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Reactive Sputtering of Oxygen-Free Metal Nitride Films : Oxygen Incorporation and Effect on Electrical Properties

Research Project

Project/Area Number 21560054
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied physics, general
Research InstitutionSeikei University

Principal Investigator

BABA Shigeru  成蹊大学, 理工学部, 教授 (80114619)

Co-Investigator(Kenkyū-buntansha) NAKANO Takeo  成蹊大学, 理工学部, 助教 (40237342)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords反応性スパッタリング / 窒化チタン / パルススパッタリング / 高純度窒化物薄膜 / 大電力パルススパッタ / 高純度金属窒化物 / モード遷移 / 酸窒化物 / 窒化物薄膜
Research Abstract

Oxygen incorporation mechanism during reactive sputtering of titanium nitride was studied. Deposition condition was 2-5 W/cm^<2> and 0.05-0.2 nm/s. High purity films could be obtained in a partial pressure of less than 1×10^<-5> Pa of O_2.Introduction of O_2 beyond a partial pressure of 1×10^<-4> Pa traces of O was detected in the film. With increasing the discharge power, the gettering of residual O_2 by sputtered Ti atoms worked effectively to obtain nitride films of high purity. The pulse sputtering method was found very effective under the low power operation compared to the DC sputtering, but as the power was increased the efficiency of sputtering in the pulse method slowed down approaching to that of the DC sputtering.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (52 results)

All 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 5 results) Presentation (34 results) Book (7 results) Remarks (1 results)

  • [Journal Article] Effects of target voltage during pulse-off period in pulsed magnetron sputtering on afterglow plasma and de-posited film structure2012

    • Author(s)
      T. Nakano, N. Hirukawa, S. Saeki, S. Baba
    • Journal Title

      Vacuum

      Volume: vol.86(in press)

    • URL

      http://dx.doi.org/10.1016/j.vacuum.2012.03.010

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural and optical properties of reactive-sputtered films of V2O5 : Meas-urement of optical bandgap and roughness correction2012

    • Author(s)
      K. Maki, T. Fukuda, T. Nakano, S. Baba
    • Journal Title

      成蹊大学理工学研究報告

      Volume: 49巻 Pages: 41-44

    • URL

      http://hdl.handle.net/10928/

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effects of target voltage during pulse-off period in pulsed magnetron sputtering on afterglow plasma and deposited film structure2012

    • Author(s)
      T.Nakano, N.Hirukawa, S.Saeki, S.Baba
    • Journal Title

      Vacuum

      Volume: 86(in press) Pages: 109-113

    • DOI

      10.1016/j.vacuum.2012.03.010

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and optical properties of reactive-sputtered films of V_2O_5 : Measurement of optical bandgap and roughness correction2012

    • Author(s)
      K.Maki, T.Fukuda, H.Momose, T.Nakano, S.Baba
    • Journal Title

      成蹊大学理工学研究報告

      Volume: 49巻1号(in press)

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Structural Properties of Island Films of Indium on Si(111) and the Sputter-Etching Profile2011

    • Author(s)
      S. Baba, M. Iozaki, S. Sato, T. Nakano
    • Journal Title

      成蹊大学理工学研究報告

      Volume: 48巻 Pages: 1-8

    • NAID

      120005614688

    • URL

      http://hdl.handle.net/10928/90

    • Related Report
      2011 Final Research Report
  • [Journal Article] Structural Properties of Island Films of Indium on Si(111) and the Sputter-Etching Profile2011

    • Author(s)
      S.Baba, M.Iozaki, S.Sato, T.Nakano
    • Journal Title

      成蹊大学理工学研究報告

      Volume: 48巻1号 Pages: 1-8

    • NAID

      120005614688

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Effect of the target bias voltage during off-pulse period on the impulse magnetron sputtering2010

    • Author(s)
      T. Nakano, C. Murata, S. Baba
    • Journal Title

      Vacuum

      Volume: vol.84 Pages: 1368-1371

    • URL

      http://dx.doi.org/10.1016/j.vacuum.2010.01.014

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the target bias voltage during off-pulse period on the impulsemagnetron sputtering2010

    • Author(s)
      T.Nakano, C.Murata, S.Baba
    • Journal Title

      Vacuum

      Volume: 84 Pages: 4-4

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the target bias voltage during off-pulse period on the impulse magnetron sputtering2010

    • Author(s)
      T.Nakano, C.Murata, S.Baba
    • Journal Title

      Vacuum(DOI : 10.1016.2010.01.014) (in press)

