Development of crystallized mesoporous materials including singlesite organometallic complexes and their catalytic activity with high selectivity

• Project/Area Number: 21550192
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Osaka Prefecture University
• Principal Investigator: MATSUOKA Masaya 大阪府立大学, 大学院・工学研究科, 教授 (80305648)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: 無機工業化学 / 触媒・化学プロセス / ナノ材料 / 表面・界面物性 / 有機無機ハイブリッド / メソ多孔性材料 / 金属カルボニル錯体 / Ru錯体 / MOF / 脱ハロゲン化水素反応 / ヒドロシリル化反応 / カーボンナノチューブ / 不均一系触媒 / アルケンのエポキシ化反応 / XAFS測定 / フェニルアセチレンの重合 / 炭化水素の部分水素化反応 / 塩化ベンジルの重合反応 / オレフィンの光メタセシス反応

Research Abstract

Various organometallic complexes were immobilized by CVD or ligand exchange methods on inorganic-organic porous materials such as HMM-ph which involves phenylene moieties in the mesoporous silica structure or MOF which is composed of metal clusters and organic linkers. Organometallic complexes can also be immobilized on carbon nanotubes(CNT) by similar method. These unique heterogeneous catalysts can be applied for the epoxidation of alkenes or hydrosilylation of alkynes.

Research Products

• [Journal Article] Characterization of phenylene-bridged hybrid mesoporous materials incorporating arenetricarbonyl complexes(-C_6H_4Me(CO)_3-; Me=Cr, Mo) and their catalytic activities (2012)
  • Author(s): T. Kamegawa, M. Saito, T. Sakai, M. Matsuoka, M. Anpo
  • Journal Title: Catal. Today Volume: 181 Pages: 14-19
  • Peer Reviewed
• [Journal Article] Influence of the Ti content on the photocatalytic oxidation of 2-propanol and CO on TiSiBEA zeolites (2012)
  • Author(s): S. Dzwigaj, J-P. Nogier, M. Che, M. Saito, T. Hosokawa, E. Thouverez, M. Matsuoka, M. Anpo
  • Journal Title: Catal. Commun Volume: 19 Pages: 17-20
  • Peer Reviewed
• [Journal Article] Characterization of phenylene-bridged hybrid mesoporous materials incorporating arenetricarbonyl complexes (-C_6H_4Me(CO)_3- ; Me=Cr, Mo) and their catalytic activities (2012)
  • Author(s): T.Kamegawa, M.Saito, T.Sakai, M.Matsuoka, M.Anpo
  • Journal Title: Catalysis Today Volume: 181 Issue: 1 Pages: 14-19
  • DOI: 10.1016/j.cattod.2011.10.019
  • Peer Reviewed
• [Journal Article] Influence of the Ti content on the photocatalytic oxidation of 2-propanol and CO on TiSiBEA zeolites (2012)
  • Author(s): S.Dzwigaj, J-P.Nogier, M.Che, M.Saito, T.Hosokawa, E.Thouverez, M.Matsuoka, M.Anpo
  • Journal Title: Catalysis Communications Volume: 19 Pages: 17-20
  • Peer Reviewed
• [Journal Article] Preparation of inorganic-organic hybrid mesoporous material incorporating organoruthenium complexes(-[C_6H_4RuCp] PF_6-) and its application as a heterogeneous catalyst (2011)
  • Author(s): T. Kamegawa, M. Saito, T. Watanabe, K. Uchihara, M. Kondo, M. Matsuoka, M. Anpo
  • Journal Title: J. Mater. Chem Volume: 21 Pages: 12228-12231
  • Peer Reviewed
• [Journal Article] Preparation of inorganic-organic hybrid mesoporous material incorporating organoruthenium complexes (-[C_6H_4RuCp]PF_6-) and its application as a heterogeneous catalyst (2011)
  • Author(s): T.Kamegawa, M.Saito, T.Watanabe, K.Uchihara, M.Kondo, M.Matsuoka, M.Anpo
  • Journal Title: Journal of Materials Chemistry Volume: 21 Issue: 6 Pages: 12228-12231
