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] カルバゾール置換型ポリグルタメートの誘電挙動2010

    • Author(s)
      高見澤陽介、川畑州一、比江島俊浩
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Related Report
      2011 Final Research Report
  • [Presentation] TEMPOラジカル誘導体を導入したポリグルタメートの液晶の発現2010

    • Author(s)
      金子純平、比江島俊浩
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 光伝導性カルバゾール基を側鎖に有するポリグルタメートの誘電挙動2010

    • Author(s)
      高見澤陽介・比江島俊浩
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリグルタメートを用いてらせん配列した有機ラジカルTEMPOのコンホメーション解析と磁気特性2010

    • Author(s)
      比江島俊浩・水谷藤雄
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリグルタメートらせんのもたらすニトロキシラジカルスピンの秩序構造解析と磁気特性2010

    • Author(s)
      比江島俊浩・金子純平
    • Organizer
      第4回分子科学討論会2010大阪
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2010 Annual Research Report
  • [Presentation] らせんスピン秩序を有するポリグルタメートの磁気特性2010

    • Author(s)
      比江島俊浩・金子純平
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] TEMPOラジカル誘導体を導入したポリグルタメートの液晶の発現2010

    • Author(s)
      金子純平・比江島俊浩
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] カルバゾール置換型ポリグルタメートの誘電挙動2010

    • Author(s)
      高見澤陽介・川畑州一・比江島俊浩
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] らせん骨格を有するポリ(L-グルタメート)の側鎖に導入した有機ラジカルTEMPOのコンホメーション解析と磁気特性2009

    • Author(s)
      比江島俊浩・水谷藤雄・阿部二朗
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・神戸国際展示場
    • Related Report
      2009 Annual Research Report
  • [Presentation] 主鎖型液晶の液晶形成に及ぼすネマチックコンホメーションの効果2009

    • Author(s)
      比江島俊浩
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学工学部
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリグルタメートを正孔輸送材料に用いた単層型有機EL素子の発光効率に与える溶媒の効果2009

    • Author(s)
      高見澤陽介・田中良実・内田孝幸・比江島俊浩
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学工学部
    • Related Report
      2009 Annual Research Report
  • [Presentation] らせん骨格を有するポリ(L-グルタメート)の側鎖に導入した有機ラジカルTEMPOのコンホメーション解析と磁気特性2009

    • Author(s)
      水谷藤雄・比江島俊浩・阿部二朗
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学工学部
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリグルタメートの側鎖にらせん配列した有機ラジカルTEMPOのコンホメーション解析と磁気特性2009

    • Author(s)
      比江島俊浩・水谷藤雄・阿部二朗
    • Organizer
      第3回分子科学討論会2009名古屋
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2009 Annual Research Report
  • [Presentation] 有機導体α-(BEDT-TTF)2MHg(SCN)4 (M=NH_4,K,Rb,Tl)の低温下の赤外・ラマン測定2009

    • Author(s)
      山田栄彰・比江島俊浩・売市幹大・薬師久弥
    • Organizer
      第3回分子科学討論会2009名古屋
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2009 Annual Research Report
  • [Presentation] Infrared and Raman Studies of α-(BEDT-TTF)_2MHg(SCN)_4 with M=K and NH_4 at Low Temperature-the charge ordering fluctuation with breaking the inversion symmetry2009

    • Author(s)
      Toshihiro Hiejima, Shigeaki Yamada, Mikio Uruichi, Kyuya Yakushi
    • Organizer
      The 64^<th> Yamada Conference, The 8^<th> international Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets.
    • Place of Presentation
      Hilton Niseko Village
    • Related Report
      2009 Annual Research Report
  • [Presentation] Charge Order and its Fluctuation in a-type BEDT-TTF Charge Transfer Salts2009

    • Author(s)
      Y.Yue, C.Nakano, K.Yamamoto, M.Uruichi, K.Yakushi, T.Hiejima, A.Kawamoto
    • Organizer
      The 64^<th> Yamada Conference, The 8^<th> international Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets.
    • Place of Presentation
      Hilton Niseko Village
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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