      Pages: 4-4

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      馬場茂(分担執筆)
    • Journal Title

      実用薄膜プロセス-機能創生・応用展開- 第7章 力学薄膜の物性と構造(技術教育出版)

      Pages: 219-235

    • Related Report
      2009 Annual Research Report
  • [Presentation] Electrical breakdown characteristics of MgO films deposited by RF magnetron sputtering and its dependence on process gas pressure2011

    • Author(s)
      R. Kosone, Y. Nakagawa, K. Arai, T. Nakano, S. Baba
    • Organizer
      15th Interna-tional Conference on Thin Films
    • Place of Presentation
      京都
    • Year and Date
      2011-11-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Electrical breakdown characteristics of MgO films deposited by RF magnetron dputtering and its dependence on process gas pressure2011

    • Author(s)
      R.Kosone, Y.Nakagawa, K.Arai, T.Nakano, S.Baba
    • Organizer
      15th Internation Conference on Thin Films, P-S17-05
    • Place of Presentation
      京都テルサ,京都
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Structural and optical properties of V2O5 thin films prepared by reactive magnetron sputtering : preparation and annealing behavior2011

    • Author(s)
      K. Maki, T. Fukuda, T. Nakano, S. Baba
    • Organizer
      15th International Conference on Thin Films
    • Place of Presentation
      京都
    • Year and Date
      2011-11-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Structural and optical properties of V_2O_5 thin films prepared by reactive magnetron sputtering : preparation and snnealing behavior2011

    • Author(s)
      K.Maki, T.Fukuda, T.Nakano, S.Baba
    • Organizer
      15th Internation Conference on Thin Films, P-S1-02
    • Place of Presentation
      京都テルサ,京都
    • Year and Date
      2011-11-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Diagnostics of impulse magnetron sputtering plasma with modified target bias voltage during pulse-off period2011

    • Author(s)
      T. Nakano, N. Hirukawa, S. Saeki, S. Baba
    • Organizer
      11th International Symposium on Sput-tering & Plasma Processes
    • Place of Presentation
      京都
    • Year and Date
      2011-07-07
    • Related Report
      2011 Final Research Report
  • [Presentation] Application of high power impulse sputtering to reactive deposition of titanium nitride to suppress oxygen im-purity from environment2011

    • Author(s)
      T. Sekiya, H. Ishida, T. Nakano, S. Baba
    • Organizer
      11th Inter-national Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      京都
    • Year and Date
      2011-07-07
    • Related Report
      2011 Final Research Report
  • [Presentation] Growth of target race track profile during magnetron sputtering2011

    • Author(s)
      M. Ueda, T. Nakano, S. Baba
    • Organizer
      11th Interna-tional Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      京都
    • Year and Date
      2011-07-07
    • Related Report
      2011 Final Research Report
  • [Presentation] Growth of target race track profile during magnetron sputtering2011

    • Author(s)
      M.Ueda, T.Nakano, S.Baba
    • Organizer
      11th International Symposium on Sputtering & Plasma Processes, SP P-9
    • Place of Presentation
      京都リサーチパーク,京都
    • Year and Date
      2011-07-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Application of high power impulse sputtering to reactive deposition of titanium nitride to suppress oxygen impurity from environment2011

    • Author(s)
      T.Sekiya, H.Ishida, T.Nakano, S.Baba
    • Organizer
      11th International Symposium on Sputtering & Plasma Processes, SP P-10
    • Place of Presentation
      京都リサーチパーク,京都
    • Year and Date
      2011-07-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Diagnostics of impulse magnetron sputtering plasma with modified target bias voltage during pulse-off period2011

    • Author(s)
      Nakano, N.Hirukawa, S.Saeki, S.Baba
    • Organizer
      11th International Symposium on Sputtering & Plasma Processes, SP 1-4
    • Place of Presentation
      京都リサーチパーク,京都
    • Year and Date
      2011-07-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] パルスoff期のターゲット電位を変化させた高電力パルスマグネトロンスパッタにおけるプラズマ診断2011

    • Author(s)
      中野武雄, 日留川紀彦, 佐伯修平, 馬場茂
    • Organizer
      第58回応用物理関係連合講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] パルスoff期のターゲット電位を変化させた高電力パルスマグネトロンスパッタにおけるプラズマ診断2011

    • Author(s)
      中野武雄, 日留川紀彦, 佐伯修平, 馬場茂
    • Organizer
      第56回応用物理関係連合講演会19p-ZB-5
    • Place of Presentation
      東海大,神奈川
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] マグネトロンスパッタリングにおけるターゲットエロージョンの時間発展2010