  • DOI: 10.1039/b9nj00775j
  • Peer Reviewed
• [Journal Article] Incorporation of Arene Metal Carbonyl Complexes within Inorganic-organic Hybrid Mesoporous Materials by CVD Method (2009)
  • Author(s): M. Matsuoka, T. Kamegawa, T.-H. Kim, T. Sakai, M. Anpo
  • Journal Title: J. Nanosci. Nanotech Volume: 10 Pages: 114-124
  • Peer Reviewed
• [Journal Article] The Design of Ti-, V-, Cr-Oxide Single-Site Catalysts within Zeolite Frameworks and Their Photocatalytic Reactivity for the Decomposition of Undesirable Molecules-The Role of Their Excited States and Reaction Mechanisms- (2009)
  • Author(s): M. Anpo, T.-H. Kim, M. Matsuoka
  • Journal Title: Catal. Today Volume: 142 Pages: 114-124
  • Peer Reviewed
• [Journal Article] Incorporation of Arene Metal Carbonyl Complexes within Inorganic-organic Hybrid Mesoporous Materials by CVD Method (2009)
  • Author(s): M.Matsuoka, T.Kamegawa, T.-H.Kim, T.Sakai, M.Anpo
  • Journal Title: J.Nanosci.Nanotech. 10 Pages: 314-318
  • Peer Reviewed
• [Journal Article] The Design of Ti-, V-, Cr-Oxide Single-Site Catalysts within Zeolite Frameworks and Their Photocatalytic Reactivity for the Decomposition of Undesirable Molecules -The Role of Their Excited States and Reaction Mechanisms- (2009)
  • Author(s): M.Anpo, T.-H.Kim, M.Matsuoka
  • Journal Title: Catal.Today 142 Pages: 114-124
  • Peer Reviewed
• [Presentation] MOF (Metal-Organic Framework)光触媒を用いた可視光照射下での水素生成反応 (2012)
  • Author(s): 鳥屋尾隆, 齋藤雅和, 堀内悠, 岩田真叔, 東村秀之, 松岡雅也
  • Organizer: 第109回触媒討論会
  • Place of Presentation: 東京
  • Year and Date: 2012-03-28
• [Presentation] 金属-有機構造体(MOF)のアレーン部位に固定化した金属カルボニル錯体の触媒活性-触媒活性に及ぼす細孔径の影響- (2012)
  • Author(s): 齋藤雅和, 上田洸造, 堀内悠, 亀川孝, 松岡雅也
  • Organizer: 第109回触媒討論会
  • Place of Presentation: 東京
  • Year and Date: 2012-03-28
• [Presentation] 可視光照射下で機能する多孔性金属錯体光触媒の開発 (2012)
  • Author(s): 鳥屋尾隆, 齋藤雅和, 堀内悠, 岩田真叔, 東村秀之, 松岡雅也
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2012-03-26
• [Presentation] 金属カルボニル錯体を固定化したZr含有MOFの触媒特性に及ぼす有機リンカーの種類の影響 (2012)
  • Author(s): 齋藤雅和, 上田洸造, 堀内悠, 亀川孝, 松岡雅也
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2012-03-26
• [Presentation] Design of Metal-Organic Framework Photocatalysts for Efficient Hydrogen Production with Visible-Light (2012)
  • Author(s): T. Toyao, M. Saito, Y. Horiuchi, M. Iwata, H. Higashimura and M. Matsuoka
  • Organizer: The 13th International Symposium on Eco-materials Processing and Design
  • Place of Presentation: Guilin, China
  • Year and Date: 2012-01-10
• [Presentation] Photocatalytic Hydrogen Production on Ti-Based Metal-Organic Framework under Visible-Light Irradiation (2011)
  • Author(s): T. Toyao, M. Saito, Y. Horiuchi, M. Iwata, H. Higashimura and M. Matsuoka
  • Organizer: International Meeting on Novel Catalyst Design and Surface Science
  • Place of Presentation: Himeji, Japan
  • Year and Date: 2011-12-10
• [Presentation] Preparation of Ru+CpPF_6-Complexes Immobilized within HMM-ph and CNTs and Their Catalytic Ability for Hydrosilylation of Terminal Alkyne (2011)
  • Author(s): M. Saito, T. Watanabe, Y. Horiuchi, T. Kamegawa and M. Matsuoka
  • Organizer: International Symposium on Catalysis and Fine Chemicals
  • Place of Presentation: Nara, Japan
  • Year and Date: 2011-12-05
