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Development of an organic thin film solar cell with no bottleneck for hole transport using polymer phthalocyanines

Research Project

Project/Area Number 21560018
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionShimane University

Principal Investigator

HIROMITSU Ichiro  島根大学, 総合理工学部, 教授 (40199138)

Co-Investigator(Kenkyū-buntansha) HANDA Makoto  島根大学, 総合理工学部, 教授 (70208700)
Co-Investigator(Renkei-kenkyūsha) TANAKA Senku  島根大学, 総合理工学部, 助教 (20397855)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords有機・分子エレクトロニクス / 太陽電池 / 分子性固体 / 有機半導体 / 薄膜 / 高分子 / フタロシアニン
Research Abstract

In the thin film of one-dimensional polymer phthalocyanine GaPcF deposited on ITO substrate, the polymer axes usually lie parallel to the substrate. In the present study, however, it has been succeeded to obtain a highly ordered alignment in which the polymer axes stand on the substrate. This made it possible to produce an organic thin film solar cells with no bottleneck for hole transport. However, the solar cells thus produced showed no improvement in the photovoltaic characteristics. This suggests that the resistance at the surface of the GaPcF film was increased by the alignment.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (34 results)

All 2012 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (20 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Effect of iodine doping of phthalocyanine on the photocurrent generation in a phthalo-cyanine/C60 heterojunction2012

    • Author(s)
      Shinsei Mizuta, Masatoshi Iyota, Senku Tanaka, Ichiro Hiromitsu
    • Journal Title

      Thin Solid Films

      Volume: 520 Pages: 5761-5769

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Luminescence of tetra-phenylporphyrin by an energy transfer from photoexcited ZnO nanoparticle2011

    • Author(s)
      Ichiro Hiromitsu, Ayana Kawami, Senku Tanaka, Shigekazu Morito, Ryo Sasai, Takahisa Ikeue, Yasuhisa Fujita and Makoto Handa
    • Journal Title

      Chemical Physics Letters

      Volume: 501 Pages: 385-389

    • NAID

      120005694043

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Improve-ment of power conversion efficiency on phthalocyanine/C60 hetero-junction solar cells by inserting a lithium phthalo-cyanine layer at the indium-tin oxide/phthalocyanine interface2010

    • Author(s)
      Senku Tanaka, Toshiyuki Hanada, Koji Ono, Kazuya Watanabe, Katsumi Yoshino and Ichiro Hiromitsu
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly ordered molecular orientation in a phthalocyanine film deposited on a well-polished indium-tin oxide sub-strate2010

    • Author(s)
      Hiroaki Ishihara, Toyotsugu Kusagaya, Senku Tanaka and Ichiro Hiromitsu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 49

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly ordered molecular orientation in a phthalocyanine film deposited on a well-polished indium-tin oxide substrate2010

    • Author(s)
      石原裕朗, 他
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of power conversion efficiency on phthalocyanine/C_<60> heterojunction solar cells by inserting a lithium phthalocyanine layer at the indium-tin oxide/phthalocyanine interface2010

    • Author(s)
      田中仙君, 他
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A polymer complex[Cu(O2CC6F5) 2(pyz)] n formed from Copper(II) pentafluoro-benzoate and pyrazine2009

    • Author(s)
      Makoto Handa, Yoshiyuki Ishitobi, Taku Yakuwa, Daisuke Yoshioka, Hideaki Ishida, Masahiro Mikuriya, Ichiro Hiromitsu, Hidekazu Tanaka and Takahisa Ikeue
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 82 Pages: 1277-1279

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Organic thin-film solar cells with a Cu anode : Improvement of the photovoltaic prop-erties on aging in air2009

    • Author(s)
      Yuki Yoshida, Senku Tanaka, Yasuhisa Fujita and Ichiro Hiromitsu
    • Journal Title

      Journal of Applied Physics

      Volume: 106

    • NAID

      120005694037

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Organic thin-film solar cells with a Cu anode : Improvement of the photovoltaic properties on aging in air2009

    • Author(s)
      吉田勇気, 他
    • Journal Title

      Journal of Applied Physics 106

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金属ドーピングした光電変換層を持つ有機薄膜太陽電池2011

    • Author(s)
      福澤謙
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光照射による有機薄膜の電子構造変化と光電変換特性との相関2011

    • Author(s)
      田中仙君
    • Organizer
      第72回応用物種学弁学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] ITO基板上に蒸着した鎖状高分子フタロシアニン薄膜の分子配向制御2011

    • Author(s)
      湊慎太郎
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] Control of molecular orientation of a phthalocyanine film deposited on an indium-tin oxide substrate2011

    • Author(s)
      広光一郎, 他
    • Organizer
      International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      仙台(大震災で会議は中止されたが,発表は成立している。)
    • Year and Date
      2011-03-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Effect of white light illumination on the electronic structure of Zn-phthalocyanine/C_<60> interface studied by photoelectron spectroscopy2011

    • Author(s)
      田中仙君, 他
    • Organizer
      International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      仙台(大震災で会議は中止されたが,発表は成立している。)
    • Year and Date
      2011-03-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属ドーピングした光電変換層をもつ有機薄膜太陽電池のデバイス特性2011

    • Author(s)
      田中仙君, 他
    • Organizer
      第58回応用物理学関連連合講演会
    • Place of Presentation
      厚木市(大震災で学会は中止されたが,発表は成立している。)
    • Year and Date
      2011-03-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属ドーピングした光電変換層を持つ有機薄膜太陽電池2011