    • Author(s)
      植田麻理子, 中野武雄, 馬場茂
    • Organizer
      第51回真空に関する連合講演会
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-05
    • Related Report
      2011 Final Research Report
  • [Presentation] マグネトロンスパッタリングにおけるターゲットエロージョンの時間発展2010

    • Author(s)
      植田麻理子, 中野武雄, 馬場茂
    • Organizer
      第51回真空に関する連合講演会 5P-045
    • Place of Presentation
      大阪大学(吹田),大阪
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] パルスoff時のターゲット電位を制御した高電力パルススパッタにおけるプラズマ分析2010

    • Author(s)
      日留川紀彦, 中野武雄, 馬場茂
    • Organizer
      第51回真空に関する連合講演会
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-04
    • Related Report
      2011 Final Research Report
  • [Presentation] パルスoff時のターゲット電位を制御した高電力パルススパッタにおけるプラズマ分析2010

    • Author(s)
      日留川紀彦, 中野武雄, 馬場茂
    • Organizer
      第51回真空に関する連合講演会 4Ba-04
    • Place of Presentation
      大阪大学(吹田),大阪
    • Year and Date
      2010-11-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 低付着性の炭素系薄膜の力学特性および界面エネルギー2010

    • Author(s)
      丸山淳, 中野武雄, 馬場茂
    • Organizer
      第122回表面技術講演大会
    • Place of Presentation
      仙台
    • Year and Date
      2010-09-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 低付着性の炭素系薄膜の力学特性および界面エネルギー2010

    • Author(s)
      丸山淳, 中野武雄, 馬場茂
    • Organizer
      第122回表面技術講演大会 7D-16
    • Place of Presentation
      東北大学(川内北), 仙台
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] Secondary electron emission and elec-trical breakdown properties of sputtered MgO films at low gas pressures2010

    • Author(s)
      K. Arai, T. Sekiya, T. Nakano, S. Baba
    • Organizer
      18th International Vacuum Congress
    • Place of Presentation
      Beijing,中国
    • Year and Date
      2010-08-26
    • Related Report
      2011 Final Research Report
  • [Presentation] Secondary electron emission and electrical breakdown properties of sputtered MgO films at low gas pressures2010

    • Author(s)
      K Arai, T.Sekiya, T.Nakano, S.Baba
    • Organizer
      18th International Vacuum Congress, P3 TF1-4 17ff6e2d-e
    • Place of Presentation
      Beijing, 中国
    • Year and Date
      2010-08-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Structure modification of films de-posited by HiPIMS with target bias voltage during pulse-off period2010

    • Author(s)
      N. Hirukawa, R. Hara, T. Nakano, S. Baba
    • Organizer
      18th Interna-tional Vacuum Congress
    • Place of Presentation
      Beijing,中国
    • Year and Date
      2010-08-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Structure modification of films deposited by HiPIMS with target bias voltage during pulse-off period2010

    • Author(s)
      N.Hirukawa, R.Hara, T.Nakano, S.Baba
    • Organizer
      18th International Vacuum Congress, P1-Tf1-546266a94-6
    • Place of Presentation
      Beijing, 中国
    • Year and Date
      2010-08-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] パルスoff期のターゲット電位を変化させたパルスマグネトロンスパッタによる薄膜構造制御2010

    • Author(s)
      中野武雄, 原良輔, 日留川紀彦, 馬場茂
    • Organizer
      第57回応用物理関係連合講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2010-03-19
    • Related Report
      2011 Final Research Report
  • [Presentation] パルス off 期のターゲット電位を変化させたパルスマグネトロンスパッタによる薄膜構造制御2010

    • Author(s)
      中野武雄, 原良輔, 日留川紀彦, 馬場茂
    • Organizer
      第56回応用物理関係連合講演会 19p-ZB-5
    • Place of Presentation
      東海大, 神奈川
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] MgOスパッタ膜の電子放出特性と絶縁破壊特性の製膜時圧力依存性2009

    • Author(s)
      新井完, 関谷賢明, 中野武雄, 馬場茂
    • Organizer
      第50回真空に関する連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2009-11-04
    • Related Report
      2011 Final Research Report
  • [Presentation] MgOスパッタ膜の電子放出特性と絶縁破壊特性の製膜時圧力依存性2009