• [Presentation] Preparation of Ru^+CpPF_6^- Complexes Immobilized within HMM-ph and CNTs and Their Catalytic Ability for Hydrosilylation of Terminal Alkyne (2011)
  • Author(s): M.Saito, T.Watanabe, Y.Horiuchi, T.Kamegawa, M.Matsuoka
  • Organizer: International Symposium on Catalysis and Fine Chemicals
  • Place of Presentation: Nara, Japan
  • Year and Date: 2011-12-05
• [Presentation] Synthesis of Visible-Light Responsive Metal-Organic Framework (MOF) Photocatalyst for Efficient Hydrogen Production (2011)
  • Author(s): T.Toyao, M.Saito, Y.Horiuchi, M.Iwata, H.Higashimura, M.Matsuoka
  • Organizer: International Symposium on Catalysis and Fine Chemicals
  • Place of Presentation: Nara, Japan
  • Year and Date: 2011-12-05
• [Presentation] 種々の有機リンカーを用いたMetal-organic framework (MOF)光触媒の創製とその上での水素生成反応 (2011)
  • Author(s): 鳥屋尾隆, 齋藤雅和, 堀内悠, 松岡雅也
  • Organizer: 第27回ゼオライト研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2011-12-01
• [Presentation] 各種担体に固定化したCpRu^+錯体触媒の調製と1-ヘキシンのヒドロシリル化反応への応用 (2011)
  • Author(s): 細川拓也, 齋藤雅和, 亀川孝, 堀内悠, 松岡雅也
  • Organizer: 第27回ゼオライト研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2011-12-01
• [Presentation] 可視光応答型Metal-organic framework(MOF)光触媒の設計と光水素生成反応への応用 (2011)
  • Author(s): 堀内悠, 鳥屋尾隆, 齋藤雅和, 岩田真叔, 東村秀之, 松岡雅也
  • Organizer: 第30回固体・表面光化学討論会
  • Place of Presentation: 長野
  • Year and Date: 2011-11-21
• [Presentation] 可視光応答型Metal-organic framework (MOF)光触媒の設計と光水素生成反応への応用 (2011)
  • Author(s): 堀内悠, 鳥屋尾隆, 齋藤雅和, 岩田真叔, 東村秀之, 松岡雅也
  • Organizer: 第30回固体・表面光化学討論会
  • Place of Presentation: 長野
  • Year and Date: 2011-11-21
• [Presentation] 金属-有機構造体(MOF)を担体として利用したArMo(CO)_3(M:Cr,Mo)錯体の調製とその上でのシクロオクテンのエポキシ化反応 (2011)
  • Author(s): 齋藤雅和, 上田洸造, 堀内悠, 亀川孝, 松岡雅也
  • Organizer: 第4回触媒表面化学研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2011-11-04
• [Presentation] カーボンナノチューブ上に固定化したCpRu^+錯体を触媒に用いる1-ヘキシンのヒドロシリル化反応 (2011)
  • Author(s): 細川拓也, 渡辺哲二, 齋藤雅和, 亀川孝, 松岡雅也
  • Organizer: 第4回触媒表面化学研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2011-11-04
• [Presentation] 金属-有機構造体(MOF)のアレーン(Ar)部位に固定化したArM(CO)_3(M=Cr,Mo)錯体の触媒特性-触媒活性に及ぼすAr部位の置換基効果- (2011)
  • Author(s): 齋藤雅和, 上田洸造, 堀内悠, 亀川孝, 松岡雅也
  • Organizer: 第108回触媒討論会
  • Place of Presentation: 北海道
  • Year and Date: 2011-09-22
• [Presentation] Preparation of Functionalized Zr(IV) Metal-Organic Frameworks Incorporating Metal Tricarbonyl Complexes and Their Applications for Heterogeneous Catalysts (2011)
  • Author(s): 齋藤雅和, 上田洸造, 鳥屋尾隆, 堀内悠, 亀川孝, 松岡雅也
  • Organizer: 第2回触媒科学研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2011-06-17
• [Presentation] Preparation of CpRu^+ complexes immobilized on carbon-coated MCM-41 and their catalytic properties for hydrosilation of 1-hexyne (2011)
  • Author(s): 細川拓也, 渡辺哲二, 齋藤雅和, 亀川孝, 松岡雅也
  • Organizer: 第2回触媒科学研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2011-06-17
• [Presentation] Catalytic Properties of Ru+Cp Complexes Immobilized within Various Supports by the Ligand Exchange Reaction (2011)
  • Author(s): M. Saito, T. Watanabe, T. Kamegawa and M. Matsuoka
  • Organizer: 5th Int. Conf. Sci. Technol. for Advanced Ceramics and 2nd Int. Conf. Advanced Materials Development and Integration
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2011-06-05
