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Elucidation of electrodeposition mechanism on metallic glass film

Research Project

Project/Area Number 21550188
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionUniversity of Yamanashi

Principal Investigator

SHIBATA Masami  山梨大学, 大学院・医学工学総合研究部, 教授 (40115316)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Keywords電気化学 / 機能性ガラス / 電析 / 金属ガラス / ガラス転移温度 / 結晶化温度 / ジルコニウム基 / パラジウム基 / 薄膜形成
Research Abstract

The composition of the electrodeposited Pd-Ni-P films was controlled by adjusting the current density and the composition of Pd-Ni-P bath. The electrodeposited Pd-Ni-P films are metallic glass with Pd, Ni, and P compositions of 36-57at%, 25-43at%, and 17-20at%, respectively, which were almost identical to those in bulk Pd-Ni-P metallic glass. The alloy composition of the electrodeposited Pd_<42> Ni_<37> P_<21> metallic glass film was very similar to that of Pd_<40> Ni_<40> P_<20>, which is one of the best bulk metallic glasses because of its glass forming ability.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (26 results)

All 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (21 results)

  • [Journal Article] 電析Pd-Ni-P金属ガラス薄膜の作製と皮膜組織に及ぼす浴組成の影響2012

    • Author(s)
      望月千裕、千賀崇史、山中淳二、柴田正実
    • Journal Title

      表面技術

      Volume: Vol.63、No.5 Pages: 323-328

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 電析Pd-Ni-P金属ガラス薄膜の作製と皮膜組成に及ぼす浴組成の影響2012

    • Author(s)
      望月千裕
    • Journal Title

      表面技術

      Volume: 63(印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電析によるPd-Ni-P金属ガラス薄膜の作製2011

    • Author(s)
      望月千裕、千賀崇史、柴田正実
    • Journal Title

      Electrochemistry

      Volume: Vol.79、No.4 Pages: 249-251

    • NAID

      10027962032

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 電析によるPd-Ni-P金属ガラス薄膜の作製2011

    • Author(s)
      望月千裕
    • Journal Title

      Electrochemistry

      Volume: 79 Pages: 249-251

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電析によるPd-Ni-P金属ガラス薄膜の作製

    • Author(s)
      望月千裕
    • Journal Title

      Electrochemistry

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pd-based metallic glass films formed by electrodeposition process2012

    • Author(s)
      Masami Shibata(代表)
    • Organizer
      18^<th> International Conference on Solid Compounds of Transition Elements
    • Place of Presentation
      リスボン大学
    • Year and Date
      2012-04-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 熱処理したPd-Ni-P金属ガラスめっきの構造に及ぼす組成の影響2012

    • Author(s)
      柴田正実(代表)
    • Organizer
      表面技術協会第125回講演大会
    • Place of Presentation
      東京都市大学
    • Year and Date
      2012-03-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Pd-based metallic glass films formed by electrodeposition process2012

    • Author(s)
      Masami Shibata, Chihiro Mochizuki, Takashi Senga
    • Organizer
      18^<th> International Conference on Solid Compounds of Transition Elements
    • Related Report
      2011 Final Research Report
  • [Presentation] 熱処理したPd-Ni-P金属ガラスのめっき構造に及ぼす組成の影響2012

    • Author(s)
      一色洋之、望月千裕、柴田正実
    • Organizer
      表面技術協会第125回講演大会
    • Related Report
      2011 Final Research Report
  • [Presentation] The structural changes with heating in the electrodeposited Pd-Ni-P metallic glass films2011

    • Author(s)
      Masami Shibata(代表)
    • Organizer
      The 62^<nd> Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      朱鷺メッセ(新潟)
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Pd-Cu-Ni-P合金組成と構造に及ぼす電析条件の検討2011

    • Author(s)
      柴田正実
    • Organizer
      表面技術協会第123回講演大会
    • Place of Presentation
      関東学院大学
    • Year and Date
      2011-03-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 熱処理したPdNip金属ガラスめっき皮膜のナノインデンテーション特性2011