    • Author(s)
      福澤謙, 花田俊幸, 田中仙君, 広光一郎
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 光照射による有機薄膜の電子構造変化と光電変換特性との相関2011

    • Author(s)
      田中仙君, 福澤謙, 広光一郎
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Related Report
      2011 Final Research Report
  • [Presentation] ITO基板上に蒸着した鎖状高分子フタロシアニン薄膜の分子配向制御2011

    • Author(s)
      湊慎太郎, 清友祥汰, 田中仙君, 広光一郎
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 金属ドーピングした光電変換層をもつ有機薄膜太陽電池のデバイス特性2011

    • Author(s)
      田中仙君, 花田俊幸, 福澤謙, 広光一郎
    • Organizer
      第58回応用物理学関連連合講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 酸化亜鉛微粒子-ポルフィリン複合体の発光特性III2011

    • Author(s)
      広光一郎, 池上崇久, 後藤智宏, 田中仙君, 藤田泰久, 半田真
    • Organizer
      第58回応用物理学関連連合講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2011 Final Research Report
  • [Presentation] Effect of white light illumination on the electronic structure of Zn-phthalocyanine/C60 inter-face studied by photoelectron spec-troscopy2011

    • Author(s)
      Senku Tanaka, Koji Ogawa, Masao Kamada, Ichiro Hiromitsu
    • Organizer
      International Conference on Molecular Electronics and Bio-electronics
    • Place of Presentation
      仙台国際センター
    • Related Report
      2011 Final Research Report
  • [Presentation] Control of molecular orientation of a phthalocyanine film deposited on an indium-tin oxide sub-strate2011

    • Author(s)
      Hiroaki Ishihara, Shintaro Minato, Toyotsugu Kusagaya, Senku Tanaka, Ichiro Hiromitsu
    • Organizer
      International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      仙台国際センター
    • Related Report
      2011 Final Research Report
  • [Presentation] Excitation energy transfer in ZnO-tetraphenylporphyrin conjugate2011

    • Author(s)
      Ichiro Hiromitsu, Ayana Kawami, Senku Tanaka, Shigekazu Morito, Ryo Sasai, Takahisa Ikeue, Yasuhisa Fujita, Makoto Handa
    • Organizer
      International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      仙台国際センター
    • Related Report
      2011 Final Research Report
  • [Presentation] Photocurrent characteristic of Ag/Zn-phthalocyanine/Ag cell : Effect of the deposition order of metal and phthalocyanine on the photovoltaic property2010

    • Author(s)
      田中仙君, 他
    • Organizer
      International Conference on Science and Technology of Synthetic Metals
    • Place of Presentation
      京都
    • Year and Date
      2010-07-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Organic thin film solar cells with a transparent electrode Ga-doped ZnO2010

    • Author(s)
      広光一郎, 他
    • Organizer
      International Conference on Science and Technology of Synthetic Metals
    • Place of Presentation
      京都
    • Year and Date
      2010-07-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] フタロシアニン薄膜の分子配向制御による薄膜太陽電池の効率改善の試み2010

    • Author(s)
      石原裕朗, 他
    • Organizer
      応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] Photocurrent characteristic of Ag/Zn-phthalocyanine/Ag cell : Effect of the deposition order of metal and phthalocyanine on the photovoltaic property2010

    • Author(s)
      Senku Tanaka, Masahiro Naruse, Ichiro Hiromitsu
    • Organizer
      International Conference on Science and Technology of Synthetic Metals
    • Place of Presentation
      京都国際会館
    • Related Report
      2011 Final Research Report
  • [Presentation] Organic thin film solar cells with a transparent electrode Ga-doped ZnO2010

    • Author(s)
      Ichiro Hiromitsu, Yuki Yoshida, Senku Tanaka, Yasuhisa Fujita, Katsumi Yoshino
    • Organizer
      International Conference on Science and Technology of Synthetic Metals
    • Place of Presentation
      京都国際会館
    • Related Report
      2011 Final Research Report
  • [Presentation] フタロシアニン薄膜の分子配向制御による薄膜太陽電池の効率改善の試み2010

    • Author(s)
      石原裕朗, 広光一郎, 草谷豊継, 田中仙君
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学
    • Related Report
      2011 Final Research Report
  • [Book] "Carrier generation in organic thin-film solar cells", in Encyclopedia of Nanoscience and Nanotechnology2011

    • Author(s)
      Ichiro Hiromitsu
    • Publisher
      American Scientific Publishers
    • Related Report
      2011 Final Research Report
  • [Book] Carrier generation in organic thin-film solar cells, in Encyclopedia of Nanoscience and Nanotechnology, ed.H.S.Nalwa2011

    • Author(s)
      広光一郎
    • Total Pages
      22
    • Publisher
      American Scientific Publisher
    • Related Report
      2011 Annual Research Report
  • [Book] 酸化亜鉛透明導電膜を用いた有機薄膜太陽電池の特性2010

    • Author(s)
      広光一郎
    • Publisher
      技術情報協会
    • Related Report
      2011 Final Research Report
  • [Book] 「酸化亜鉛透明導電膜を用いた有機薄膜大陽電池の特性」in「透明導電膜・フィルムの高透明・低抵抗化と耐久性向上」2010

    • Author(s)
      広光一郎
    • Total Pages
      13
    • Publisher
      技術情報協会
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.phys.shimane-u.ac.jp/hiromitsu_lab/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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