Construction of Molecular Reaction Flask Using Assemblies of Well-Defined Stimuli-Responsive Star-Shaped Polymers
Project/Area Number |
21550209
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Polymer/Textile materials
|
Research Institution | Osaka University |
Principal Investigator |
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
Keywords | 星型ポリマー / リビング重合 / カチオン重合 / ワンステップ合成 / 分子フラスコ / ドミノ合成 / 刺激応答性 / ビニルエーテル / スチレン誘導体 / コアファースト法 / 高分子ミセル / 温度応答フィルム / アミノ基 |
Research Abstract |
Star-shaped polymers with many arms may function as" molecular flasks," as their structures can be multi-layered. In order to realize effective reactions fields, star polymers with multiple components should be precisely synthesized. In this study, innovation strategies for precision star polymer synthesis of star polymers were achieved using base-assisting living cationic polymerization. Facile one-step synthesis of star polymers based on monomer-selective domino living polymerization of a vinyl ether and a divinyl compound with alkoxystyryl moieties can be achieved using an EtAlCl_2/ SnCl_4 initiating system. Well-defined star polymers were also synthesized by a core-first method, in which a microgel core was first prepared. Heteroarm star polymers were prepared by simple mixing of a couple of living polymers with a divinyl compound.
|
Report
(4 results)
Research Products
(79 results)