• [Presentation] Catalytic Properties of Ru^+Cp Complexes Immobilized within Various Supports by the Ligand Exchange Reaction (2011)
  • Author(s): M.Saito, T.Watanabe, T.Kamegawa, M.Matsuoka
  • Organizer: 5th Int.Conf.Sci.Technol.for Advanced Ceramics and 2nd Int.Conf.Advanced Materials Development and Integration
  • Place of Presentation: Seoul, Korea
  • Year and Date: 2011-06-05
• [Presentation] 各種担体上に固定化した[CpRu^+C_6H_6]PF_6-錯体のキャラクタリゼーションとそ触媒反応性 (2011)
  • Author(s): 齋藤雅和、渡辺哲二、細川拓也、亀川孝、松岡雅也
  • Organizer: 第107回触媒討論会
  • Place of Presentation: 東京 首都大学東京
  • Year and Date: 2011-03-29
• [Presentation] 各種担体上に固定化した有機ルテニウム錯体のキャラクタリゼーションとその上での触媒反応 (2011)
  • Author(s): 齋藤雅和、渡辺哲二、細川拓也、亀川孝、松岡雅也
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 神奈川 神奈川大学
  • Year and Date: 2011-03-27
• [Presentation] Preparations of Pt deposited MOFs (Metal-organic frameworks) by photoassisted deposition method and their photocatalytic activities (2011)
  • Author(s): 鳥屋尾隆、上田洸造、齋藤雅和、亀川孝、松岡雅也
  • Organizer: 第1回触媒表面科学研究発表会
  • Place of Presentation: 大分 大分大学
  • Year and Date: 2011-01-17
• [Presentation] Catalytic Activity of Ru^+Cp Complex Immobilized within HMM-ph and CNTs for Hydrosilylation of Terminal Alkyne (2011)
  • Author(s): T.Watanabe, M.Saito, T.Kamegawa, M.Matsuoka
  • Organizer: The 12th International Symposium on Eco-materials Processing and Design
  • Place of Presentation: Chiang Mai, Thailand
  • Year and Date: 2011-01-10
• [Presentation] Preparation of Metal organic Frameworks (MOF) Incorporating Arene-M(CO)_3 (M=Cr, Mo) Complexes and Their Application for Heterogeneous Catalysts (2011)
  • Author(s): K.Ueda, M.Saito, T.Kamegawa, M.Matsuoka, M.Anpo
  • Organizer: The 12th International Symposium on Eco-materials Processing and Design
  • Place of Presentation: Chiang Mai, Thailand
  • Year and Date: 2011-01-10
• [Presentation] Pt担持Ti含有MOF(Metal-organic frameworks)の調製とその上での光触媒酸化反応 (2010)
  • Author(s): 鳥屋尾隆、上田洸造、齋藤雅和、亀川孝、松岡雅也
  • Organizer: 第20回キャラクタリゼーション講習会
  • Place of Presentation: 大分 大分大学
  • Year and Date: 2010-10-15
• [Presentation] イオン交換反応法により各種担体に固定化したルテニウム錯体のキャラクタリゼーションとその触媒反応特性 (2010)
  • Author(s): 齋藤雅和、渡辺哲二、亀川孝、松岡雅也
  • Organizer: 第106回触媒討論会
  • Place of Presentation: 山梨 山梨大学
  • Year and Date: 2010-09-16
• [Presentation] 配位子交換法により各種多孔体上に固定化したRu^+Cp錯体の触媒反応性 (2010)
  • Author(s): 渡辺哲二、齋藤雅和、亀川孝、松岡雅也
  • Organizer: 第106回触媒討論会
  • Place of Presentation: 山梨 山梨大学
  • Year and Date: 2010-09-16
• [Presentation] CVD法により骨格内に金属カルボニル錯体を固定化した新規Metal-organic frameworks(MOF)の調製とその触媒反応特性 (2010)
  • Author(s): 上田洸造、齋藤雅和、亀川孝、松岡雅也
  • Organizer: 第106回触媒討論会
  • Place of Presentation: 山梨 山梨大学
  • Year and Date: 2010-09-16
• [Presentation] Al-MCM-41に固定化した有機ルテニウム錯体を不均一系触媒とする末端アルキンのヒドロシリル化反応の検討 (2010)
  • Author(s): 齋藤雅和、内原和弘、渡辺哲二、亀川孝、松岡雅也
  • Organizer: 第4回触媒道場
  • Place of Presentation: 島根 松江ニューアーバンホテル
  • Year and Date: 2010-09-04
• [Presentation] 配位子交換法によりHMM-ph細孔骨格内に構築した[CpRu^+ph]錯体の触媒反応性 (2010)
  • Author(s): 渡辺哲二、内原和弘、齋藤雅和、金兌鎬、亀川孝、松岡雅也、安保正一
  • Organizer: 日本化学会第90回春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-27
• [Presentation] CVD法によりアレーン金属カルボニル錯体を含有したMetal-organic framework(MOF)の創製とその触媒特性 (2010)
  • Author(s): 上田洸造、亀川孝、松岡雅也、安保正一