    • Author(s)
      新井完, 関谷賢明, 中野武雄, 馬場茂
    • Organizer
      第50回真空に関する連合講演会 4Ba-2
    • Place of Presentation
      学習院大, 東京
    • Year and Date
      2009-11-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] PTFE・フラーレン重ね蒸着薄膜の摩擦・摩耗特性2009

    • Author(s)
      丸山淳, 塚本英貴, 中野武雄, 馬場茂
    • Organizer
      表面技術協会第120回講演大会
    • Place of Presentation
      千葉
    • Year and Date
      2009-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] PTFE・フラーレン(C60)重ね蒸着薄膜の摩擦・摩耗特性2009

    • Author(s)
      丸山淳, 塚本英貴, 中野武雄, 馬場茂
    • Organizer
      表面技術協会第120回講演大会 18D-02
    • Place of Presentation
      幕張メッセ, 千葉
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] パルスoff時のバイアス電位を制御したパルスマグネトロンスパッタの特性(2)2009

    • Author(s)
      中野武雄, 新井完, 馬場茂
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山
    • Year and Date
      2009-09-09
    • Related Report
      2011 Final Research Report
  • [Presentation] パルス off 時のバイアス電位を制御したパルスマグネトロンスパッタの特性(2)2009

    • Author(s)
      中野武雄, 新井完, 馬場茂
    • Organizer
      第70回応用物理学会学術講演会 9a-N-5
    • Place of Presentation
      富山大, 富山
    • Year and Date
      2009-09-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Effect of the bias voltage during off-pulse period on the impulse magnetron sput-tering2009

    • Author(s)
      T. Nakano, C. Murata, S. Baba
    • Organizer
      10th International Symposium on Sputtering & Plasma Processes
    • Place of Presentation
      石川
    • Year and Date
      2009-07-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Effects of vacuum environment on oxygen impurity during the reactive sputtering deposition of metal nitrides2009

    • Author(s)
      N. Hirukawa, A. Suzuki, T. Nakano, S. Baba
    • Organizer
      10th International Symposium on Sput-tering & Plasma Processes
    • Place of Presentation
      石川
    • Year and Date
      2009-07-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Effects of vacuum environment on oxygen impurity during the reactive sputtering deposition of metal nitrides2009

    • Author(s)
      Hirukawa, Nakamura, Suzuki, Nakano, Baba
    • Organizer
      10th International Symposium on Sputtering & Plasma Processes(日本真空協会)SP P2-5
    • Place of Presentation
      金沢国際ホテル, 石川
    • Year and Date
      2009-07-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Effect of the bias voltage during off-pulse period on the impulse magnetron sputtering2009

    • Author(s)
      T.Nakano, C.Murata, S.Baba
    • Organizer
      10th International Symposium on Sputtering & Plasma Processes(日本真空協会)SP 3-2
    • Place of Presentation
      金沢国際ホテル, 石川
    • Year and Date
      2009-07-09
    • Related Report
      2009 Annual Research Report
  • [Book] 異種材料界面の測定と評価技術第13章2節付着の測定法と評価2012

    • Author(s)
      馬場茂(分担)
    • Related Report
      2011 Final Research Report
  • [Book] 異種材料界面の測定と評価技術(監修:石井淑夫)第13章2節付着の測定法と評価2012

    • Author(s)
      馬場茂(分担執筆)
    • Publisher
      テクノシステム(東京)
    • Related Report
      2011 Annual Research Report
  • [Book] 薄膜工学第2版第3章3節力学的・機械的性質の評価2011

    • Author(s)
      馬場茂(分担)
    • Publisher
      丸善出版
    • Related Report
      2011 Final Research Report
  • [Book] 薄膜工学第2版(監修:金原粲)第3章3節力学的・機械的性質の評価2011

    • Author(s)
      馬場茂(分担執筆)
    • Publisher
      丸善出版(東京)
    • Related Report
      2011 Annual Research Report
  • [Book] 剥離対策と接着・密着性の向上,第5章1節付着試験に伴う薄膜の応力場2010

    • Author(s)
      馬場茂(分担)
    • Publisher
      サイエンサイエンス & テクノロジーテクノロジーテクノロジー
    • Related Report
      2011 Final Research Report
  • [Book] 剥離対策と接着・密着性の向上-第5章1節 付着試験に伴う薄膜の応力場2010

    • Author(s)
      馬場茂 (分担執筆)
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2010 Annual Research Report
  • [Book] 実用薄膜プロセス-機能創生・応用展開-,第7章力学薄膜の物性と構造2009

    • Author(s)
      馬場茂(分担)
    • Publisher
      技術教育出版
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://surf.ml.seikei.ac.jp/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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