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Development of a new nano-material in thin film with widely variable resistivity and its application to state-of-the-art integrated circuits

Research Project

Project/Area Number 21560320
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionKitami Institute of Technology

Principal Investigator

TAKEYAMA Mayumi  北見工業大学, 工学部・電気電子工学科, 准教授 (80236512)

Co-Investigator(Kenkyū-buntansha) NOYA Atsushi  北見工業大学, 工学部, 教授 (60133807)
MACHIDA Hideaki  気相成長(株), 代表取締役 (30535670)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsナノ材料 / ホウ化物 / 抵抗率 / ナノコンポジット / Zr-B
Research Abstract

We have examined characteristics of ZrB_x thin films with off-stoichiometric compositions from the ZrB_2 compound as an application to Cu interconnects as a metal capping layer. The Zr-rich ZrB_x films containing oxygen show the dominant ZrB_2 phase and good properties as a metal capping layer. The films also show good barrier properties against Cu diffusion and/or reaction with Cu after annealing up to 500 °C for 30min. In the application of Zr-rich ZrB_x films as a metallic capping layer, it is revealed that the oxygen incorporation in proper content play an important role for stabilizing the ZrB_2 phase in the films. In addition to this, good barrier properties are characteristics of the ZrBx thin films for Cu interconnects in Si-LSI technology. From these results, the ZrBx thin films with off-stoichiometric compositions from the ZrB_2 compound are one of the promising materials as a metal capping layer also a diffusion barrier for Cu interconnects.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (12 results)

All 2012 2011 2010 2009 Other

All Journal Article (1 results) Presentation (11 results)

  • [Journal Article] Properites of ZrB_x thin films withoff-stoichiometric compositions from ZrB_2compound

    • Author(s)
      M. B. Takeyama, M. Sato, A. Noya
    • Journal Title

      Thin Solid Films

      Volume: (投稿中)

    • Related Report
      2011 Final Research Report
  • [Presentation] 非化学量論組成のZrBx薄膜のCuメタルキャップとしての特性2012

    • Author(s)
      佐藤、武山、野矢
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 非化学量論組成のZrB_x薄膜のCuメタルキャップとしての特性2012

    • Author(s)
      佐藤勝、武山真弓、野矢厚
    • Organizer
      2012応用物理学関係連合講演会
    • Related Report
      2011 Final Research Report
  • [Presentation] Cu配線のメタルキャップ層としてのZrBx膜の特性2011

    • Author(s)
      佐藤、武山、野矢
    • Organizer
      2011年電子情報通信学会エレクトロニクスソサイエティ大会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 組成を変化させたZrBx薄膜の特性評価2011

    • Author(s)
      武山、佐藤、野矢
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      青森
    • Year and Date
      2011-08-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] 組成を変化させたZrB_x薄膜の特性評価2011

    • Author(s)
      武山真弓、佐藤勝、野矢厚
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Related Report
      2011 Final Research Report
  • [Presentation] Cu配線のメタルキャップ層としてのZrB_x膜の特性2011

    • Author(s)
      佐藤勝、武山真弓、野矢厚
    • Organizer
      2011年電子情報通信学会エレクトロソサイエティ大会
    • Related Report
      2011 Final Research Report
  • [Presentation] ラジカル反応を応用したZrNx膜の低温作製2010

    • Author(s)
      佐藤、武山、早坂、青柳、野矢
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      北海道
    • Year and Date
      2010-07-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 低温作製されたZrBx薄膜のCu配線への適用2010

    • Author(s)
      武山, 佐藤, 野矢
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川)
    • Year and Date
      2010-03-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] 低温作製されたZrB_x薄膜のCu配線への適用2010

    • Author(s)
      武山真弓、佐藤勝、野矢厚
    • Organizer
      2010春季用物理学関係連合講演会
    • Place of Presentation
      神奈川
    • Related Report
      2011 Final Research Report
  • [Presentation] ZrBx薄膜の特性評価とCu配線への応用2009

    • Author(s)
      武山, 佐藤, 早坂, 青柳, 野矢
    • Organizer
      電子情報通信学会技術研究報告(電子部品・材料研究会)
    • Place of Presentation
      弘前大学(青森)
    • Year and Date
      2009-08-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] ZrB_x薄膜の特性評価とCu多層配線への応用2009

    • Author(s)
      武山真弓、佐藤勝、早坂祐一郎、青柳英二、野矢厚
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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