Development of fluorescent organic-inorganic IPN hybrid gels and its application for plane emission device

• Project/Area Number: 21550211
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Shibaura Institute of Technology
• Principal Investigator: NAGA Naofumi 芝浦工業大学, 工学部, 准教授 (40314538)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2009: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
• Keywords: ゲル / 共役高分子 / 発光素子 / 相互侵入網目 / 有機-無機ハイブリッドゲル / σ-π共役高分子 / 電気化学発光 / 平面発光素子

Research Abstract

Development of organic-inorganic IPN hybrid gels with fluorescent properties were investigated for a plane flexible electro-generated chemi-luminescence display. The organic-inorganic hybrid gels were synthesized in the presence of liner σ-π conjugated luminescent linear polymers in organic solvent. Network structure and luminescent properties of the resulting hybrid semi-IPN gels were studied.

Research Products

• [Journal Article] Synthesis and Chemosensing Behavior of Fluorene-Based Alternating Copolymers Containing Si and Vinylene Units in the Main Chain (2011)
  • Author(s): N. Naga, Y. Ohkura, N. Tagaya, H. Tomoda
  • Journal Title: J. Polym. Sci. Part A, Polym. Chem Volume: Vol.49 Pages: 4925-4940
  • Peer Reviewed
• [Journal Article] Synthesis and Chemosensing Behavior of Fluorene-Based Alternating Copolymers Containing Si and Vinylene Units in the Main Chain (2011)
  • Author(s): N.Naga, et.al.
  • Journal Title: J.Polym.Sci.Part A ; Polym.Chem. Volume: 49 Pages: 4935-4940
  • Peer Reviewed
• [Journal Article] Synthesis and optical properties of organic-inorganic hybrid gels containing fluorescent molecules (2010)
  • Author(s): N. Naga, T. Miyanaga, H. Furukawa
  • Journal Title: Polymer Volume: Vol.51 Pages: 5095-5099
  • Peer Reviewed
• [Journal Article] Synthesis and optical properties of organic-inorganic hybrid gels containing fluorescent molecules (2010)
  • Author(s): N.Naga, T.Miyanaga, H.Furukawa
  • Journal Title: Polymer Volume: 51 Pages: 5095-5099
  • Peer Reviewed
• [Presentation] 多官能チオール化合物を用いたゲルの合成と特性解析 (2011)
  • Author(s): 永見陽佑, 永直文, 古川英光
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: 大阪国際会議場
  • Year and Date: 2011-05-27
• [Presentation] ポリフルオレンを含有する有機-無機ハイブリッドsemi-IPNゲルの合成と光学的特性解析 (2011)
  • Author(s): 永直文, 宮永朋治, 古川英光
  • Organizer: 第22回高分子ゲル研究討論会
  • Place of Presentation: 東京大学山上開館
  • Year and Date: 2011-01-12
• [Presentation] ポリフルオレンを含有する有機-無機ハイブリッドsemi-IPNゲルの合成と光学的特性解析 (2011)
  • Author(s): 永直文, 宮永朋治, 古川英光
  • Organizer: 第22回高分子ゲル研究討論会
  • Place of Presentation: 東京大学山上会館
  • Year and Date: 2011-01-12
• [Presentation] Synthesis and optical properties of organic-inorganic hybrid gels containing conjugated polymers (2010)
  • Author(s): N. Naga, T. Miyanaga, H. Furukawa
  • Organizer: PACIFICHEM 2010
  • Place of Presentation: ハワイコンベンションセンター
  • Year and Date: 2010-12-17
• [Presentation] S Synthesis and optical properties of organic-inorganic hybrid gels containing conjugated polymers (2010)
  • Author(s): N.Naga, T.Miyanaga, H.Furukawa
  • Organizer: PACIFICHEM 2010
  • Place of Presentation: ハワイコンベンションセンター
  • Year and Date: 2010-12-17
• [Presentation] π共役系高分子/有機-無機ハイブリッドsemi-IPNゲルの合成と光学的特性解析 (2009)
  • Author(s): 宮永朋治, 永直文, 古川英光
  • Organizer: 第18回ポリマー材料フォーラム
  • Place of Presentation: タワーホール船堀(東京)
  • Year and Date: 2009-11-26
• [Presentation] π共役系高分子/-機ハイブリッド semi-IPN ゲルの合成と光学的特性解析 (2009)
  • Author(s): 宮永朋治, 永直文, 古川英光
  • Organizer: 第18回 ポリマー材料フォーラム
  • Place of Presentation: タワーホール船堀(東京)
  • Year and Date: 2009-11-26