    • Author(s)
      柴田正実
    • Organizer
      表面技術協会第123回講演大会
    • Place of Presentation
      関東学院大学
    • Year and Date
      2011-03-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] PdNip金属ガラス薄膜の組成と熱による構造変化2011

    • Author(s)
      柴田正実
    • Organizer
      表面技術協会第123回講演大会
    • Place of Presentation
      関東学院大学
    • Year and Date
      2011-03-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] The structural changes with heating in the electrodeposited Pd-Ni-P metallic glass films2011

    • Author(s)
      Chihiro Mochizuki, Takashi Senga, Masami Shibata
    • Organizer
      The 62_<nd> Annual Meeting of the International Society of Electrochemistry
    • Related Report
      2011 Final Research Report
  • [Presentation] Pd-Ni-P金属ガラス薄膜の組成と熱による構造変化2011

    • Author(s)
      望月千裕、一色洋之、山本千綾、山中淳二、柴田正実
    • Organizer
      表面技術協会第123回講演大会
    • Related Report
      2011 Final Research Report
  • [Presentation] Pd-Cu-Ni-P合金組成と構造に及ぼす電析条件の検討2011

    • Author(s)
      千賀崇史、望月千裕、柴田正実
    • Organizer
      表面技術協会第123回講演大会
    • Related Report
      2011 Final Research Report
  • [Presentation] 熱処理したPd-Ni-P金属ガラスめっき皮膜のナノインデンテーション特性2011

    • Author(s)
      鈴木理、望月千裕、柴田正実
    • Organizer
      表面技術協会第123回講演大会
    • Related Report
      2011 Final Research Report
  • [Presentation] 電析法により作製したPd-Ni-P金属ガラス薄膜に及ぼす熱処理の影響2010

    • Author(s)
      柴田正実
    • Organizer
      電気化学会第34回電解技術討論会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fe-Ni-P-B合金皮膜の組成および構造に及ぼすめっき条件の影響2010

    • Author(s)
      柴田正実
    • Organizer
      表面技術協会第122回講演大会
    • Place of Presentation
      東北大学
    • Year and Date
      2010-09-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation of Pd-Ni-P Metallic Glasses by Electrodeposition Method2010

    • Author(s)
      M.Shibata
    • Organizer
      3rdEuCheMS Chemistry Congress
    • Place of Presentation
      ニュルンベルク(ドイツ)
    • Year and Date
      2010-08-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属ガラスPd-Ni-P皮膜の電析2010

    • Author(s)
      柴田正実
    • Organizer
      表面技術協会第121回講演大会
    • Place of Presentation
      成蹊大学(東京都)
    • Year and Date
      2010-03-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] 無電解Pd-Ni-P合金めっきの組成比と皮膜特性2010

    • Author(s)
      柴田正実
    • Organizer
      表面技術協会第121回講演大会
    • Place of Presentation
      成蹊大学(東京都)
    • Year and Date
      2010-03-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formation of Pd-Ni-P Metallic Glasses by Electro-deposition Method2010

    • Author(s)
      Masami Shibata, Chihiro Mochizuki, Takashi Senga
    • Organizer
      3^<rd> EuCheMS Chemistry Congress
    • Related Report
      2011 Final Research Report
  • [Presentation] 電析法により作製したPd-Ni-P金属ガラス薄膜に及ぼす熱処理の影響2010

    • Author(s)
      一色洋之、望月千裕、山本千綾、山中淳二、柴田正実
    • Organizer
      第34回電解技術討論会
    • Related Report
      2011 Final Research Report
  • [Presentation] 無電解Pd-Ni-P合金めっきの組成比と皮膜特性2010

    • Author(s)
      鈴木理、一色洋之、望月千裕、柴田正実
    • Organizer
      表面技術協会第121回講演大会
    • Related Report
      2011 Final Research Report
  • [Presentation] 金属ガラスPd-Ni-P皮膜の電析2010

    • Author(s)
      千賀崇史、柴田正実
    • Organizer
      表面技術協会第121回講演大会
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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