  • Organizer: 日本化学会第90回春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-27
• [Presentation] Catalytic Activity of C_6H_4Ru^+Cp Complex Incorporated within HMM-ph for Hydrosilylation of Terminal Alkyne (2010)
  • Author(s): T.Watanabe, K.Uchihara, M.Saitoh, T.H.Kim, T.Kamegawa, M.Matsuoka, M.Anpo
  • Organizer: International Symposium on Eco-materials Processing and Design(ISEPD 2010)
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2010-01-10
• [Presentation] Catalytic Activities of Metal carbonyl Complexes Incorporated within Inorganic-organic Hybrid Mesoporous Materials (2009)
  • Author(s): Y.Sakai, M.Matsuoka, T.Kamegawa, T.Sakai, M.Anpo
  • Organizer: 15th International Conference on Advanced Oxidation Technologies for Treatment of Water, Air and Soil
  • Place of Presentation: New York, USA
  • Year and Date: 2009-10-16
• [Presentation] Catalytic Properties of CpRu^+L_N Complexes[L=C_6H_4, O_<(L)N>]within Various Mesoporous Materials (2009)
  • Author(s): T.Watanabe, K.Uchihara, T.H.Kim, T.Kamegawa, M.Matsuoka, M.Anpo
  • Organizer: The 12^<th> Japan-Korea Symposium on Catalysis
  • Place of Presentation: Akita, Japan
  • Year and Date: 2009-10-14
• [Presentation] CVD法により金属カルボニル錯体を固定化したMetal-Organic Framework(MOF)の創製と触媒反応 (2009)
  • Author(s): 上田洸造、亀川孝、松岡雅也、安保正一
  • Organizer: 第2回触媒表面化学研究発表会
  • Place of Presentation: 大阪
  • Year and Date: 2009-10-09
• [Presentation] 配位子交換法により調製したHMM-phRu^+Cpの触媒反応性 (2009)
  • Author(s): 渡辺哲二、内原和弘、齋藤雅和、金兌鎬、亀川孝、松岡雅也、安保正一
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2009-09-27
• [Presentation] CVD法により金属カルボニル錯体を固定化したMetal-Organic Framework(MOF)の創製と触媒反応 (2009)
  • Author(s): 上田洸造、亀川孝、松岡雅也、安保正一
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2009-09-27
• [Presentation] A1MCM-41上に固定化したCpRu^+C6H6錯体の触媒反応性 (2009)
  • Author(s): 内原和弘、渡辺哲二、金兌鎬、亀川孝、松岡雅也、安保正一
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2009-09-27
• [Presentation] 金属カルボニル錯体を固定化した無機有機ハイブリッドメソポーラスシリカの触媒特性 (2009)
  • Author(s): 酒井勇輔、亀川孝、松岡雅也、安保正一
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎
  • Year and Date: 2009-09-27
• [Presentation] Photochemical and Catalytic Properties of Organo-Ru Complexes within Various Mesoporous Materials (2009)
  • Author(s): K.Uchihara, T.Watanabe, T.H.Kim, T.Kamegawa, M.Matsuoka, M.Anpo
  • Organizer: XXIV International Conference on Photochemistry
  • Place of Presentation: Toledo, Spain
  • Year and Date: 2009-07-20
• [Presentation] Catalytic Properties of Organo-Ruthenium Complexes Immobilized within Various Mesoporous Materials (2009)
  • Author(s): T.-H.Kim, T.Watanabe, K.Uchihara, T.Kamegawa, M.Matsuoka, M.Anpo
  • Organizer: The 4^<th> East Asia Symposium on Functional Dyes and Advanced Materials
  • Place of Presentation: Osaka
  • Year and Date: 2009-06-03
• [Patent(Industrial Property Rights)] 光機能性材料、水分解光触媒及び金属錯体 (2011)
  • Inventor(s): 松岡雅也、堀内悠、鳥屋尾隆、齋藤雅和、岩田真叔、東村秀之
  • Industrial Property Rights Holder: 住友化学(株)、大阪府立大学
  • Industrial Property Number: 2011-251557
  • Filing Date: 2011-11-17
• [Patent(Industrial Property Rights)] 光機能性材料、水分解光触媒及び金属錯体 (2011)
  • Inventor(s): 松岡雅也, 堀内悠, 鳥屋尾隆, 齋藤雅和, 岩田真叔, 東村秀之
  • Industrial Property Rights Holder: 大阪府立大学、住友化学
  • Industrial Property Number: 2011-251557
  • Filing Date: 2011-11-17